Argonne Coin Cell NMR/MRI Imager
First-of-a-kind device lets researchers study battery components in real time, under real test conditions
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Argonne Coin Cell NMR/MRI Imager
(with NMR/MRI add-on capability),
being held by undergraduate
intern Katarina Ruscic. |
Lithium-ion batteries have grown to a $4 to $5 billion market over the past 15 years. In addition to the electronics
and communications uses familiar to most consumers, lithium systems offer the best future opportunities for high-power, high-energy
batteries for transportation (electric vehicles, and in the nearer term, hybrid-electric vehicles, which represent a major growth
opportunity), medical devices, aerospace, defense, and power tools.
But there are serious materials challenges to be overcome in realizing the potential of lithium-ion batteries, including finding
safer, less costly, and more stable anode and cathode materials.
Seeing Events as They Unfold
Most investigations of the causes of battery degradation are performed after the battery has cycled for some number of times,
or been held at some temperature; the battery components are studied “post-mortem.”
Now, however, it is possible for the first time to study what happens to battery components as events occur. Thanks to a unique
design twist the Argonne Coin Cell NMR/MRI Imager offers the heretofore impossible capability to conduct NMR/MRI analysis in-situ,
on real components, in real time, and under real test conditions. Using add-on features, a film sample can be studied under user-set
adjustable temperature and pressure simultaneously from two additional perspectives—electrochemistry and video imaging.
This is akin to seeing an event from multiple, dynamic perspectives as it unfolds rather than piecing the event together afterward
from information gathered by several different sources.
The Argonne Coin Cell NMR/MRI Imager is a modular system with a standalone base unit for electrochemical analysis and that
a variety of add-on kits (video, temperature, pressure, additional reference electrode, and flow). Each of the add-on features
can be used with the base unit alone or in combination with other features.
The base unit is superior to comparable commercial devices, and is simpler and less expensive. That alone is a significant
technological advantage because more cells can be purchased for parallel experiments. A video imaging add-on has the advantage
of being simpler in design than comparable capabilities in competing products. But because of a unique design twist that uses
metal disks as the detector element of an NMR device, the Argonne Coin Cell NMR/MRI Imager offers the heretofore impossible capability
to conduct NMR/MRI analysis on actual, as-manufactured battery components (thin films and membranes) in real time and under real
test conditions, including user-specified pressure and temperature.
These capabilities can greatly impact the advancement of coatings and adhesives, but the most significant impact of Argonne's
Coin Cell NMR/MRI Imager will be realized in the development of the batteries and fuel cells that are essential to meeting our
energy needs for the future.
Key Patents
- U.S. Patent 6,469,507, Flat Metal Conductor Principal Detector Element for NMR
Analysis of a Sample, R.E. Gerald, II, R. J. Klingler, and J. W. Rathke, issued October 22, 2002
- U.S. Patent 6,674,283, Nuclear Magnetic Resonance Imaging Apparatus, R.E. Gerald,
II, R.J. Klingler, and J. W. Rathke, issued January 6, 2004
- U.S. Patent 6,774,635, Video Toroid Cavity Imager, R.E. Gerald, II, J. Sanchez,
and J. W. Rathke, issued August 10, 2004
The patented Argonne Coin Cell NMR/MRI Imager is available for licensing.
For More Information
Contact William Ingle, 630-252-4694, wingle@anl.gov .
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