DEFENSE NUCLEAR FACILITIES SAFETY BOARD October 20, 1994 MEMORANDUM FOR: G. W. Cunningham, Technical Director COPIES: Board Members FROM: J. Kent Fortenberry SUBJECT: Hanford Plutonium Finishing Plant Interim Actions 1. Purpose: This report summarizes interim actions being pursued at the Hanford Plutonium Finishing Plant. This information is based on a facility visit conducted by the Defense Nuclear Facilities Safety Board (DNFSB) technical staff (Fortenberry, Grover, and Gubanc) on October 5- 6, 1994, which also included a visit to the K-East Basin. 2. Summary: The Plutonium Finishing Plant is awaiting results of an Environmental Impact Statement (EIS) to decide future actions at the facility. In the interim, actions are being taken to address immediate safety concerns and to improve the facility condition. Safety concerns being addressed include stabilizing and repackaging reactive plutonium- bearing material, reducing operator exposure, and verifying container integrity of highly corrosive plutonium solutions. Facility condition improvements being pursued include reducing contamination areas, increasing available glovebox storage capacity, and improving cleanliness and appearance. These interim actions provide an additional benefit of helping to maintain proficiency, morale, and general facility readiness. Except for the Plutonium Reclamation Facility canyon and most of the gloveboxes, the Plutonium Finishing Plant appeared clean and well kept. Discussion with operators confirmed a sense of pride and ownership in the facility. The interim actions being pursued at the Plutonium Finishing Plant can be contrasted with the K-East Basin, where there is little evidence of efforts to improve the facility condition and readiness while waiting for future actions to be identified. A significant interim action being pursued at the Plutonium Finishing Plant is the thermal stabilization of plutonium-bearing sludge and residue. Attachment I describes this activity. Specific technical staff observations concerning this sludge stabilization process are included as Attachment II. 3. Background: The Department of Energy (DOE) had intended to restart portions of the Plutonium Finishing Plant to stabilize the large inventory of plutonium bearing materials (solutions, sludge, scrap, etc.). However, public input into this proposed stabilization campaign convinced the DOE to change its plans and to prepare an Environmental Impact Statement (EIS) to consider potential future actions. This EIS is due to be completed in August 1995. 4. Discussion: Because of the decision to perform an EIS, the Plutonium Finishing Plant was faced with a significant delay in cleanup activities. Rather than wait idly for the EIS record of decision, several interim actions were developed to address immediate safety issues and to improve the facility condition. These interim activities are using existing resources in planning, engineering and conducting various nuclear materials handling activities. Some of the interim actions are identified below. Aqueous solutions used during a recent training run (about 1500 liters of less than 1 gram/liter plutonium nitrate - 475 grams Pu total) were diluted and transferred to the Tank Farms. Disposal of this solution reduced the possibility of leakage, operator exposure, equipment degradation due to corrosion, and operator surveillance requirements. Organic solutions used during a recent training run (about 250 liters) were packaged and sent to the central waste complex. Disposal of this solution reduced corrosion of equipment and the possibility of leakage. Twenty-seven 10-liter containers of highly corrosive plutonium-bearing chloride-fluoride solutions were x-rayed to confirm inner container integrity. Preparations are nearly complete for transferring this material to the Plutonium Process Support Laboratory for testing. This testing will be used to develop processing alternatives for remaining plutonium and uranium nitrate solutions. Portions of the facility have been cleaned and decontaminated. The duct level rooms and the tunnel areas have been cleaned of loose smearable contamination and reduced from a Surface Contamination Area (SCA) to a Radiological Controlled Area (RCA). Plutonium bearing duct work is being removed to reduce radiation exposure to plant personnel, to reduce the inventory of seismically dispersible plutonium, and to prepare certain areas for decontamination and decommissioning. Low plutonium content sludge has been cemented and transferred to the central waste complex. This reduced the number of sludge items and freed storage space for future cleanup activities. In addition, high plutonium content sludge will be stabilized in a furnace and then placed in vault storage. Attachment I discusses this sludge stabilization activity in more detail. 5. Future Staff Actions: The DNFSB technical staff will continue to follow activities at the Plutonium Finishing Plant, including the high-plutonium content sludge stabilization. DOE's record of decision from the EIS will of course influence future staff actions.