John R. Miller 
Publication List


Scavenging Kinetics of Electrons Produced by Irradiation of Organic Glasses.  Experimental Evidence for Long-Range Tunneling Miller, J. R. J. Chem. Phys. 1972, 56, 5173-83

Time-dependent Scavenging of Trapped Electrons in 2-Methyltetrahydrofuran Glass at 77 K
Miller, J. R., Willard, J. E. J. Phys. Chem. 1972, 76, 2641-2

Wavelength Dependence of Photobleaching of Trapped Electrons in 3-Methylpentane Glass
Miller, J. R., Willard, J. E. J. Phys. Chem. 1972, 76, 2341-2

Picosecond Pulse Radiolysis.  I.  Time or Concentration Dependent Rate Constants
Jonah, C. D., Miller, J. R., Hart, E. J., Matheson, M. S. J. Phys. Chem. 1975, 79, 2705-11

Intermolecular Electron Transfer by Quantum Mechanical Tunneling
Miller, J. R. Science 1975, 189, 221-2

Reactions of Trapped Electrons by Quantum Mechanical Tunneling Observed by Pulse Radiolysis of an Aqueous Glass
Miller, J. R. J. Phys. Chem. 1975, 79, 1070-8

Electron Tunneling.  Reply to comments
Miller, J. R., Jonah, C. D. Chem. Phys. Lett. 1975, 33, 159-61

Yield and Decay of the Hydrated Electron from 100 ps to 3 ns
Jonah, C. D., Matheson, M. S., Miller, J. R., Hart, E. J. J. Phys. Chem. 1976, 80, 1267-70

Solvation of Electrons in Alcohol Glasses from 10-6 to 102s After Pulse Radiolysis at 77 K
Miller, J. R., Clifft, B. E., Hines, J. J., Runowski, R. F., Johnson, K. W. J. Phys. Chem. 1976, 80, 457-9

Yield and Decay of the Hydroxyl Radical from 200 ps to 2 ns
Jonah, C. D., Miller, J. R. J. Phys. Chem. 1977, 81, 1974-6

The Reaction of the Precursor of the Hydrated Electron With Electron Scavengers
Jonah, C. D., Miller, J. R., Matheson, M. S. J. Phys. Chem. 1977, 81, 1618-22

The Reaction of Hydrated Electron + Oxonium.  Concentration Effects of Acid or Salts
Jonah, C. D. Miller, J. R., Matheson, M. S. J. Phys. Chem. 1977, 81, 931-4

Picosecond Pulse Radiolysis Studies of Hydrated Electron Reactions, Matheson, M. S., Miller, J. R., Jonah, C. D. Proc. Tihany Symp. Radiat. Chem. 1977, 4, 819-25

Ion Recombination Processes in Rigid Solutions
Miller, J. R. Can. J. Chem. 1977, 55, 1867-75

Radiation Products and Tunneling Process in Ionic Glasses.  1.  Radiation Products and Recombination in Undoped Nitrate and Acetate Glasses
Barkatt, A., Angell, C. A., Miller, J. R. J. Phys. Chem. 1978, 82, 2143-8

Tunneling Reactions of Trapped Electrons with Added Electron Acceptors in Alcohol Glasses at 77 K
Miller, J. R. J. Phys. Chem. 1978, 82, 767-74

Experimental Determination of the Electron Tunneling Probability as a Function of Distance for Chemical Reactions
Zamaraev, K. I., Khairutdinov, R. F., Miller, J. R. Chem. Phys. Lett. 1978, 57, 311-15

Exothermic Rate Restrictions on Electron Transfer in a Rigid Medium
Beitz, J. V., Miller, J. R. J. Chem. Phys. 1979, 71, 4579-95

Activation Energies for an Intramolecular Electron Transfer Reaction
Beitz, J. V., Miller, J. R., Cohen, H., Wieghardt, K., Meyerstein, D.
Inorg. Chem. 1980, 19, 966-8
 
Kinetics of the Tunnel Reaction of Captured Electrons With Copper(II) bis(ethylenediaminate) Over a Wide Time Range
Zamaraev, K. I., Khairutdinov, R. F., Miller, J. R. Kinet. Katal. 1980, 21, 616-19

Visible Spectroscopy of Irradiated High-Alkali Borate and Mixed-Alkali Phosphate Glasses
Barkatt, A., Angell, C. A., Miller, J. R. J. Am. Ceram. Soc. 1981, 64, 158-62

Trapped-Electron Capture by Steroid Molecules with Two Distinct, Reactive Groups.  A Test of the Long-Range Tunneling Mechanism
Huddleston, R. K., Miller, J. R. J. Phys. Chem. 1981, 85, 2292-8

Long-Range Transfer of Positive Charge Between Dopant Molecules in a Rigid Glassy Matrix
Miller, J. R., Beitz, J. V. J. Chem. Phys. 1981, 74, 6746-56

Effects of Competition for Charge Capture from the Matrix on Intermolecular Electron-Tunneling Reactions
Huddleston, R. K., Miller, J. R. J. Phys. Chem. 1982, 86, 1347-50

Dynamic Spectral Shifts of Molecular Anions in Organic Glasses
Huddleston, R. K., Miller, J. R. J. Phys. Chem. 1982, 86, 2410-15

Determination of Electron-Transfer Rate Constants from Data on Tunneling to Randomly Distributed Acceptors in a Rigid Medium, Huddleston, R. K., Miller, J. R. J. Phys. Chem. 1982, 86, 200-3

Long-Distance (25 Ĺ) Electron Transfer by Triplet Excited States in Rigid Media
Miller, J. R. Hartman, K. W., Abrash, S. J. Am. Chem. Soc. 1982, 104, 4296-8

Long-Distance Fluorescence Quenching by Electron Transfer in Rigid Solutions
Miller, J. R., Peeples, J. A., Schmitt, M. J., Closs, G. L. J. Am. Chem. Soc. 1982, 104, 6488-93

Fast Intramolecular Electron Transfer in Radical Ions Over Long Distances Across Rigid Saturated Hydrocarbon Spacers
Calcaterra, L. T., Closs, G. L., Miller, J. R. J. Am. Chem. Soc. 1983, 105, 670-2
 
Rapid Long Range Intramolecular Electron Transfer Within a Steroid Molecule With Two Electron Binding Groups
Huddleston, R. K., Miller, J. R. J. Chem. Phys. 1983, 79, 5337-44
 
An Experimental Test of the Competition Correction for Charge Capture from the Matrix in Intermolecular Electron Tunneling Reactions
Huddleston, R. K., Miller, J. R. J. Phys. Chem. 1983, 87, 4867-72
 
Effect of Free Energy on Rates of Electron Transfer Between Molecules
Miller, J. R., Beitz, J. V., Huddleston, R. K. J. Am. Chem. Soc. 1984, 106, 5057-68
 
Intramolecular Long-Distance Electron Transfer in Radical Anions.  The Effects of Free Energy and Solvent on the Reaction Rates
Miller, J. R., Calcaterra, L. T., Closs, G. L. J. Am. Chem. Soc. 1984, 106, 3047-9

The Dependence of Biological Electron Transfer Rates on Exothermicity.  The Cytochrome c/cytochrome b5 Couple
McLendon, G., Miller, J. R. J. Am. Chem. Soc. 1985, 107, 7811-16
 
Effects of Distance, Energy and Molecular Structure on Long-Distance Electron-Transfer Between Molecules
Miller, J. R. Springer Ser. Chem. Phys. 1985, 42, 234-41
 
Direct Measurements of Intramolecular Electron Transfer Rates Between Cytochrome c and Cytochrome c Peroxidase:  Effects of Exothermicity and Primary Sequence on Rate
Cheung, E., Taylor, K., Kornblatt, J. A., English, A. M., McLendon, G., Miller, J. R.
Proc. Natl. Acad. Sci. U. S. A. 1986, 83, 1330-3

Distance, Stereoelectronic Effects, and the Marcus Inverted Region in Intramolecular Electron Transfer in Organic Radical Anions
Closs, G. L., Calcaterra, L. T., Green, N. J., Penfield, K. W., Miller, J. R. J. Phys. Chem. 1986, 90, 3673-83

Controlling Charge Separation Through Effects of Energy, Distance and Molecular Structure on Electron Transfer Rates
Miller, J. R. New J. Chem. 1987, 11, 83-9
 
Through-Bond Electronic Couplings in Intramolecular Electron Transfer Reactions
Miller, J. R. NATO ASI Ser., Ser. C 1987, 214, 241-54
 
Optical and Thermal Electron Transfer in Rigid Difunctional Molecules of Fixed Distance and Orientation
Penfield, K. W., Miller, J. R., Paddon-Row, M. N., Cotsaris, E., Oliver, A. M., Hush, N. S.
J. Am. Chem. Soc. 1987, 109, 5061-5
 
Intramolecular Long-Distance Electron Transfer in Organic Molecules
Closs, G. L., Miller, J. R. Science 1988, 240, 440-447

A Connection Between Intramolecular Long-Range Electron, Hole, and Triplet Energy Transfers
Closs, G. L., Johnson, M. D., Miller, J. R. Piotrowiak, P. J. Am. Chem. Soc. 1989, 111, 3751-3
 
Distance Dependence of Intramolecular Hole and Electron Transfer in Organic Radical Ions
Johnson, M. D., Miller, J. R., Green, N. S., Closs, G. L. J. Phys. Chem. 1989, 93, 1173-6
 
Correlating Temperature Dependence to Free-Energy Dependence of Intramolecular Long-Range Electron Transfers
Liang, N., Miller, J. R., Closs, G. L. J. Am. Chem. Soc. 1989, 111, 8740-1
 
Temperature-Independent Long-Range Electron Transfer Reactions in the Marcus Inverted Region
Liang, N., Miller, J. R. Closs, G. L. J. Am. Chem. Soc. 1990, 112, 5353-4

Puzzles of Electron Transfer
Miller, J. R. Adv. Chem. Ser. 1991, 228, 265-76

Superexchange-Pathway Model for Long-Distance Electronic Couplings
Naleway, C. A., Curtiss, L. A., Miller, J. R. J. Phys. Chem. 1991, 95, 8434-7
 
Spectra of the Solvated Electron in the Presence of Sodium Cation in Tetrahydrofuran and in its a,a'-methylated Derivatives
Piotrowiak, P., Miller, J. R. J. Am. Chem. Soc. 1991, 113, 5086-7

Superexchange Pathway Calculation of Long-Distance Electronic Coupling in H2C(CH2)n-2CH2 Chains
Curtiss, L. A., Naleway, C. A., Miller, J. R. Chem. Phys. 1993, 176, 387-405

Theoretical Study of Long-Distance Electronic Coupling in H2C(CH2)n-2CH2 Chains, n = 3-16
Curtiss, L. A., Naleway, C. A., Miller, J. R. J. Phys. Chem. 1993, 97, 4059-63

Distance Dependence of Intramolecular Electron Transfer Across Oligoprolines in [(bpy)2RuIIL.-(Pro)n-CoIII(NH3)5]3+, n = 1-6: Different Effects for Helical and Nonhelical Polyproline II Structure
Ogawa, M. Y., Wishart, J. F., Young, Z., Miller, J. R., Isied, S. S., J. Phys. Chem.  1993, 97, 11456-63
 
Long-Distance Electron Transfer Through Rodlike Molecules With Cubyl Spacers
Paulson, B., Pramod, K., Eaton, P., Closs, G., Miller, J. R. J. Phys. Chem. 1993, 97, 13042-5

Counterion Effects in Intramolecular Charge Transfer in Radical Anions
Piotrowiak, P., Miller, J. R. J. Phys. Chem. 1993, 97, 13052-13060

Superexchange Pathway Calculation of Electronic Coupling through Cyclohexane Spacers
Curtiss, L. A., Naleway, C. A., Miller, J. R. J. Phys. Chem. 1995, 99, 1182-93
 
Torsional Low-Frequency Reorganization Energy of Biphenyl Anion in Electron Transfer Reactions
Miller, J. R., Paulson, B. P., Bal, R., Closs, G. L. J. Phys. Chem. 1995, 99, 6923-5

Investigation of Through-Bond Coupling Dependence on Spacer Structure
Paulson, B. P., Curtiss, L. A., Bal, B., Closs, G. L., Miller, J. R. J. Am. Chem. Soc. 1996, 118, 378-87
 
Electron Binding Energy and Long-Range Electronic Coupling: A Theoretical Study
Sengupta, B., Curtiss, L. A., Miller, J. R. J. Chem. Phys. 1996, 104, 9888-9896

Fluorescence of the 1,4-Benzoquinone Radical Anion
Cook, A. R., Curtiss, L. A., Miller, J. R. J. Am. Chem. Soc. 1997, 119, 5729-5734
 
Distance Dependence of Electronic Coupling through Trans Alkyl Chains: Effects of Electron Correlation
Curtiss, L. A., Miller, J. R. J. Phys. Chem. A 1998, 102, 160-167
 
Pulse Radiolysis Measurements of Intramolecular Electron Transfer With Comparisons to Laser Photoexcitation
Miller, J. R., Penfield, K., Johnson, M., Closs, G., Green, N. Adv. Chem. Ser. 1998, 254, 161-176
 
Books and Book Chapters

Tunneling Distances and Exothermic Rate Restrictions in Electron Transfer Reactions
Beitz, J. V., Miller, J. R., in Tunneling in Biological Systems, Academic Press, New York, NY, 1979, pp 269-280

Effects of Distance, Energy and Molecular Structure on Long-Distance Electron-Transfer between Molecules
Miller, J. R., in Antennas and Reaction Centers of Photosynthetic Bacteria, M. E. Michel-Beyerle, Ed., Springer-Verlag, Berlin, 1985, Vol. 42, pp 234-241.

Thermal and Photoinduced Long Distance Electron Transfer in Proteins and in Model Systems
McLendon, G., Miller, J. R., Simolo, K., Taylor, K., Mauk, A. G., English, A. M., in Excited States and Reactive Intermediates. Photochemistry, Photophysics and Electrochemistry, A. B. P. Lever, Ed., American Chemical Society, Washington, DC, 1986, Vol. 307, pp 150-165.

Effects of Energy, Distance and Orientation on Electron Transfer Rates Studied by Pulse Radiolysis in Organic Media
Miller, J. R., in Radiation Research, Proceedings, 8th International Congress of Radiation Research, Edinburgh, Scotland, July 19-24, 1987, E. M. Fielden, Ed., Taylor & Francis, 1987, Vol, 2, pp 96-101.

Effects of Distance, Energy and Molecular Structure on Electron Transfer Rates
Miller, J. R., in Protein Structure. Molecular and Electronic Reactivity, Austin, R., Buhks, E., Chance, B., DeVault, D., Dutton, P. L., Fruaenfelder, H., Goldanski, V. I., Eds., Springer-Verlag, New York, 1987, pp 329-338
 
 A Comparison of Long Distance Electron and Energy Transfer
Closs, G. L., Piotrowiak, P., Miller, J. R., in Photochemical Energy Conversion, Proceedings of the International Conference on Photochemical Conversion and Storage of Solar Energy, 7th;
Norris, J. R., Meisel, D., Eds., Elsevier, New York, 1989, pp 23-31.

Control of Electron Transfer Rates by Motions of Atoms and Molecules
Miller, J. R., in Photochem. Processes Organized Molecular Systems,  Proceedings of the Memorial Conference for the Late Professor Shigeo Tazuke, Honda, K., Ed., North-Holland, Amsterdam, 1991, pp 41-60

Rate Processes with Kinetic Parameters Distributed over Time and Space
Miller, J. R., in a Special Issue of Chemical Physics, Berlin, Y. A., Plonka, A., Editors; Elsevier, Amsterdam, 1996, Vol. 212 (1), pp 246

Pulse Radiolysis Measurements of Intramolecular Electron Transfer with Comparisons to Laser Photoexcitation
Miller, J. R., Penfield, K., Johnson, M., Closs, G., Green, N.,
in Photochemistry and Radiation Chemistry:  Complementary Methods for the Study of Electron Transfer, Wishart, J. F., Nocera, D. G., Eds., American Chemical Society, 1998, Vol. 254, pp 161-176.
 

Thesis and Report
 
Evidence for Long Range Tunneling by Electrons Trapped in Organic Glasses at Low Temperatures
Univ. Wisconsin, Madison, Wisconsin 1971
 
Matheson, M. S., Miller, J. R., Jonah, C. D.  “Picosecond Pulse Radiolysis Studies of Hydrated Electron Reactions,” Argonne National Laboratory, Argonne, Illinois, 1976