PART 414--ORGANIC CHEMICALS, PLASTICS, AND SYNTHETIC FIBERS Subpart A--General Sec. 414.10 General definitions. 414.11 Applicability. 414.12 Compliance date for pretreatment standards for existing sources (PSES). Subpart B--Rayon Fibers 414.20 Applicability; description of the rayon fibers subcategory. 414.21 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). 414.22 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.23 Effluent limitations representing the degree of effluent reduction attainable by the application of best available technology economically achievable (BAT). 414.24 New source performance standards (NSPS). 414.25 Pretreatment standards for existing sources (PSES). 414.26 Pretreatment standards for new sources (PSNS). Subpart C--Other Fibers 414.30 Applicability; description of the other fibers subcategory. 414.31 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). 414.32 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.33 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). 414.34 New source performance standards (NSPS). 414.35 Pretreatment standards for existing sources (PSES). 414.36 Pretreatment standards for new sources (PSNS). Subpart D--Thermoplastic Resins 414.40 Applicability; description of the thermoplastics resins subcategory. 414.41 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). 414.42 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.43 Effluent limitations representing the degree of effluent reduction attainable by the application of best available technology economically achievable (BAT). 414.44 New source performance standards (NSPS). 414.45 Pretreatment standards for existing sources (PSES). 414.46 Pretreatment standards for new sources (PSNS). Subpart E--Thermosetting Resins 414.50 Applicability; description of the thermosetting resins subcategory. 414.51 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). 414.52 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.53 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). 414.54 New source performance standards (NSPS). 414.55 Pretreatment standards for existing sources (PSES). 414.56 Pretreatment standards for new sources (PSNS). Subpart F--Commodity Organic Chemicals 414.60 Applicability; description of the commodity organic chemicals subcategory. 414.61 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). 414.62 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.63 Effluent limitations representing the degree of effluent reduction attainable by the application of best available technology economically achievable (BAT). 414.64 New source performance standards (NSPS). 414.65 Pretreatment standards for existing sources (PSES). 414.66 Pretreatment standards for new sources (PSNS). Subpart G--Bulk Organic Chemicals 414.70 Applicability; description of the bulk organic chemicals subcategory. 414.71 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). 414.72 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.73 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). 414.74 New source performance standards (NSPS). 414.75 Pretreatment standards for existing sources (PSES). 414.76 Pretreatment standards for new sources (PSNS). Subpart H--Specialty Organic Chemicals 414.80 Applicability; description of the specialty organic chemicals subcategory. 414.81 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). 414.82 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.83 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). 414.84 New source performance standards (NSPS). 414.85 Pretreatment standards for existing sources (PSES). 414.86 Pretreatment standards for new sources (PSNS). Subpart I--Direct Discharge Point Sources That Use End-of-Pipe Biological Treatment 414.90 Applicability; description of the subcategory of direct discharge point sources that use end-of-pipe biological treatment. 414.91 Toxic pollutant effluent limitations and standards for direct discharge point sources that use end-of-pipe biological treatment. Subpart J--Direct Discharge Point Sources That Do Not Use End-of-Pipe Biological Treatment 414.100 Applicability; description of the subcategory of direct discharge point sources that do not use end-of-pipe biological treatment. 414.101 Toxic pollutant effluent limitations and standards for direct discharge point sources that do not use end-of-pipe biological treatment. Appendix A to Part 414--Non-Complexed Metal-Bearing Waste Streams and Cyanide-Bearing Waste Streams Appendix B to Part 414--Complexed Metal-Bearing Waste Streams Authority: Secs. 301, 304, 306, 307, and 501, Pub. L. 92-500, 86 Stat. 816, Pub. L. 95-217, 91 Stat. 156, Pub. L. 100-4, 101 Stat. 7 (33 U.S.C. 1311, 1314, 1316, 1317, and 1361). Source: 52 FR 42568, Nov. 5, 1987, unless otherwise noted. Subpart A--General 414.10 General definitions. As used in this part: (a) Except as provided in this regulation, the general definitions, abbreviations and methods of analysis set forth in part 401 of this chapter shall apply to this part. (b) Pretreatment control authority means: (1) The POTW if the POTW's submission for its pretreatment program has been approved in accordance with the requirements of 40 CFR 403.11, or (2) The Approval Authority if the submission has not been approved. (c) Priority pollutants means the toxic pollutants listed in 40 CFR 401.15. 414.11 Applicability. (a) The provisions of this part are applicable to process wastewater discharges from all establishments or portions of establishments that manufacture the organic chemicals, plastics, and synthetic fibers (OCPSF) products or product groups covered by subparts B through H of this regulation and are included within the following U.S. Department of Commerce Bureau of the Census Standard Industrial Classification (SIC) major groups: (1) SIC 2821--Plastic Materials, Synthetic Resins, and Nonvulcanizable Elastomers, (2) SIC 2823--Cellulosic Man-Made Fibers, (3) SIC 2824--Synthetic Organic Fibers, Except Cellulosic, (4) SIC 2865--Cyclic Crudes and Intermediates, Dyes, and Organic Pigments, (5) SIC 2869--Industrial Organic Chemicals, Not Elsewhere Classified. (b) The provisions of this part are applicable to wastewater discharges from OCPSF research and development, pilot plant, technical service and laboratory bench scale operations if such operations are conducted in conjunction with and related to existing OCPSF manufacturing activities at the plant site. (c) Notwithstanding paragraph (a) of this section, the provisions of this part are not applicable to discharges resulting from the manufacture of OCPSF products if the products are included in the following SIC subgroups and have in the past been reported by the establishment under these subgroups and not under the SIC groups listed in paragraph (a) of this section: (1) SIC 2843085--bulk surface active agents; (2) SIC 28914--synthetic resin and rubber adhesives; (3) Chemicals and Chemical Preparations, not Elsewhere Classified: (i) SIC 2899568--sizes, all types (ii) SIC 2899597--other industrial chemical specialties, including fluxes, plastic wood preparations, and embalming fluids; (4) SIC 2911058--aromatic hydrocarbons manufactured from purchased refinery products; and (5) SIC 2911632--aliphatic hydrocarbons manufactured from purchased refinery products. (d) Notwithstanding paragraph (a) of this section, the provisions of this part are not applicable to any discharges for which a different set of previously promulgated effluent limitations guidelines and standards in this subchapter apply, unless the facility reports OCPSF products under SIC codes 2865, 2869, or 2821, and the facility's OCPSF wastewaters are treated in a separate treatment system or discharged separately to a publicly owned treatment works. (e) The provisions of this part do not apply to any process wastewater discharges from the manufacture of organic chemical compounds solely by extraction from plant and animal raw materials or by fermentation processes. (f) Discharges of chromium, copper, lead, nickel, and zinc in ``complexed metal-bearing waste streams,'' listed in appendix B of this part, are not subject to the requirements of this part. 414.12 Compliance date for Pretreatment Standards for Existing Sources (PSES). All dischargers subject to PSES in this part must comply with the standards by no later than three years after date of promulgation in the Federal Register. Subpart B--Rayon Fibers 414.20 Applicability; description of the rayon fibers subcategory. The provisions of this subpart are applicable to process wastewater discharges resulting from the manufacture of rayon fiber by the viscose process only. 414.21 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BPT effluent limitations\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5........................................................ 64 24 TSS......................................................... 130 40 pH.......................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\ Within the range of 6.0 to 9.0 at all times. 414.22 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.23 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) The Agency has determined that for existing point sources whose total OCPSF production defined by 414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources. (b) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part. (c) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part. 414.24 New source performance standards (NSPS). (a) Any new source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Maximum Effluent characteristics Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5........................................................ 64 24 TSS......................................................... 130 40 pH.......................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.25 Pretreatment standards for existing sources (PSES). (a) Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metals or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and (2) That the combination of such streams, prior to treatment, with the appendix A waste streams would result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Pretreatment standards\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Benzene..................................................... 134 57 Carbon Tetrachloride........................................ 380 142 Chlorobenzene............................................... 380 142 1,2,4-Trichlorobenzene...................................... 794 196 Hexachlorobenzene........................................... 794 196 1,2-Dichloroethane.......................................... 574 180 1,1,1-Trichloroethane....................................... 59 22 Hexachloroethane............................................ 794 196 1,1-Dichloroethane.......................................... 59 22 1,1,2-Trichloroethane....................................... 127 32 Chloroethane................................................ 295 110 Chloroform.................................................. 325 111 1,2-Dichlorobenzene......................................... 794 196 1,3-Dichlorobenzene......................................... 380 142 1,4-Dichlorobenzene......................................... 380 142 1,1-Dichloroethylene........................................ 60 22 1,2-Trans-dichloroethylene.................................. 66 25 1,2-Dichloropropane......................................... 794 196 1,3-Dichloropropylene....................................... 794 196 Ethylbenzene................................................ 380 142 Methylene Chloride.......................................... 170 36 Methyl Chloride............................................. 295 110 Hexachlorobutadiene......................................... 380 142 Nitrobenzene................................................ 6,402 2,237 2-Nitrophenol............................................... 231 65 4-Nitrophenol............................................... 576 162 4,6-Dinitro-o-cresol........................................ 277 78 Tetrachloroethylene......................................... 164 52 Toluene..................................................... 74 28 Trichloroethylene........................................... 69 26 Vinyl Chloride.............................................. 172 97 Total Cyanide............................................... 1,200 420 Total Lead.................................................. 690 320 Total Zinc\2\............................................... 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. \2\Total Zinc for Rayon Fiber Manufacture that uses the viscose process is 6,796 g/l and 3,325 g/l for maximum for any one day and maximum for monthly average, respectively. [52 FR 42568, Nov. 5, 1987, as amended at 55 FR 26692, June 29, 1990] 414.26 Pretreatment standards for new sources (PSNS). (a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above in 414.25. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in 414.25 for the metal pollutants times the flow from metal-bearing waste streams and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and (2) That the combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. Subpart C--Other Fibers 414.30 Applicability; description of the other fibers subcategory. The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the following SIC 2823 cellulosic man-made fibers and fiber groups, except Rayon, and SIC 2824 synthetic organic fibers and fiber groups. Product groups are indicated with an asterisk (*). *Acrylic Fibers (85% Polyacrylonitrile) *Cellulose Acetate Fibers *Fluorocarbon (Teflon) Fibers *Modacrylic Fibers *Nylon 6 Fibers Nylon 6 Monofilament *Nylon 66 Fibers Nylon 66 Monofilament *Polyamide Fibers (Quiana) *Polyaramid (Kevlar) Resin-Fibers *Polyaramid (Nomex) Resin-Fibers *Polyester Fibers *Polyethylene Fibers *Polypropylene Fibers *Polyurethane Fibers (Spandex) 414.31 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve discharges not exceeding the (mass) quantity determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BPT effluent limitations\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 48 18 TSS..................................................... 115 36 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.32 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.33 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) The Agency has determined that for existing point sources whose total OCPSF production defined by 414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources. (b) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part. (c) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part. 414.34 New source performance standards (NSPS). (a) Any new source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Maximum Effluent characteristics Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 48 18 TSS..................................................... 115 36 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.35 Pretreatment standards for existing sources (PSES). (a) Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR Part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for the metals pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in Appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the Appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Pretreatment standards\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Benzene................................................. 134 57 Carbon Tetrachloride.................................... 380 142 Chlorobenzene........................................... 380 142 1,2,4-Trichlorobenzene.................................. 794 196 Hexachlorobenzene....................................... 794 196 1,2-Dichloroethane...................................... 574 180 1,1,1-Trichloroethane................................... 59 22 Hexachloroethane........................................ 794 196 1,1-Dichloroethane...................................... 59 22 1,1,2-Trichloroethane................................... 127 32 Chloroethane............................................ 295 110 Chloroform.............................................. 325 111 1,2-Dichlorobenzene..................................... 794 196 1,3-Dichlorobenzene..................................... 380 142 1,4-Dichlorobenzene..................................... 380 142 1,1-Dichloroethylene.................................... 60 22 1,2-trans-Dichloroethylene.............................. 66 25 1,2-Dichloropropane..................................... 794 196 1,3-Dichloropropylene................................... 794 196 Ethylbenzene............................................ 380 142 Methylene Chloride...................................... 170 36 Methyl Chloride......................................... 295 110 Hexachlorobutadiene..................................... 380 142 Nitrobenzene............................................ 6,402 2,237 2-Nitrophenol........................................... 231 65 4-Nitrophenol........................................... 576 162 4,6-Dinitro-o-cresol.................................... 277 78 Tetrachloroethylene..................................... 164 52 Toluene................................................. 74 28 Trichloroethylene....................................... 69 26 Vinyl Chloride.......................................... 172 97 Total Cyanide........................................... 1,200 420 Total Lead.............................................. 690 320 Total Zinc\2\........................................... 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. \2\Total zinc for the manufacture of acrylic fibers using the zinc chloride/ solvent process is 6,796 g/l and 3,325 g/l for maximum for any one day and maximum for monthly average, respectively. [52 FR 42568, Nov. 5, 1987, as amended at 55 FR 26692, June 29, 1990] 414.36 Pretreatment standards for new sources (PSNS). (a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above in 414.35. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in 414.35 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. Subpart D--Thermoplastic Resins 414.40 Applicability; description of the thermoplastic resins subcategory. The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the following SIC 28213 thermoplastic resins and thermoplastic resin groups. Product groups are indicated with an asterisk (*). *Abietic Acid--Derivatives *ABS Resins *ABS-SAN Resins *Acrylate-Methacrylate Latexes *Acrylic Latex *Acrylic Resins *Cellulose Acetate Butyrates Cellulose Acetate Resin *Cellulose Acetates *Cellulose Acetates Propionates Cellulose Nitrate Cellulose Sponge *Ethylene-Methacrylic Acid Copolymers *Ethylene-Vinyl Acetate Copolymers *Fatty Acid Resins *Fluorocarbon Polymers Nylon 11 Resin *Nylon 6--66 Copolymers *Nylon 6--Nylon 11 Blends Nylon 6 Resin Nylon 612 Resin Nylon 66 Resin *Nylons *Petroleum Hydrocarbon Resins *Polyvinyl Pyrrolidone--Copolymers *Poly(Alpha)Olefins Polyacrylic Acid *Polyamides *Polyarylamides Polybutadiene *Polybutenes Polybutenyl Succinic Anhydride *Polycarbonates *Polyester Resins *Polyester Resins, Polybutylene Terephthalate *Polyester Resins, Polyoxybenzoate Polyethylene *Polyethylene--Ethyl Acrylate Resins *Polyethylene--Polyvinyl Acetate Copolymers Polyethylene Resin (HDPE) Polyethylene Resin (LPDE) Polyethylene Resin, Scrap Polyethylene Resin, Wax (Low M.W.) Polyethylene Resin, Latex Polyethylene Resins *Polyethylene Resins, Compounded *Polyethylene, Chlorinated *Polyimides *Polypropylene Resins Polystyrene (Crystal) Polystyrene (Crystal) Modified *Polystyrene--Copolymers *Polystyrene--Acrylic Latexes Polystyrene Impact Resins Polystyrene Latex Polystyrene, Expandable Polystyrene, Expanded *Polysulfone Resins Polyvinyl Acetate *Polyvinyl Acetate--PVC Copolymers *Polyvinyl Acetate Copolymers *Polyvinyl Acetate Resins Polyvinyl Alcohol Resin Polyvinyl Chloride Polyvinyl Chloride, Chlorinated *Polyvinyl Ether-Maleic Anhydride *Polyvinyl Formal Resins *Polyvinylacetate--Methacrylic Copolymers *Polyvinylacetate Acrylic Copolymers *Polyvinylacetate-2-Ethylhexylacrylate Copolymers Polyvinylidene Chloride *Polyvinylidene Chloride Copolymers *Polyvinylidene-Vinyl Chloride Resins *PVC Copolymers, Acrylates (Latex) *PVC Copolymers, Ethylene-Vinyl Chloride *Rosin Derivative Resins *Rosin Modified Resins *Rosin Resins *SAN Resins *Silicones: Silicone Resins *Silicones: Silicone Rubbers *Styrene Maleic Anhydride Resins Styrene Polymeric Residue *Styrene-Acrylic Copolymer Resins *Styrene-Acrylonitrile-Acrylates Copolymers *Styrene-Butadiene Resins *Styrene-Butadiene Resins (<50% Butadiene) *Styrene-Butadiene Resins (latex) *Styrene-Divinyl Benzene Resins (Ion Exchange) *Styrene-Methacrylate Terpolymer Resins *Styrene-Methyl Methacrylate Copolymers *Styrene, Butadiene, Vinyl Toluene Terpolymers *Sulfonated Styrene-Maleic Anhydride Resins *Unsaturated Polyester Resins *Vinyl Toluene Resins *Vinyl Toluene-Acrylate Resins *Vinyl Toluene-Butadiene Resins *Vinyl Toluene-Methacrylate Resins *Vinylacetate-N-Butylacrylate Copolymers 414.41 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BPT Effluent Limitations\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5........................................................ 64 24 TSS......................................................... 130 40 pH.......................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.42 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.43 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) The Agency has determined that for existing point sources whose total OCPSF production defined by 414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources. (b) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part. (c) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part. 414.44 New source performance standards (NSPS). (a) Any new source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Maximum Effluent characteristics Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5........................................................ 64 24 TSS......................................................... 130 40 pH.......................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.45 Pretreatment standards for existing sources (PSES). (a) Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Pretreatment standards\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Benzene..................................................... 134 57 Carbon Tetrachloride........................................ 380 142 Chlorobenzene............................................... 380 142 1,2,4-Trichlorobenzene...................................... 794 196 Hexachlorobenzene........................................... 794 196 1,2-Dichloroethane.......................................... 574 180 1,1,1-Trichloroethane....................................... 59 22 Hexachloroethane............................................ 794 196 1,1-Dichloroethane.......................................... 59 22 1,1,2-Trichloroethane....................................... 127 32 Chloroethane................................................ 295 110 Chloroform.................................................. 325 111 1,2-Dichlorobenzene......................................... 794 196 1,3-Dichlorobenzene......................................... 380 142 1,4-Dichlorobenzene......................................... 380 142 1,1-Dichloroethylene........................................ 60 22 1,2-trans-Dichloroethylene.................................. 66 25 1,2-Dichloropropane......................................... 794 196 1,3-Dichloropropylene....................................... 794 196 Ethylbenzene................................................ 380 142 Methylene Chloride.......................................... 170 36 Methyl Chloride............................................. 295 110 Hexachlorobutadiene......................................... 380 142 Nitrobenzene................................................ 6,402 2,237 2-Nitrophenol............................................... 231 65 4-Nitrophenol............................................... 576 162 4,6-Dinitro-o-cresol........................................ 277 78 Tetrachloroethylene......................................... 164 52 Toluene..................................................... 74 28 Trichloroethylene........................................... 69 26 Vinyl Chloride.............................................. 172 97 Total Cyanide............................................... 1,200 420 Total Lead.................................................. 690 320 Total Zinc.................................................. 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. [52 FR 42568, Nov. 5, 1987, as amended at 55 FR 26692, June 29, 1990] 414.46 Pretreatment standards for new sources (PSNS). (a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above in 414.45. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in 414.45 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. Subpart E--Thermosetting Resins 414.50 Applicability; description of the thermosetting resins subcategory. The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the following SIC 28214 thermosetting resins and thermosetting resin groups. Product groups are indicated with an asterisk (*). *Alkyd Resins Dicyanodiamide Resin *Epoxy Resins *Fumaric Acid Polyesters *Furan Resins Glyoxal-Urea Formaldehyde Textile Resin *Ketone-Formaldehyde Resins *Melamine Resins *Phenolic Resins *Polyacetal Resins Polyacrylamide *Polyurethane Prepolymers *Polyurethane Resins *Urea Formaldehyde Resins *Urea Resins 414.51 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BPT effluent limitations\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5........................................................ 163 61 TSS......................................................... 216 67 pH.......................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.52 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.53 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) The Agency has determined that for existing point sources whose total OCPSF production defined by 414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources. (b) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part. (c) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part. 414.54 New source performance standards (NSPS). (a) Any new source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Maximum Effluent characteristics Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 163 61 TSS..................................................... 216 67 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.55 Pretreatment standards for existing sources (PSES). (a) Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Pretreatment standards\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Benzene................................................. 134 57 Carbon Tetrachloride.................................... 380 142 Chlorobenzene........................................... 380 142 1,2,4-Trichlorobenzene.................................. 794 196 Hexachlorobenzene....................................... 794 196 1,2-Dichloroethane...................................... 574 180 1,1,1-Trichloroethane................................... 59 22 Hexachloroethane........................................ 794 196 1,1-Dichloroethane...................................... 59 22 1,1,2-Trichloroethane................................... 127 32 Chloroethane............................................ 295 110 Chloroform.............................................. 325 111 1,2-Dichlorobenzene..................................... 794 196 1,3-Dichlorobenzene..................................... 380 142 1,4-Dichlorobenzene..................................... 380 142 1,1-Dichloroethylene.................................... 60 22 1,2-Trans-Dichloroethylene.............................. 66 25 1,2-Dichloropropane..................................... 794 196 1,3-Dichloropropylene................................... 794 196 Ethylbenzene............................................ 380 142 Methylene Chloride...................................... 170 36 Methyl Chloride......................................... 295 110 Hexachlorobutadiene..................................... 380 142 Nitrobenzene............................................ 6,402 2,237 2-Nitrophenol........................................... 231 65 4-Nitrophenol........................................... 576 162 4,6-Dinitro-o-cresol.................................... 277 78 Tetrachloroethylene..................................... 164 52 Toluene................................................. 74 28 Trichloroethylene....................................... 69 26 Vinyl Chloride.......................................... 172 97 Total Cyanide........................................... 1,200 420 Total Lead.............................................. 690 320 Total Zinc.............................................. 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. [52 FR 42568, Nov. 5, 1987, as amended at 55 FR 26692, June 29, 1990] 414.56 Pretreatment standards for new sources (PSNS). (a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above in 414.55. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in 414.55 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. Subpart F--Commodity Organic Chemicals 414.60 Applicability; description of the commodity organic chemicals subcategory. The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the following SIC 2865 and 2869 commodity organic chemicals and commodity organic chemical groups. Product groups are indicated with an asterisk (*). (a) Aliphatic Organic Chemicals Acetaldehyde Acetic Acid Acetic Anhydride Acetone Acrylonitrile Adipic Acid *Butylenes (Butenes) Cyclohexane Ethanol Ethylene Ethylene Glycol Ethylene Oxide Formaldehyde Isopropanol Methanol Polyoxypropylene Glycol Propylene Propylene Oxide Vinyl Acetate 1,2-Dichloroethane 1,3-Butadiene (b) Aromatic Organic Chemicals Benzene Cumene Dimethyl Terephthalate Ethylbenzene m-Xylene (impure) p-Xylene Phenol *Pitch Tar Residues *Pyrolysis Gasolines Styrene Terephthalic Acid Toluene *Xylenes, Mixed o-Xylene (c) Halogenated Organic Chemicals Vinyl Chloride 414.61 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BPT Effluent limitations\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 80 30 TSS..................................................... 149 46 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.62 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.63 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) The Agency has determined that for existing point sources whose total OCPSF production defined by 414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources. (b) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part. (c) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part. 414.64 New source performance standards (NSPS) (a) Any new source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Maximum Effluent characteristics Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 80 30 TSS..................................................... 149 46 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.65 Pretreatment standards for existing sources (PSES). (a) Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Pretreatment standards\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Benzene................................................. 134 57 Carbon Tetrachloride.................................... 380 142 Chlorobenzene........................................... 380 142 1,2,4-Trichlorobenzene.................................. 794 196 Hexachlorobenzene....................................... 794 196 1,2-Dichloroethane...................................... 574 180 1,1,1-Trichloroethane................................... 59 22 Hexachloroethane........................................ 794 196 1,1-Dichloroethane...................................... 59 22 1,1,2-Trichloroethane................................... 127 32 Chloroethane............................................ 295 110 Chloroform.............................................. 325 111 1,2-Dichlorobenzene..................................... 794 196 1,3-Dichlorobenzene..................................... 380 142 1,4-Dichlorobenzene..................................... 380 142 1,1-Dichloroethylene.................................... 60 22 1,2-trans-Dichloroethylene.............................. 66 25 1,2-Dichloropropane..................................... 794 196 1,3-Dichloropropylene................................... 794 196 Ethylbenzene............................................ 380 142 Methylene Chloride...................................... 170 36 Methyl Chloride......................................... 295 110 Hexachlorobutadiene..................................... 380 142 Nitrobenzene............................................ 6,402 2,237 2-Nitrophenol........................................... 231 65 4-Nitrophenol........................................... 576 162 4,6-Dinitro-o-cresol.................................... 277 78 Tetrachloroethylene..................................... 164 52 Toluene................................................. 74 28 Trichloroethylene....................................... 69 26 Vinyl Chloride.......................................... 172 97 Total Cyanide........................................... 1,200 420 Total Lead.............................................. 690 320 Total Zinc.............................................. 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. [52 FR 42568, Nov. 5, 1987, as amended at 55 FR 26692, June 29, 1990] 414.66 Pretreatment standards for new sources (PSNS). (a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above in 414.65. (b) In the case of lead, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in 414.65 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. Subpart G--Bulk Organic Chemicals 414.70 Applicability; description of the bulk organic chemicals subcategory. The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the following SIC 2865 and 2869 bulk organic chemicals and bulk organic chemical groups. Product groups are indicated with an asterisk (*). (a) Aliphatic Organic Chemicals *Acetic Acid Esters *Acetic Acid Salts Acetone Cyanohydrin Acetylene Acrylic Acid *Acrylic Acid Esters *Alkoxy Alkanols *Alkylates *Alpha-Olefins Butane (all forms) *C - 4 Hydrocarbons (Unsaturated) Calcium Stearate Caprolactam Carboxymethyl Cellulose Cellulose Acetate Butyrates *Cellulose Ethers Citric Acid Cumene Hydroperoxide Cyclohexanol Cyclohexanol, Cyclohexanone (Mixed) Cyclohexanone Cyclohexene *C12 - C18 Primary Alcohols *C5 Concentrates *C9 Concentrates Decanol Diacetone Alcohol *Dicarboxylic Acids--Salts Diethyl Ether Diethylene Glycol Diethylene Glycol Diethyl Ether Diethylene Glycol Dimethyl Ether Diethylene Glycol Monoethyl Ether Diethylene Glycol Monomethyl Ether *Dimer Acids Dioxane Ethane Ethylene Glycol Monophenyl Ether *Ethoxylates, Misc. Ethylene Glycol Dimethyl Ether Ethylene Glycol Monobutyl Ether Ethylene Glycol Monoethyl Ether Ethylene Glycol Monomethyl Ether *Fatty Acids Glycerine (Synthetic) Glyoxal Hexane *Hexanes and Other C6 Hydrocarbons Isobutanol Isobutylene Isobutyraldehyde Isophorone Isophthalic Acid Isoprene Isopropyl Acetate Ligninsulfonic Acid, Calcium Salt Maleic Anhydride Methacrylic Acid *Methacrylic Acid Esters Methane Methyl Ethyl Ketone Methyl Methacrylate Methyl Tert-Butyl Ether Methylisobutyl Ketone *n-Alkanes n-Butyl Alcohol n-Butylacetate n-Butyraldehyde n-Butyric Acid n-Butyric Anhydride *n-Paraffins n-Propyl Acetate n-Propyl Alcohol Nitrilotriacetic Acid Nylon Salt Oxalic Acid *Oxo Aldehydes--Alcohols Pentaerythritol Pentane *Pentenes *Petroleum Sulfonates Pine Oil Polyoxybutylene Glycol Polyoxyethylene Glycol Propane Propionaldehyde Propionic Acid Propylene Glycol Sec-Butyl Alcohol Sodium Formate Sorbitol Stearic Acid, Calcium Salt (Wax) Tert-Butyl Alcohol 1-Butene 1-Pentene 1,4-Butanediol Isobutyl Acetate 2-Butene (Cis and Trans) 2-Ethyl Hexanol 2-Ethylbutyraldehyde 2,2,4-Trimethyl-1,3-Pentanediol (b) Amine and Amide Organic Chemicals 2,4-Diaminotoluene *Alkyl Amines Aniline Caprolactam, Aqueous Concentrate Diethanolamine Diphenylamine *Ethanolamines Ethylamine Ethylenediamine Ethylenediaminetetracetic Acid *Fatty Amines Hexamethylene Diamine Isopropylamine m-Toluidine Melamine Melamine Crystal *Methylamines Methylene Dianiline n-Butylamine N,N-Diethylaniline N,N-Dimethylformamide *Nitroanilines Polymeric Methylene Dianiline Sec-Butylamine Tert-Butylamine Toluenediamine (Mixture) *Toluidines o-Phenylenediamine 2,6-Dimethylaniline 4-(N-Hydroxyethylethylamino)-2-Hydroxyethyl Analine 4,4'-Methylenebis (N,N'-dimethyl)-aniline 4,4'Methylenedianiline (c) Aromatic Organic Chemicals Alpha-Methylstyrene *Alkyl Benzenes *Alkyl Phenols *Alkylbenzene Sulfonic Acids, Salts Aminobenzoic Acid (Meta and Para) Aspirin Beta-Naphthalene Sulfonic Acid Benzenedisulfonic Acid Benzoic Acid Bis(2-Ethylhexyl)Phthalate Bisphenol A BTX-Benzene, Toluene, Xylene (Mixed) Butyl Octyl Phthalate Coal Tar *Coal Tar Products (Misc.) Creosote *Cresols, Mixed Cyanuric Acid *Cyclic Aromatic Sulfonates Dibutyl Phthalate Diisobutyl Phthalate Diisodecyl Phthalate Diisooctyl Phthalate Dimethyl Phthalate Dinitrotoluene (Mixed) Ditridecyl Phthalate m-Cresol Metanilic Acid Methylenediphenyldiisocyanate Naphthalene *Naphthas, Solvent Nitrobenzene Nitrotoluene Nonylphenol p-Cresol Phthalic Acid Phthalic Anhydride *Tars--Pitches Tert-Butylphenol *Toluene Diisocyanates (Mixture) Trimellitic Acid o-Cresol 1-Tetralol, 1-Tetralone Mix 2,4-Dinitrotoluene 2,6-Dinitrotoluene (d) Halogenated Organic Chemicals 1,4-Phenylenediamine Dihydrochloride Allyl Chloride Benzyl Chloride Carbon Tetrachloride *Chlorinated Paraffins, 35 - 64 PCT, Chlorine Chlorobenzene *Chlorobenzenes (Mixed) Chlorodifluoroethane Chloroform *Chloromethanes 2-Chloro-5-Methylphenol (6-chloro-m-cresol) *Chlorophenols Chloroprene Cyanogen Chloride Cyanuric Chloride Dichloropropane Epichlorohydrin Ethyl Chloride *Fluorocarbons (Freons) Methyl Chloride Methylene Chloride Pentachlorophenol Phosgene Tetrachloroethylene Trichloroethylene Trichlorofluoromethane Vinylidene Chloride 1,1-Dichloroethane 1,1,1-Trichloroethane 2,4-Dichlorophenol (e) Other Organic Chemicals Adiponitrile Carbon Disulfide Dithiophosphates, Sodium Salt Fatty Nitriles *Organo-Tin Compounds *Phosphate Esters Tetraethyl Lead Tetramethyl Lead *Urethane Prepolymers *Waxes, Emulsions--Dispersions 414.71 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BPT Effluent limitations\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 92 34 TSS..................................................... 159 49 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\ Within the range of 6.0 to 9.0 at all times. 414.72 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.73 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) The Agency has determined that for existing point sources whose total OCPSF production defined by 414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources. (b) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part. (c) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part. 414.74 New source performance standards (NSPS) (a) Any new source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Maximum Effluent characteristics Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 92 34 TSS..................................................... 159 49 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.75 Pretreatment standards for existing sources (PSES). (a) Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. (b) In the case of lead, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Pretreatment standards\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Benzene................................................. 134 57 Carbon Tetrachloride.................................... 380 142 Chlorobenzene........................................... 380 142 1,2,4-Trichlorobenzene.................................. 794 196 Hexachlorobenzene....................................... 794 196 1,2-Dichloroethane...................................... 574 180 1,1,1-Trichloroethane................................... 59 22 Hexachloroethane........................................ 794 196 1,1-Dichloroethane...................................... 59 22 1,1,2-Trichloroethane................................... 127 32 Chloroethane............................................ 295 110 Chloroform.............................................. 325 111 1,2-Dichlorobenzene..................................... 794 196 1,3-Dichlorobenzene..................................... 380 142 1,4-Dichlorobenzene..................................... 380 142 1,1-Dichloroethylene.................................... 60 22 1,2-trans-Dichloroethylene.............................. 66 25 1,2-Dichloropropane..................................... 794 196 1,3-Dichloropropylene................................... 794 196 Ethylbenzene............................................ 380 142 Methylene Chloride...................................... 170 36 Methyl Chloride......................................... 295 110 Hexachlorobutadiene..................................... 380 142 Nitrobenzene............................................ 6,402 2,237 2-Nitrophenol........................................... 231 65 4-Nitrophenol........................................... 576 162 4,6-Dinitro-o-cresol.................................... 277 78 Tetrachloroethylene..................................... 164 52 Toluene................................................. 74 28 Trichloroethylene....................................... 69 26 Vinyl Chloride.......................................... 172 97 Total Cyanide........................................... 1,200 420 Total Lead.............................................. 690 320 Total Zinc.............................................. 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. [52 FR 42568, Nov. 5, 1987, as amended at 55 FR 26692, June 29, 1990] 414.76 Pretreatment standards for new sources (PSNS). (a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above in 414.75. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in 414.75 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. Subpart H--Specialty Organic Chemicals 414.80 Applicability; description of the specialty organic chemicals subcategory. The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of all SIC 2865 and 2869 organic chemicals and organic chemical groups which are not defined as commodity or bulk organic chemicals in 414.60 and 414.70, respectively. 414.81 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BPT effluent limitations\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 120 45 TSS..................................................... 183 57 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.82 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved] 414.83 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) The Agency has determined that for existing point sources whose total OCPSF production defined by 414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources. (b) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.91 of this part. (c) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part. 414.84 New source performance standards (NSPS). (a) Any new source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.9 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with 414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Maximum Effluent characteristics Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BOD5.................................................... 120 45 TSS..................................................... 183 57 pH...................................................... (\2\) (\2\) ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units except pH are milligrams per liter. \2\Within the range of 6.0 to 9.0 at all times. 414.85 Pretreatment standards for existing sources (PSES). (a) Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table. (b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Pretreatment standards\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Benzene................................................. 134 57 Carbon Tetrachloride.................................... 380 142 Chlorobenzene........................................... 380 142 1,2,4-Trichlorobenzene.................................. 794 196 Hexachlorobenzene....................................... 794 196 1,2-Dichloroethane...................................... 574 180 1,1,1-Trichloroethane................................... 59 22 Hexachloroethane........................................ 794 196 1,1-Dichloroethane...................................... 59 22 1,1,2-Trichloroethane................................... 127 32 Chloroethane............................................ 295 110 Chloroform.............................................. 325 111 1,2-Dichlorobenzene..................................... 794 196 1,3-Dichlorobenzene..................................... 380 142 1,4-Dichlorobenzene..................................... 380 142 1,1-Dichloroethylene.................................... 60 22 1,2-trans-Dichloroethylene.............................. 66 25 1,2-Dichloropropane..................................... 794 196 1,3-Dichloropropylene................................... 794 196 Ethylbenzene............................................ 380 142 Methylene Chloride...................................... 170 36 Methyl Chloride......................................... 295 110 Hexachlorobutadiene..................................... 380 142 Nitrobenzene............................................ 6,402 2,237 2-Nitrophenol........................................... 231 65 4-Nitrophenol........................................... 576 162 4,6-Dinitro-o-cresol.................................... 277 78 Tetrachloroethylene..................................... 164 52 Toluene................................................. 74 28 Trichloroethylene....................................... 69 26 Vinyl Chloride.......................................... 172 97 Total Cyanide........................................... 1,200 420 Total Lead.............................................. 690 320 Total Zinc.............................................. 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. [52 FR 42568, Nov. 5, 1987, as amended at 55 FR 26692, June 29, 1990] 414.86 Pretreatment standards for new sources (PSNS). (a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above in 414.85. (b) In the case of lead, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in 414.85 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. Subpart I--Direct Discharge Point Sources That Use End-of-Pipe Biological Treatment 414.90 Applicability; description of the subcategory of direct discharge point sources that use end-of-pipe biological treatment. The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the OCPSF products and product groups defined by 414.11 from any point source that uses end-of-pipe biological treatment or installs end-of-pipe biological treatment to comply with BPT effluent limitations. 414.91 Toxic pollutant effluent limitations and standards for direct discharge point sources that use end-of-pipe biological treatment. (a) Any point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) In the case of chromium, copper, lead, nickel, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for these pollutants times the flow from metal-bearing waste streams for the metals and times the flow from cyanide-bearing waste streams for total cyanide. Metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the permitting authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and that (2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent limitations BAT and NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Acenaphthene............................................ 59 22 Acrylonitrile........................................... 242 96 Benzene................................................. 136 37 Carbon Tetrachloride.................................... 38 18 Chlorobenzene........................................... 28 15 1,2,4-Trichlorobenzene.................................. 140 68 Hexachlorobenzene....................................... 28 15 1,2-Dichloroethane...................................... 211 68 1,1,1-Trichloroethane................................... 54 21 Hexachloroethane........................................ 54 21 1,1-Dichloroethane...................................... 59 22 1,1,2-Trichloroethane................................... 54 21 Chloroethane............................................ 268 104 Chloroform.............................................. 46 21 2-Chlorophenol.......................................... 98 31 1,2-Dichlorobenzene..................................... 163 77 1,3-Dichlorobenzene..................................... 44 31 1,4-Dichlorobenzene..................................... 28 15 1,1-Dichloroethylene.................................... 25 16 1,2-trans-Dichloroethylene.............................. 54 21 2,4-Dichlorophenol...................................... 112 39 1,2-Dichloropropane..................................... 230 153 1,3-Dichloropropylene................................... 44 29 2,4-Dimethylphenol...................................... 36 18 2,4-Dinitrotoluene...................................... 285 113 2,6-Dinitrotoluene...................................... 641 255 Ethylbenzene............................................ 108 32 Fluoranthene............................................ 68 25 Methylene Chloride...................................... 89 40 Methyl Chloride......................................... 190 86 Hexachlorobutadiene..................................... 49 20 Naphthalene............................................. 59 22 Nitrobenzene............................................ 68 27 2-Nitrophenol........................................... 69 41 4-Nitrophenol........................................... 124 72 2,4-Dinitrophenol....................................... 123 71 4,6-Dinitro-o-cresol.................................... 277 78 Phenol.................................................. 26 15 Bis(2-ethylhexyl) phthalate............................. 279 103 Di-n-butyl phthalate.................................... 57 27 Diethyl phthalate....................................... 203 81 Dimethyl phthalate...................................... 47 19 Benzo(a)anthracene...................................... 59 22 Benzo(a)pyrene.......................................... 61 23 3,4-Benzofluoranthene................................... 61 23 Benzo(k)fluoranthene.................................... 59 22 Chrysene................................................ 59 22 Acenaphthylene.......................................... 59 22 Anthracene.............................................. 59 22 Fluorene................................................ 59 22 Phenanthrene............................................ 59 22 Pyrene.................................................. 67 25 Tetrachloroethylene..................................... 56 22 Toluene................................................. 80 26 Trichloroethylene....................................... 54 21 Vinyl Chloride.......................................... 268 104 Total Chromium.......................................... 2,770 1,110 Total Copper............................................ 3,380 1,450 Total Cyanide........................................... 1,200 420 Total Lead.............................................. 690 320 Total Nickel............................................ 3,980 1,690 Total Zinc\2\........................................... 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. \2\Total Zinc for Rayon Fiber Manufacture that uses the viscose process and Acrylic Fiber Manufacture that uses the zinc chloride/solvent process is 6,796 g/l and 3,325 g/l for maximum for any one day and maximum for monthly average, respectively. [52 FR 42568, Nov. 5, 1987, as amended at 54 FR 27352, June 29, 1989] Subpart J--Direct Discharge Point Sources That Do Not Use End-of-Pipe Biological Treatment 414.100 Applicability; description of the subcategory of direct discharge point sources that do not use end-of-pipe biological treatment. The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the OCPSF products and product groups defined by 414.11 from any point source that does not use end-of-pipe biological treatment and does not install end-of-pipe biological treatment to comply with BPT effluent limitations. 414.101 Toxic pollutant effluent limitations and standards for direct discharge point sources that do not use end-of-pipe biological treatment. (a) Any point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table. (b) In the case of chromium, copper, lead, nickel, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for these pollutants times the flow from metal-bearing waste streams for the metals and times the cyanide-bearing waste streams for total cyanide. Metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the permitting authority on a case-by-case basis as metal or cyanide bearing based upon a determination-- (1) That such streams contain significant amounts of the pollutants identified above and (2) That the combination of such streams, prior to treatment, with the appendix A waste streams would result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information. ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ BAT effluent limitations and NSPS\1\ ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Effluent characteristics Maximum Maximum for for any monthly one day average ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ Acrylonitrile........................................... 232 94 Benzene................................................. 134 57 Carbon Tetrachloride.................................... 380 142 Chlorobenzene........................................... 380 142 1,2,4-Trichlorobenzene.................................. 794 196 Hexachlorobenzene....................................... 794 196 1,2-Dichloroethane...................................... 574 180 1,1,1-Trichloroethane................................... 59 22 Hexachloroethane........................................ 794 196 1,1-Dichloroethane...................................... 59 22 1,1,2-Trichloroethane................................... 127 32 Chloroethane............................................ 295 110 Chloroform.............................................. 325 111 1,2-Dichlorobenzene..................................... 794 196 1,3-Dichlorobenzene..................................... 380 142 1,4-Dichlorobenzene..................................... 380 142 1,1-Dichloroethylene.................................... 60 22 1,2-trans-Dichloroethylene.............................. 66 25 1,2-Dichloropropane..................................... 794 196 1,3-Dichloropropylene................................... 794 196 Ethylbenzene............................................ 380 142 Methylene Chloride...................................... 170 36 Methyl Chloride......................................... 295 110 Hexachlorobutadiene..................................... 380 142 Nitrobenzene............................................ 6,402 2,237 2-Nitrophenol........................................... 231 65 4-Nitrophenol........................................... 576 162 2,4-Dinitrophenol....................................... 4,291 1,207 4,6-Dinitro-o-cresol.................................... 277 78 Tetrachloroethylene..................................... 164 52 Toluene................................................. 74 28 Trichloroethylene....................................... 69 26 Vinyl Chloride.......................................... 172 97 Total Chromium.......................................... 2,770 1,110 Total Copper............................................ 3,380 1,450 Total Cyanide........................................... 1,200 420 Total Lead.............................................. 690 320 Total Nickel............................................ 3,980 1,690 Total Zinc\2\........................................... 2,610 1,050 ÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ \1\All units are micrograms per liter. \2\Total Zinc for Rayon Fiber Manufacture that uses the viscose process and Acrylic Fibers Manufacture that uses the zinc chloride/solvent process is 6,796 g/l and 3,325 g/l for maximum for any one day and maximum for monthly average, respectively. [52 FR 42568, Nov. 5, 1987, as amended at 54 FR 27352, June 29, 1989; 55 FR 26692, June 29, 1990] Appendix A to Part 414--Non-Complexed Metal-Bearing Waste Streams and Cyanide-Bearing Waste Streams Chromium Methylhydroabietate/Esterification of hydroabietic acid (rosin) with methanol Acrylic acid/Oxidation of propylene via acrolein N-butyl alcohol/Hydrogenation of n-Butyraldehyde, Oxo process Cyclohexanone/From phenol via cyclohexanol by hydrogenation-dehydrogenation Fatty amines/Hydrogenation of fatty nitriles (batch) Helioptropin/Oxidation of isosafrole, chromium catalyst Isobutanol/Hydrogenation of isobutyraldehyde, Oxo process Cyclohexyl Mercaptan/Cyclohexanol + Hydrogen sulfide Ethyl Mercaptan/Ethanol + Hydrogen sulfide Methanol/H.P. Synthesis from natural gas via synthetic gas Oxo Alcohols, C7 - C11/Carbonation & hydrogenation of C6 - C10 Olefins Polyoxypropylene diamine/Polypropylene glycol + Ammonia n-Propyl alcohol/Hydrogenation of propionaldehyde, Oxo process SAN resin/Suspension polymerization Styrene/Dehydrogenation of ethylbenzene Styrene/Dehydration of methyl benzyl alcohol (coproduct of propylene oxide) 1-Tetralol, 1-Tetralone mix/Oxidation of tetralin (1,2,3,4-Tetrahydronaphthalene) 3,3,3-Trifluoropropene/Catalyzed hydrogen fluoride exchange with chlorinated propane Vinyl toluene/Dehydrogenation (thermal) of ethyltoluene Copper Methylhydroabietate/Esterification of hydroabietic acid (rosin) with methanol Acetaldehyde/Oxidation of ethylene with cupric chloride catalyst Acetic acid/Catalytic oxidation of butane Acetone/Dehydrogenation of isopropanol Acrylamide/Catalytic hydration of acrylonitrile Acrylic acid/Oxidation of propylene via acrolein Acrylonitrile/Propylene ammoxidation Adipic acid/Oxidation of cyclohexanol-cyclohexanone mixture Adipic acid/Oxidation of cyclohexane via cyclohexanol-cyclohexanone mixture Allynitrile/Allychloride + sodium cyanide Aniline/Hydrogenation of nitrobenzene Benzofurans, 2,3-Dihydro-2,2-dimethyl-7-benzofuranol/ from o-Nitrophenol + Methallyl chloride n-Butyl alcohol/Hydrogenation of n-Butyraldehyde, Oxo process 1,4-Butanediol/Hydrogenation of 1,4-butynediol Butryolactone/Dehydrogenation of 1,4-butanediol Caprolactam/From cyclohexane via cyclohexanone and its oxime Lilian (hydroxydihydrocitronellal)/Hydration and oxidation of citronellol 1,2-Dichloroethane/Oxyhydrochlorination of ethylene Dialkyldithiocarbamates, metal salts/Dialkylamines + carbon disulfide 2-Ethylhexanol/from n-Butyraldehyde by Aldo condensation and hydrogenation Fatty amines/Hydrogenation of fatty nitriles (batch) Geraniol/B-Myrcene + Hydrogen chloride, esterification of geranyl chloride, hydrolysis of geranyl acetate Furfuryl alcohol/Hydrogenation of furfural Geranial (Citral)/Oxidation of geraniol (copper catalyst) Glyoxal/Oxidation of ethylene glycol Isobutanol/Hydrogenation of isobutyraldehyde, Oxo process Isopropanol/Catalytic hydrogenation of acetone 2-Mercaptobenzothiazoles, copper salt/2-Mercaptobenzothiazole + copper salt Methanol/High pressure synthesis from natural gas via synthetic gas Methanol/Low pressure synthesis from natural gas via synthetic gas Methyl ethyl ketone/Dehydrogenation of sec-Butanol Oxo alcohols, C7 - C11/Carbonation & hydrogenation of C6 - C10 olefins Phenol/Liquid phase oxidation of benzoic acid Polyoxyalkylene amines/Polyoxyalkylene glycol + ammonia Polyphenylene oxide/Solution polymerization of 2,6-xylenol by oxidative coupling (cuprous salt catalyst) Polyoxypropylene diamine/Polypropylene glycol + Ammonia Quinaldine (dye intermediate)/Skraup reaction of aniline + crotonaldehyde Silicones, silicone fluids/Hydrolysis and condensation of chlorosilanes Silicones, silicone rubbers/Hydrolysis and condensation of chlorosilanes Silicones, silicone specialties (grease, dispersion agents, defoamers & other products) Silicones: Silicone resins/Hydrolysis & condensation of methyl, phenyl & vinyl chlorosilanes Silicones: Silicone fluids/Hydrolysis of chlorosilanes to acyclic & cyclic organosiloxanes Styrene/Dehydration of a-Methylbenzyl alcohol (coproduct of propylene oxide) Tetrachloroethylene (perchloroethylene)/Oxyhydrochlorination of tetrachloroethane Tris(anilino)s-triazine/Cyanuric chloride + aniline + cogeners Trichloroethylene/Oxyhydrochlorination of tetrachloroethane Unsaturated polyester resin/Reaction of maleic anhydride + phthalic anhydride + propylene glycol polyester with styrene or methyl methacrylate Lead Alkyd resin/Condensation polymerization Alkyd resins/Condensation polymerization of phthalic anhydride + glycerin + vegetable oil esters Dialkydithiocarbamates, metal salts/Dialkylamines + carbon disulfide Thiuram (dimethyldithiocarbamate) hexasulfide/Dimethyldithiocarbamate + sulfur Triphenylmethane dyes (methyl violet)/Condensation of Formaldehyde + N-Methylaniline + N,N-dimethylaniline, oxidation of reaction product 4,4'-Bis-(N,N-dimethylaniline) carbinol, Michler's hydrol/Oxidation of 4,4'-Methylene-bis(N,N-dimethylaniline) with lead oxide Naphthenic acid salts Stearic acid, metal salts/Neutralization with a metallic base Nickel Acetates, 7,11-Hexadecadien-1-ol (gossyplure)/Coupling reactions, low pressure hydrogenation, esterification Acetates, 9-dodecen-1-ol (pheromone)/Coupling reactions, low pressure hydrogenation, esterification Acrylic acid/oxidation of propylene via acrolein Acrylonitrile/Propylene ammoxidation n-Alkanes/Hydrogenation of C6-C22 alpha olefins (ethylene oligomers) Adiponitrile/Direct cyanation of butadiene Alkyl amines/Amination of alcohols 4-Aminoacetanilide/Hydrogenation of 4-Nitroacetanilide BTX/Hydrogenation of olefins (cyclohexenes) Terphenyls, hydrogenated/Nickel catalyst, hydrogenation of terphenyl Bisphenol-A, hydrogenated (Biscyclohexanol-A)/Hydrogenation of Bisphenol-A Butadiene (1,3)/Extractive distillation of C - 4 pyrolyzates n-Butanol/Hydrogenation of n-Butyraldehyde, Oxo process 1,3-Butylene glycol/Hydrogenation of acetaldol 1,4-Butanediol/Hydrogenation of 1,4-butynediol Butylenes (mixed)/Distillation pf C4 pyrolyzates 4-Chloro-2-aminophenol/Hydrogenation of 4-Chloro-2-nitrophenol Lilial (hydroxydihydrocitronellal)/Hydration and oxidation of citronellol Cycloparaffins/Catalytic hydrogenation of aromatics in kerosene solvent Cyclohexanol/Hydrogenation of phenol, distillation Cyclohexanone/From phenol via cyclohexanol by hydrogenation-dehydrogenation Dialkyldithiocarbamates, metal salts/Dialkylamines + carbon disulfide Ethylamine/Reductive amination of ethanol Ethylamines (mono, di, tri)/Reductive ammination (ammonia + hydrogen) of ethanol Isoeugenol, high % trans/Separation of mixed cis & trans isoeugenols 2-Ethylhexanol/from n-Butyraldehyde by Aldol condensation and hydrogenation Fatty acids, hydrogenated/tallow & coco acids + Hydrogen Fatty amines/Hydrogenation of fatty nitriles (batch) Fatty amines/Hydrogenation of tallow & coco nitriles Glyoxal-urea formaldehyde textile resin/condensation to N-bis(hydroxymethyl) ureas & N,N'-(dihydroxyethyl) ureas 11-hexadecenal/Coupling rxns, low pressure hydrogenation Hexahydrophthalic anhydride/Condensation of butadiene & maleic anhydride (Diels-Alder reaction) + hydrogenation Isobutanol/Hydrogenation of isobutyraldehyde, Oxo process Diisobutyl amine/Ammonolysis of isobutanol Isopropyl amines (mono, di)/Reductive ammination (Ammonia + Hydrogen) of isopropanol Linalool/Pyrolysis of 2-Pinanol Methanol/High pressure synthesis from natural gas via synthetic gas Methanol/Low pressure sythesis fron natural gas via synthetic gas Methanol/Butane oxidation Tris-(hydroxymethyl) methyl amine/Hydrogenation of tris(hydroxymethyl) nitromethane N-Methyl morpholine/Morpholine + Methanol N-Ethyl morpholine/Morpholine + Ethanol 2-Methyl-7,8-epoxy octadecane/Coupling reactions, low pressure hydrogenation, epoxidation Alpha-Olefins/Ethylene oligomer, & Zeigler Cat. Petroleum hydrocarbon resins, hydrogenated/Hydrogenation of petroleum hydrocarbon resin products Pinane/Hydrogenation of A-Pinene 2-Pinanol/Reduction of pinane hydroperoxide Bis-(p-Octylphenol) sulfide, Nickel salt/p-Octylphenol + sulfur chloride (S2C12), neutralize with Nickel base Piperazine/Reductive amination of ethanol amine (ammonia & hydrogenation, metal catalyst) N,N-Dimethylpiperazine/Condensation piperazine + formaldehyde, hydrogenation Polyoxylalkylene amines/Polyoxyalkylene glycol + Ammonia Polyoxypropylene diamine/Polypropylene glycol + Ammonia 2-Amino-2-methyl-1-propanol/Hydrogenation of 2-Nitro 2-methyl-1-propanol 3-Methoxypropyl amine/Reductive amination of acrylamide with methanol & hydrogen N-Propylamine/Reductive ammination (ammonia + hydrogen) of n-propanol Sorbitol/Hydrogenation of sugars Sulfolane/Condensation butadiene + sulfur dioxide, Hydrogenation Thionocarbamates, N-Ethyl-o-isopropyl/Isopropyl xanthate + Ethylamine Toluene diamine (mixture)/Catalytic hydrogenation of dinitrotoluene Methylated urea-formaldehyde resins (textile)/Methylation of urea-formaldehyde adduct Methylated urea-formaldehyde glyoxol (textile resin)/Reaction of methylated urea-formaldehyde + glyoxal Zinc Methylhydroabietate, diels-alder adducts/Derivatives of abietic esters from rosin Acrylic resins/Emulsion or solution polymerization to coatings Acrylic resins (latex)/Emulsion polymerization of acrylonitrile with polybutadiene Acrylic fibers (85% polyacrylonitrile) by solution polymerization/Wet spinning Alkyd Resins/Condensation polymerization of phthalic anhydride + glycerin + vegetable oil esters Benzene/By-product of styrene by ethylbenzene dehydrogenation Benzene/By-product of vinyl toluene (from ethyltoluene) n-butyl alcohol/Hydrogenation of n-Butyraldehyde, Oxo process Coumarin (benz-a-pyrone)/Salicylaldehyde, Oxo process Cycloparaffins/Catalytic hydrogenation of aromatics in kerosene solvent Dithiocarbamates, zinc salt/Reaction of zinc oxide + Sodium dithiocarbamates Dialkyldithiocarbamates, metal salts/Diakylamines + Carbon disulfide Dithiocarbamates, metal salts/Dithiocarbamic acid + metal oxide Thiuram (dimethyldithiocarbamate) hexasulfide/Dimethyldithiocarbamate + sulfur Fluorescent brighteners/Coumarin based Ethyl acetate/Redox reaction (Tschenko) of acetaldehyde Ethylbenzene/Benzene alkylation in liquid phase Ethylbenzyl chloride/Chloromethylation (Hydrogen chloride + formaldehyde, zinc chloride) of ethylbenzene 2-Ethyl hexanol/Aldol condensation-hydrogenation of n-Butyraldehyde Glyoxal-urea formaldehyde textile resin/Condensation to N-bis (hydroxymethyl) ureas + N,N'-(Dihydroxyethyl) ureas Isobutanol/Hydrogenation of isobutyraldehyde, Oxo process Isopropanol/Catalytic hydrogenation of acetone Methallylidene diacetate/Condensation of 2-Methypropenal + acetic anhydride Methanol/Low pressure sythesis from natural gas via synthetic gas Methyl chloride/Hydrochlorination of methanol Methylethyl ketone/Dehydrogenation of sec-Butanol Naphthenic acid salts Nylon Nylon 6 & 66 copolymers/Polycondensation of Nylon salt + Caprolatam Nylon 6 fiber/Extrusion (melt spinning) Oxo alcohols, C12-C15/Hydroformylation & hydrogenation of C11-C14 olefins Phenolic urethan resins/Phenol + excess formaldehyde + Methylene aniline diisocyanate Polystyrene (crystal) modified/Polystyrene + sulfonation, chloromethylation and/or amination Rayon/Viscose process SAN resin/Emulsion polymerization Silicones: Silicone rubbers/Hydrolysis and condensation of chlorosilanes Silicones: Silicone specialties (grease, dispersion agents, defoamers & other products) Silicones: Silicone resins/Hydrolysis & condensation of methyl, phenyl & vinyl chlorosilanes Silicones: Silicone fluids/Hydrolysis of chlorosilanes to acyclic & cyclic organosiloxanes Stearic acid, metal salts/Neutralization with a metallic base Styrene/Dehydrogenation of ethylbenzene Styrene-butadiene resin/Emulsion polymerization Vinyl acetate/Reduction of acetylene + acetic acid Vinyl toluene/Dehydrogenation (thermal) of ethyltoluene Xylenes, mixed/By-product vinyl toluene (from ethyltoluene) Cyanide Acetone cyanohydrin/Acetone + Hydrogen cyanide Acetonitrile/By-product of acrylonitrile from propylene by ammoxidation Acrylic resins/Solution polymerization Acrylic fiber (85% acrylonitrile)/Suspension polymerization, and wet spinning Acrylic fiber (85% acrylonitrile)/Solution polymerization, and wet spinning Acrylonitrile/Ammoxidation of propylene Adiponitrile/Butadiene + Hydrogen cyanide (direct cyanation) Allylnitrile/Allyl chloride + Sodium cyanide Dimethoxybenzaldehyde/Hydroquinone dimethyl ether + Hydrogen cyanide, hydrolysis Benzyl cyanide/Benzyl chloride + Sodium cyanide Coal tar products/Distillation of coal tar condensate Cyanoacetic acid/Chloracetic acid + sodium cyanide Cyanuric chloride/Catalyzed trimerization of cyanogen chloride Vat dyes, Indigo paste as Vat Blue 1/Sodamide + potassium N-Phenylglycine, fused with caustic/N-phenylglycine + Aniline + Formaldehyde + Sodium bisulfite, sodium cyanide, hydrolysis with potassium hydroxide Disperse dyes, Azo and Vat Ethylenediamine tetraacetic acid/Ethylenediamine + Formaldehyde + Sodium cyanide Diethylenetriamine pentaacetic acid/Diethylenetriamine + Formaldehyde + Sodium cyanide N,N'-bis(o-Acetamidophenol)ethylenediamine, ferric complex/ Salicyladehyde + Ethylenediamine + Hydrogen cyanide, hydrolysis to amide Diethylenetriamine pentaacetic acid, pentasodium salt/Diethylenetriamine pentaacetic acide + caustic Ethylenediamine tetraacetic acid, metal salts/Ethylenediamine tetraacetic acid + metal bases Hydroxyethyl ethylenediamine triacetic acid, trisodium salt/ Ethylenediamine + Ethylene oxide + Formaldehyde + Sodium cyanide, hydrolysis Hexamethylene diisocyanate/Hexamethylene diamine (1,6-Diaminohexane) + phosgene 5,5-Dimethyl hyantoin/Acetone + ammonia + carbon dioxide + hydrogen cyanide Hydrogen cyanide/By-product of acrylonitrile by ammoxidation of propylene Iminodiacetic acid/Hexamethylene tetraamine + Hydrogen cyanide, hydrolysis of iminoacetonitrile salt Methionine/Acrolein + Methyl mercaptan, with hydrogen cyanide and ammonium carbonate Methylene Diphenylisocyanate (MDI)/Phosgenation of methylene dianiline from Aniline + Formaldehyde Nitrilotriacetic acid/Hexamethylene tetraamine + Hydrogen cyanide, hydrolysis of nitrilotriacetonitrile salt Picolines, mixed/Condensation of acetaldehyde + formaldehyde + ammonia Organic pigments, Azo/Diazotization of aniline cogener, coupling to B-Napthol Polyurethane resins/Diisocyanate + Polyoxyalkylene glycol Polyurethane fibers (Spandex)/Polyoxyalkylene glycol + Tolylene diisocyanate + dialkylamine Pyrimidines, 2-Isopropyl-4-methoxy-/Isobutyronitrile + methanol, ammonia and methylacetoacetate (ring closure) Pyridine (synthetic)/Condensation of acetaldehyde + ammonia + formaldehyde Cyanopyridine/Ammoxidation of picoline Sarcosine (N-Methyl glycine), sodium salt/Hexamethylene tetraamine + Sodium cyanide, hydrolysis Thiophene acetic acid/Chloromethylation (Hydrogen chloride + Formaldehyde) + Sodium cyanide, hydrolysis Tolylene diisocyanate (isomeric mixture)/Tolylene diamines + Phosgene Tris(anilino)S-triazine/Cyanuric chloride + Aniline and its cogeners Triethylorthoformate/Ethanol + Hydrogen cyanide Trimethylorthoformate/Methanol + Hydrogen cyanide [52 FR 42568, Nov. 5, 1987, as amended at 54 FR 27352, June 29, 1989; 55 FR 26692, June 29, 1990] Appendix B to Part 414--Complexed Metal-Bearing Waste Streams Chromium Azo dye intermediates/Substituted diazonium salts + coupling compounds Vat dyes Acid dyes Azo dyes, metallized/Azo dye + metal acetate Acid dyes, Azo (including metallized) Organic pigments, miscellaneous lakes and toners Copper Disperse dyes Acid dyes Direct dyes Vat dyes Sulfur dyes Disperse dye coupler/N-substitution of 2-Amino-4-acetamidoanisole Azo dyes, metallized/Azo dye + metal acetate Direct dyes, Azo Disperse dyes, Azo and Vat Organic pigment Green 7/Copper phthalocyanine Organic pigments Organic pigments/Phthalocyanine pigments Organic pigments/Copper phthalocyanine (Blue Crude) Organic pigments, miscellaneous lakes and toners Lead Organic pigments, Quinacridines Organic pigments, Thioindigoids Nickel Azo dyes, metallized/Azo dye + metal acetate Zinc Organic pigments/Azo pigments by diazotization and coupling [52 FR 42568, Nov. 5, 1987, as amended at 54 FR 27352, June 29, 1989]