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Oleg Poluektov
Chemist, Photosynthesis Group
Argonne National Laboratory
Chemistry Division, E117
9700 South Cass Ave.
Argonne, IL 60439
Phone: 630-252-3546
Fax: 630-252-9289
E-mail: oleg@anl.gov
Career
Summary
20 years of research work in the field of chemical physics.
Specialization in EPR spectroscopy, mainly, very high frequency EPR
(95GHz, 140 GHz; CW, pulsed, ODMR, ENDOR, ESEEM, imaging,
multifrequency EPR). Development of new EPR techniques. Experienced
in the spin label technique, study of the molecular motion and the structure
of glass, crystal, liquid crystal, polymer and biopolymer systems,
mechanisms and kinetics of the chemical reactions in liquid phase.
Teaching experience. More than 60 scientific publications.
Education
1964-1974 - High School
1974-1980 - Moscow Inst.of Physics and Technology, Dept. of Chem.
Physics
1980-1983 - Postgraduate study at Moscow Inst. of Physics and Technology
1983 - Ph.D. in Physics
Positions
Held
2000-present - Chemist, Argonne National Lab., Chem. Div., Argonne,
IL
1983-2000 - Research Scientist, Inst. of Chem. Phys., Russian Academy
of
Science, Moscow, Russia
1997-1998 - Visiting Scientist, Argonne National Lab., Chem. Div.,
Argonne, IL
1991-1996 - Research Scientist, University of Lieden, The Netherlands
Research
Interest and Experience
1980-1991 - Institute of Chemical Physics of the Russian Academy
of Sciences,
laboratory of Prof. Ya. S. Lebedev, Ph.D student then research scientist
- Development and application of the very high frequency (140 GHz)
EPR technique.
- Investigation of the details of the molecular mobility, such as models
and anisotropy of the molecular reorientational motion in the glass,
liquid
crystal, biomembrane and spin labeled polymer systems. Good experience
in spin probe and spin label technique.
- Study of the polyconjugated systems, irradiated polymers and high
temperature superconductors.
- Development of new methods of the high field EPR: EPR imaging and
pulsed EPR, multifrequency EPR.
- Correlation between the molecular mobility and the kinetic of the
chemical reactions.
1991-1996 - Research scientist in the group of Prof. J. Schmidt,
Huygens Laboratory, University of Leiden, The Netherlands
- ODMR (Zero-field, 95 GHz), pulsed, time-resolved very high frequency
(95 GHz) EPR technique, pulsed (95 GHz) ENDOR-technique.
- Time-resolved EPR and ENDOR (95 GHz) study of the dynamical
properties and structure of the self-trapped exciton and the shallow
donor center in AgCl-single crystal. Shallow and deep B-acceptor centers
in SiC-single crystal.
- Structure and triplet excitations in the C60, C70- single crystals.
ENDOR (95 GHz) and ESEEM (X-Band) study of the triplet states in C60.
- EPR (95 HGz), ESEEM (95 GHz, X-Band) and ENDOR (95 GHz)
study of the single crystal of the blue copper protein azurin and its
mutants.
1997-1998 - Visiting Scientist, Argonne National Laboratory,
Chemistry Division, Argonne, IL
- Time resolved, pulsed EPR study of the photosynthetic reaction
centres, instrumentational development of the pulsed EPR systems.
Teaching
Experience
1983-1991 - Hold lectures, seminars and laboratories in General
Physics in the Moscow Institute of Communication.
Publications
(Journals and Book Chapters)
- Investigations of Anisotropic Motions of Nitroxide Radicals by
2mm Band EPR, Dubinskii A.A., Grinberg O.Ya., Kurochkin V.I.,
Oranski L.G., Poluektov O.G., Lebedev Ya.S., Teor. i Exper.
Chim. (in Russian), 1981, 17, N2, p.231-236.
- Study of Peroxide Radicals in Teflon by 2mm Band EPR,
Grinberg O.Ya., Dubinskii A.A., Poluektov O.G., Lebedev Ya.S.,
Teor. i Exper. Chim. (in Russian), 1981, 17, N6, p.806-813.
- Intermolecular Interactions in the Aqueous Solutions of
Glycerol as Studied by Spin Label Technique, Khudajberdyev V.N.,
Khabibulaev P.K., Poluektov O.G., Pulatova L.F., Ergashev U.U.,
Doklady AN Uz.SSR, (in Russian), 1982, N8, p.24-26.
- The Use of 2-mm Range Electron Spin Resonance Spectroscopy
for Investigating Rotational Motions by Spin Prob Technique,
Poluectov O.G., Dubinskii A.A., Grinberg O.Ya., Lebedev Ya.S.,
Sov. Jour. of Chem. Phys., 1984, 1, N 11, p.2500-2516.
- Intermolecular Iteractions in the Ethers of Glycerol, Reznik E.K.,
Zhulina T.V., Poluektov O.G., Pulatova L.F., Khudajberdyev V.N.,
Izvestiya AN Uz.SSR, (in Russian), 1984, N1, p.66-70.
- A Study of the Dynamics of Spin-labeled Macromolecules by
Electron Spin Resonance in the 2-mm Band, Poluectov O.G.,
Dubinskii A.A., Grinberg O.Ya., Lebedev Ya.S. Sov. Jour. of
Chem. Phys., 1985, 2, N 2, p.30.
- Study of the Structure of Glycerol Solutions, Hudiberdiev V.N.,
Habibulaev P.K., Ergashev U.U., Poluektov O.G., Pulatova L.F.,
Jorn. Phisich. Chimi. (in Russian), 1985, 59, N8, p.1957-1959.
- Study of the Structure of Glycerol Ethers, Habibulaev P.K.,
Hudiberdiev V.N., Burhonov S.A. Poluektov O.G., Pulatova L.F.,
Ergashev U.U. Chim. Physika (in Russian), 1986, 5, N5,
p.659-663.
- Study of the Flax Fibers by Spin Label Technique, Grican V.N.,
Poluektov O.G., Fazlyev F.K., Izvestiya VUZOV. Texnologiya
tekstil'noj promyshlennosti, (in Russian), 1986, 172, N.4, p.10-13.
- High Resolution EPR Spectroscopy in Investigation of
Molecular Motion, Grinberg O.Ya., Dubinskii A.A., Krimov V.N.,
Poluektov O.G., Lebedev Ya.S., Chim. Physika (in Russian),
1988, 7, N8, p.1011-1017.
- Model of Molecular Motion as Studied by 3cm and 2mm
Band EPR, Poluektov O.G., Grinberg O.Ya., Dubinskii A.A.,
Luk'yanenko L.V., Sidorov O.Yu., Lebedev Ya.S., Zhurnal
Fizicheskoi Khimii (in Russian), 1988, 62, N8, p.2079-2084.
- Determination of the Model of Isotropic Rotational Motion from
2 mm Band ESR Spectra, Poluektov O.G., Lubashevskaya E.V.,
Dubinskii A.A., Grinberg O.Ya., Antsiferova L.I., Lebedev Ya.S.,
Sov. Jour. of Chem. Phys., 1989, 4, N12, p.2683.
- Absorption of Magnetic and Electric Components of
Microwave Field in High Temperature Superconductors,
Smirnov A.I., Poluektov O.G., Grinberg O.Ya., Dubinskii A.A.,
Krimov V.N., Kaul A.R., Graboi I.E., Lebedev Ya.S., Chim.
Physika (in Russian), 1989, 8, N2, p.221-224.
- Study of Dynamics of Spin Labeled Polymers by 3cm and
2mm Band EPR, Poluektov O.G., Grinberg O.Ya., Dubinskii A.A.,
Sidorov O.Yu., Lebedev Ya.S. Teor. i Exper. Chim. (in Russian),
1989, 26, N4, p.459-466.
- Propan Oxidation in the Presence of Metal's
Polyphtalocianites, Moshkina R.I., Poluektov O.G., Polyak S.S.,
Romanovich L.B., Sherle A.I., Epshtein B.P., Kinetika i kataliz
(in Russian), 1990, 31, N2, p.381-388.
- EPR Imaging in 2mm Band, Poluektov O.G., Smirnov A.I.,
Lebedev Ya.S. Jorn. Phisich. Chimi. (in Russian), 1990, 64,
N10, p.2867-2870.
- Perchloride-3-phenylmethyl Radical as a New Spin Probe
without SHI Structure, Grinberg O.Ya., Dubinskii A.A.,
Poluektov O.G., Lebedev Ya.S., Zhurnal Fizicheskoi Khimii
(in Russian), 1990, 64, N6, p.1586-1591.
- Dynamic Characteristics and Intermolecular Interactions of
Nitroxyl Radicals in Polar Solvents, Poluectov O.G.,
Grinberg O.Ya., Dubinskii A.A., Sidorov O.Yu., Lebedev Ya.S.,
Sov. Jour. of Chem. Phys., 1990, 5, N 6, p.1375.
- Investigation of Models for Anisotropic Molecular Motion
in Vitrified Matrices Using ESR in the Two-millimetre Range,
Lubashevskaya E.V., Poluektov O.G., Dubinskii A.A.,
Grinberg O.Ya., Antsiferova L.I., Lebedev Ya.S., Sov. Jour.
of Chem. Phys., 1990, 5, N8, p.1857-1867.
- Study of Orientational Order in Liquid Crystals by the Spin
Label Technique in the 2-mm EPR Range, Grinberg O.Ya.,
Dubinskii A.A., Poluektov O.G., Lebedev Ya.S., Sov. Jorn.
of Chem. Phys., 1990, 6, N10, p.2685-2704.
- A Motion Model for an Analysis of Molecular Mobility
of Spin Probes, Lubashevskaya E.V., Antsiferova L.I.,
Poluektov O.G., Grinberg O.Ya.,Dubinskii A.A., Lebedev Ya.S.,
Sov. Jour. of Chem. Phys., 1990, 7, N4, p.940-945.
- EPR of Coals: New Approach to an Old Problem with
Multifrequency EPR and Spin Echo, Bresgunov A.Yu.,
Dubinsky A.A., Poluektov O.G., Vorob'eva G.A., Lebedev Ya.S.,
J. Chem. Soc. (Faraday Transactions), 1990, 86, N19,
p.3185-3189.
- Very High Field and Multifrequency ESR Study of a Coal
Sample, Bresgunov A.Yu., Poluektov O.G., Lebedev Ya.S.,
Barra A.L., Brunel L.C., Robert J.B., Chem. Phys. Letters,
1990, 175, p.621-623.
- Pulsed EPR in 2mm Band, Bresgunov A.Yu., Dubinskii A.A.,
Krimov V.N., Poluektov O.G., Lebedev Ya.S., J. Appl. Magn.
Res., 1991, 2, N3, p.715-728.
- Brezgunov A.Yu., Vorob'eva G.A., Dubinskii A.A.,
Pluektov O.G., Lebedev Ya.S. Russ. J. Phys. Chem., 1991,
65, p.313-318.
- Brezgunov A.Yu., Dubinskii A.A., Poluektov O.G.,
Prokof'ev A.I., Chemerisov S.D., Lebedev Ya.S., Zhurnal
Structurnoj Khimii, (in Russian), 1992, 33, p.69-77.
- High-Field EPR Imaging, Smirnov A.I., Poluektov O.G.,
Lebedev Ya.S., J.Magn. Res., 1992, 97, p. 1-12.
- Molecular Mobility and Oxidation Rate of Nitroxyl Radicals
in Micellar and Homogeneous Systems, Todorov G.P.,
Poluektov O.G., Petrov A.N., Grinberg O.Ya.,
Lebedev Ya.S., Zhurnal Fizicheskoi Khimii, (in Russian),
1992, 66, N3, p.651-655.
- Shear Strain Effect on Molecular Orientation and
Rotational Mobility of the Spin Probe in Aromatic Polyesters,
Dadali A.A., Lushchik A.N, Poluektov O.G., Vysokomol.
Soedineniya, (in Russian), 1992, 34, N1, p.35-41.
- On the Nature of Manganese Ions in the beta-Ca2SiO4
Structure Detected by High Field ESR, Luck R., Stosser R.,
Poluektov O. G., Grinberg O.Ya., Lebedev Ya.S., Z. Anorg.
Allg. Chem., 1992, 607, p.183-187.
- The Structure of Phenoxyl Radicals as Studied by 2mm
Band ESR, Brezgunov A.Yu., Dubinsky A.A., Poluektov O.G.,
Lebedev Ya.S., Prokof'ev A.I., Molecular Physics, 1992,
75, N5, p.1123-1131.
- Kuzina S.I., Demidov S.V., Brezgunov A.Yu., Poluektov O.G.,
Grinberg O.Ya., Dubinskii A.A., Mikhailov A.I., Lebedev Ya.S.,
Vysokomol. Soedineniya, (in Russian), 1993, 35A, p.798-802.
- 2mm EPR of Nitroxide Spin Probes, Grinberg O.Ya.,
Dubinsky A.A., Poluektov O.G., Lebedev Ya.S., in "Bioactive
Spin Labels", ed., Zhdanov R.I., Springer Verlag, 1992,
p.227-278.
- Exchange Splitting of Self-Trapped Excitons in AgCI from
Optically Detected EPR at 95 GHz, Donckers M.C.J.M.,
Poluektov O.G., Schmidt J., Phys. Rev. B, 1992, 45,
N22, p.13061-13063.
- Triplet excitation of C60 and the Structure of the Crystal
at 1.2 K, Groenen E.J.J., Poluektov O.G., Matsushita M.,
Schmidt J., van der Waals J.H., Meijer G., Chem. Phys. Lett.,
1992, 197, N3, p.314-318.
- Dynamical Properties of the Self-trapped Exciton in AgCl
as Studied by Time-resolved EPR at 95 GHz, Poluektov O.G.,
Donckers M.C.J.M., Baranov P.G., Schmidt J., Phys.
Rev. B, 1993, 47, N16, p.10226-10234.
- ESE-detected EPR of Triplet Radical Pairs Produced by
Mechano-chemical Treatment of 2,6-di-t-butylquinone Diazide
Mixed with 3,5-di-t-butylpyrocathechon, Tipikin D.S.,
Lebedev Ya.S., Poluektov O.G., Schmidt J., Chem. Phys.
Lett., 1993, 215, N1,2,3, p.199-202.
- A W-Band Electron Paramagnetic Resonance Study of a
Single Crystal of Azurin, Coremans J.W.A., Poluektov O.G.,
Groenen E.J.J., Canters G.W., Nar H., Messerschmidt A.,
J. Am. Chem. Soc., 1994, 116, p.3097-3101.
- Triplet Excitations of Crystalline C60: An Optically-
Detected Magnetic Resonance Study in Zero-Field,
Matsushita M., Frens A.M., Groenen E.J.J., Poluektov O.G.,
Schmidt J., Chem. Phys. Lett., 1994, 214, N3,4,
p.349-352.
- An ENDOR and ESEEM Study of the Blue Copper
Protein Azurin, Coremans J.W.A., van Gastel M.,
Poluektov O.G., Groenen E.J.J., den Blaauwen T.,
van Pouderoyen G., Canters G.W., Nar H., Hammann C.,
Messerschmidt A., J. Chem. Phys., 1995, 235, p.202-210.
- Structure of the Intrinsic Shallow Electron Center in
AgCl Studied by Pulsed Electron Nuclear Double Resonance
Spectroscopy at 95 GHz, Bennebroek M.T., Poluektov O.G.,
Zakrzewski A.J., Baranov P.G., Schmidt J., Phys. Rev.
Lett., 1995, 74, p.442-445.
- A Pulsed EPR and ENDOR Spectrometer Operating at 95
GHz, Disselhorst J.A.J.M., van der Meer H., Poluektov O.G.,
Schmidt J., J. Mag. Res., 1995, A115, p.183-188.
- Studies of Framework Iron in Ziolites by Pulsed ENDOR
at 95 GHz, Goldfarb D., Strohmaier K.G., Vaughan D.E.W.,
Thomann H., Poluektov O.G., Schmidt J., J. Am. Chem.
Soc., 1996, 118, p.4665-4671.
- Magnetic Properties of Metal-Quinone High-Spin
Complexes Prepared by Solid-State Mechano-Activation
and by Chemical Synthesis in Solution, Chemerisov S.D.,
Perekhodtsev G.D., Tipikin D.S., Lebedev Ya.S.,
Prokof'ev A.I., Aleksandrov A.I., Dubinskii A.A., Mobius K.,
Poluektov O.G., Schmidt J., J. Chem. Soc., Faraday
Trans., 1996, 92, p.1959-1968.
- Spatial Distribution of the Wave Function of the
Self-Trapped Exciton in AgCl, Bennebroek M.T., Arnold A.,
Poluektov O.G., Baranov P.G., Schmidt J., Phys. Rev
B, 1996, 53, p.15607-15616.
- The Azurin Mutant Met121Gln: a Blue-Copper Protein
with a Strong Axial Ligand, Coremans J.W.A., Poluektov O.G.,
Groenen E.J.J., Warmerdam G., Canters G.W., Nar. H.,
Messerschmidt A., J. Phys. Chem., 1996, 100, #50,
p.19706-19713.
- Pulsed EPR and ENDOR Spectroscopy at 95 GHz,
Poluektov O.G., Schmidt J., Bruker Report, 1996, 143,
p.34-37.
- Shallow Electron Centers in Silver Halides, Bennebroek M.T.,
Arnold A., Poluektov O.G., Baranov P.G., Schmidt J., Phys.
Rev. B, 1996, 54, #16, p.11276-11289.
- W-Band Electron Nuclear Double Resonance Study of
Single Crystals of 14N and 15N Azurin, Coremans J.W.A.,
Poluektov O.G., Groenen E.J.J., Canters G.W., Nar. H.,
Messerschmidt A., J. Am. Chem. Soc., 1996, 118, #48,
p.12141-12153.
- W-Band Electron Spin Echo Envelope Modulation Study
of a Single Crystal of Azurin, Coremans J.W.A., Poluektov O.G.,
Groenen E.J.J., Canters G.W., Nar. H., Messerschmidt A.,
J. Am. Chem. Soc., 1997, 119, #20, p.4726-4731.
- Electronic Structure of the Shallow Boron Acceptor in
6H-SiC: A Pulsed EPR/ENDOR Study at 95 GHz,
Matsumoto T., Poluektov O.G., Schmidt J., Mokhov E.N.,
Baranov P.G., Phys. Rev. B, 1997, 55, #4, p.2219-2229.
- Spin-Spin Coupling in Complexes of Diamagnetic Metals
with Semiquinone Radicals, Gal'tseva E.V., Vorob'eva G.A.,
Dubinskii A.A., Perekhodtsev G.D., Poluektov O.G.,
Chemerisov S.D., Aleksandrov A.I., Prokofev A.I.,
Lebedev Ya.S., Russian Journal of Physical Chemistry,
71, No. 11, 1997, pp. 1826-1831. [Translated from
Zhurnal Fizicheskoi Khimii, 71, No. 11, 1997,
pp. 2021 - 2026.]
- Electronic Structure of the Deep Boron Acceptor in Boron-
Doped 6H-SiC, van Duijn-Arnold A., Ikoma T., Poluektov O.G.,
Baranov P.G., Mokhov E.N., Schmidt J. Phys. Rev. B, 1998,
57, #3, p.1607-1619.
- Pulsed ENDOR Studies at 95 GHz of the Triplet State of
13C60, van den Berg G.J.B., van den Heuvel D.J.,
Poluektov O.G., Holleman I., Meijer G., Groenen E.J.J.,
J. Mag. Res., 1998, 131, p.39-45.
- Triplet-State Dynamics of C70, Dauw X.L.R., Poluektov O.G.,
Warntjes J.B.M., Bronsveld M.V., Groenen E.J.J., J. Phys.
Chem., 1998, 102, #18, p.3078-3082.
- Two-Dimensional High-Field Electron Spin Echo
Spectroscopy of Nitroxide Spin Probes, Poluektov O.G.,
Doubinski A.A. Chem. Phys. Lett., 1998, 288, p.841-846.
- Improving Optical and Charge Separation Properties of
Nanocrystalline TiO2 by Surface Modification with Vitamin
C,
Rajh T., Nedeljkovic J.M., Chen L.X., Poluektov O.,
Thurnauer M.C., J. Phys. Chem. B, 1999, 103, #18,
p. 3515-3519.
- Magnetic Field Induced Orientation of Photosynthetic
Reaction Centers as Revealed by Time-Resolved W-Band
EPR of Spin-Correlated Radical Pairs, Berthold, T., Bechtold,
M., Heinen, U., Link, G., Poluektov, O., Utschig, L., Tang, J.,
Thurnauer, M. C., Kothe, G., J. Phys. Chem. B, 1999, 103,
p. 10733-10736.
- Transient W-Band EPR Study of Sequential Electron
Transfer in Photosynthetic Bacterial Reaction Centers,
Tang J., Utschig L.M., Poluektov O., Thurnauer M.,
J. Phys. Chem. B, 1999, 103, 5145-5150.
- Spectroscopic and Computational Studies of [OsCl5(NO)]3-
and [RuCl5(NO)]3- Donors in AgCl, Eachus R.S.,
Baetzold R.C., Pawlik Th.D., Poluektov O.G., Schmidt J.,
Phys. Rev. B., 1999, 59, p. 8560-8571.
- EPR Spectroscopy of Polydiphenyldiacetylene Derivatives,
Kokorin, A.I., Poluektov, O.G., Kholuiskaya, S.N.,
Rudakova, L.N. and Misin, V.M., Russian Journ. Phys.
Chem., 1999, 73, p. 1046-1050.
- Electronic Structure of the Be Acceptor Center in 6H-SiC,
v.Duijn-Arnold, A., Schmidt, J., Poluektov, O.G.,
Baranov, P.G. and Mokhov, E.N., Phys. Rev. B, 1999,
60, p. 15799-15809.
- The Triplet Wavefunction of C60 from W-band Electron
Nuclear Double Resonance Spectroscopy, Dauw, X.L.R.,
van de Berg, G.J.B., van den Heuvel, D.J., Poluektov, O.G.
and Groenen, E.J.J., J. Chem. Phys., 2000, 112, p. 7102-7110.
- EPR Investigation of Cu2+ -Substituted Photosynthetic
Bacterial Reaction Centers: Evidence for Histidine Ligation
at the Surface Metal Site, Utschig L.M., Poluektov O.
Tiede D.M. and Thurnauer M.C., Biochem., 2000, 39,
p. 2961-2969.
- The G-Factor Anisotropy of Plant Chlorophyll a+., Bratt
P.J.,
Poluektov O., Thurnauer M., Knzystek J., Brunel L-C.,
Xchrier J., Hsiao Y-W., Zerner M., Angerhofer A., J. Phys.
Chem., 2000, 104, p. 6973-6977.
- High-Field EPR Study of Carotenoid and Chlorophyll Cation
Radicals in Photosystem II, Lakshmi, K. V., Reifler, M. J.,
Brudvig, G. W., Poleuktov, O. G., Wagner, A. M. and
Thurnauer, M. C., J. Phys. Chem. B, 2000, 104, p. 10445-10448.
- Structure of the P+700A-1
Radical Pair Intermediate in
Photosystem I by High Time Resolution Multifrequency Electron
Paramagnetic Resonance - Analysis of Quantum Beat
Oscillations, Link, G., Berthold, T., Bechtold, M., Weidner, J.-U.,
Ohmes, E., Tang, J., Poluektov, O.G., Utschig, L., Schlesselman,
S., Thurnauer, M.C. and Kothe, G., J. Am. Chem. Soc., 2001,
123, p. 4211-4222.
- A Cu2+ Site in Photosynthetic Bacterial Reaction Centers
from
Rb. sphaeroides, Rb. capsulatus, and Rps. viridis, Utschig, L.M.,
Poluektov, O.G., Schlesselman, S.L., Thurnauer, M.C. and
Tiede, D.M., Biochem., 2001, 40, p. 6132-6141.
- Spin Polarization Mechanisms in Early Stages of Photoinduced
Charge Separation in Surface-Modified TiO2 Nanoparticles,
Rajh, T., Poluektov, O., Dubinski, A. A., Wiederrecht, G.,
Thurnauer, M. C., and Trifunac, A. D., Chem. Phys. Lett.,
2001, 344, p. 31-39.
- High-Frequency EPR Approach to the Electron Spin-
Polarization Effects Observed in the Photosynthetic Reaction
Centers, Poluektov, O.G., Utschig, L.M., Tang, J., Dubinski, A.A.,
Schlesselman, S. and Thurnauer, M.C., Appl. Magn. Reson., 2001,
21, 311-323.
- Exploring the Structure of Radical Pair Intermediates by Quantum
Beat Oscillations and High-Field EPR, Link, G., Poluektov, O.,
Thurnauer, M.C. and Kothe, G., RIKEN Review, 2001, No. 44.
- The G-Factor Anisotropy of Bacteriochlorophyll a-,
Poluektov, O.,
Thurnauer, M., Brunel, L.-C., Zvyagin, S., Boyce, C., Walker, L.,
and Angerhofer, A., NHMFL 2000 Annual Research Review, p. 42,
2001 (Published on website
www.nhmfl.gov/publications/2000annualreview/pdfs/NHMFL2000AR-Biology.pdf).
- Analytical Treatment of EPR Spectra of Weakly Coupled Spin
Correlated Radical Pairs in Disordered Solids: Applications to the
Charge Separated State in TiO2 Nanoparticles, Dubinski, A.A.,
Perekhotsev, G.D., Poluektov, O.G., Rajh, T. and Thurnauer, M.C.,
J. Phys. Chem. B, 2002, 106 (5), 938-944.
- Electron and Hole Adducts Formed in Illuminated InP Colloidal
Quantum Dots Studied by Electron Paramagnetic Resonance,
O. I. Micic, A. J. Nozik, E. Lifschitz, T. Rajh, O. G. Poluektov,
and M. C. Thurnauer, J. Phys. Chem. B, 2002, 106 (17), 4390-4395.
- Pulsed High-Frequency EPR Study on the Location of Carotenoid
and Chlorophyll Cation Radicals in Photosystem II, K. V. Lakshmi,
O. G. Poluektov, M. J. Reifler, A. M. Wagner, M. C. Thurnauer,
and G. W. Brudvig, J. Am. Chem. Soc., 2003, 125 (17), 5005-5014.
- Probing Local Dynamics of the Photosynthetic Bacterial Reaction
Center with a Cysteine Specific Spin Label, O. G. Poluektov,
L. M. Utschig, S. Dalosto, and M. C. Thurnauer, J. Phys. Chem. B.,
2003, 107 (25), 6239-6244.
- Charge Separation in Titanium Oxide Nanocrystalline Semiconductors
Revealed by Magnetic Resonance, Rajh, T., Poluektov, O. G., and
Thurnauer, M. C., Chemical Physics of Nanostructured Semiconductors,
Chapter 1, 2003, Ed., A. I. Kokorin, NOVA Science Publ., Inc., New York
- Substrate-Supported Lipid Nanotube Arrays, Smirnov, A. I. and
Poluektov, O. G., J. Am. Chem. Soc. Comm., 2003, 125 (28),
8434-8435.
- ENDOR of Spin-Correlated Radical Pairs in Photosynthesis at High
Magnetic Field: A Tool for Mapping Electron Transfer Pathways,
Poluektov, O. G., Utschig, L. M., Dubinskij, A. A. and Thurnauer, M.
C.,
J. Am. Chem. Soc. Comm., 2004, 126 (6), 1644-1645.
- Photoinitiated Charge Separation: From Photosynthesis to Nanoparticles,
M. C. Thurnauer, N. M. Dimitrijevic, O. G. Poluektov, and T. Rajh,
The Spectrum, 2004, 17 (1), 10-15.
- Magnetic-Field-Induced Orientation of Photosynthetic Reaction Centers,
as Revealed by Time-Resolved D-Band Electron Paramagnetic
Resonance of Spin-Correlated Radical Pairs. II. Field Dependence
of the Alignment, U. Heinen, O. Poluektov, E. Stavitski, T. Berthold,
E. Ohmes, S. L. Schlesselman, J. R. Golecki, G. J. Moro, H. Levanon,
M. C. Thurnauer, and G. Kothe, J. Phys. Chem. B, 2004, 108 (27),
9498-9504.
- Pulsed EPR/ENDOR Characterization of the Cu2+ Surface Site
in
Photosynthetic Bacterial Reaction Centers, Utschig, L. M.,
Astashkin, A. V., Raitsimring, A. M., Thurnauer, M. C., and
Poluektov, O. G., J. Phys. Chem. B, 2004, 108, 11150-11156.
- Magnetic Field Induced Orientation of Photosynthetic Reaction Centers
as Revealed by Time-Resolved W-Band EPR of Spin-Correlated
Radical Pairs. III. Development of a Molecular Model, U. Heinen,
J. R. Goleski, O. Poluektov, T. Berthold, S. L. Schlesselman, D. Frezzato,
E. Ohmes, G. J. Moro, M. C. Thurnauer, and G. Kothe, Appl. Magn.
Res., 2004, 26 (1-2).
- Time-Resolved High-Frequency and Multifrequency EPR Studies of
Spin-Correlated Radical Pairs in Photosynthetic Reaction Center Proteins,
M. C. Thurnauer, O. G. Poluektov, and G. Kothe Chapter 6 in Biological
Magnetic Resonance, Vol. 22, Very High Frequency (VHF) ESR/EPR,
O. Y. Grinberg and L. J. Berliner, Eds., Kluwer Academic/Plenum
Publishers, New York, 2004, pp 165-206.
- Electron Transfer Pathways and Protein Response to Charge
Separation in Photosynthetic Reaction Centers: Time-Resolved
High-Field ENDOR of the Spin-Correlated Radical Pair P865+QA-,
O. G. Poluektov, L. M. Utschig, A. A. Dubinskij, and M. C. Thurnauer,
J. Am. Chem. Soc., 2005, 127 (11), 4049-4059.
- High-Field Pulsed EPR and ENDOR of Gd3+ Complexes in Glassy
Solutions, A. M. Raitsimring, A. V. Astashkin, O. G. Poluektov, and
P. Caravan, Appl. Magn. Reson., 2005, 28, 281-295.
- Bidirectional Electron Transfer in Photosystem I: Direct Evidence
from
High-Frequency Time-Resolved EPR, O. G. Poluektov, S. V. Paschenko,
L. M. Utschig, K. V. Lakshmi, and M. C. Thurnauer, J. Am. Chem. Soc.,
2005, 127 (34), 11910-11911.
- Structural Organization in Photosynthetic Proteins as Studied by High-Field
EPR of Spin-Correlated Radical Pair States, G. Link, O. G. Poluektov,
L. M. Utschig, J. Lalevee, T. Yago, J-U. Weidner, M. C. Thurnauer,
and G. Kothe, Magn. Res. In Chem., 2005, 43, S103-S109.
- Low Temperature Interquinone Electron Transfer in Photosynthetic
Reaction Centers from Rb. sphaeroides and Blc. viridis: Characterization
of QB- States by High-Frequency EPR and ENDOR,
L. M. Utschig,
M. C. Thurnauer, D. M. Tiede, and O. G. Poluektov, Biochemistry, 2005,
44 (43), 14131-14142.
- Determination of the Hydration Number of Gadolinium(III) Complexes
by High-Field Pulsed 17O ENDOR Spectroscopy, A. M. Raitsimring,
A. V. Astashkin, D. Baute, D. Goldfarb, O. G. Poluektov, M. P. Lowe,
S. G. Zech, and P. Caravan, ChemPhysChem, 2006, 7, 1590-1597.
- The Chemistry of Phospholipid Binding by the Saccharomyces cerevisiae
Phosphatidylinositol Transfer Protein Sec14p as Determined by Electron
Paramagnetic Resonance Spectroscopy, T. I. Smirnova, T. G. Chadwick,
R. MacArthur, O. Poluektov, L. Song, M. Ryan, and V. A. Bankaitis,
J. Biol. Chem., 2006, 281 (46), 34897-34908.
- Spin-Correlated Radical Pairs: Differential Effect in High-Field ENDOR
Spectra, A. A. Dubinskij, L. M. Utschig, and O. G. Poluektov, Appl.
Magn.
Reson., 2006, 30, 269-286.
- Charge Separation and Surface Reconstruction: A Mn2+ Doping
Study,
Z. V. Saponjic, N. M. Dimitrijevic, O. Poluektov, L. X. Chen, E. Wasinger,
U. Welp, D. Tiede, X. Zuo, and T. Rajh, J. Phys. Chem. B, 2006, 110
(50),
25441-25450.
- Complex and Charge Transfer between TiO2 and Pyrroloquinoline
Quinone,
N. M. Dimitrijevic, O. G. Poluektov, Z. Saponjic, and T. Rajh, J. Phys.
Chem.
B, 2006, 110 (50), 25392-25398.
- Exploring Hyperfine Interactions in Spin-Correlated Radical Pairs
from
Photosynthetic Proteins: High-Frequency ENDOR and Quantum Beat
Oscillations, O. G. Poluektov, L. M. Utschig, M. C. Thurnauer, and G.
Kothe,
Appl. Magn. Reson., 2007, 31 (1-2), 123-143.
- Geometry of Hydrogen Bonds Formed by Lipid Bilayer Nitroxide Probes:
A High Frequency Pulsed ENDOR/EPR Study, T. I. Smirnova, A. I. Smirnov,
S. Pachtchenko, and O. G. Poluektov, J. Am. Chem. Soc. Commun., 2007,
129 (12), 3476-3477.
- Geometry of Hydrogen Bonds Formed by Lipid Bilayer Nitroxide Probes:
A High Frequency Pulsed ENDOR/EPR Study, T. I. Smirnova, A. I. Smirnov,
S. Pachtchenko, and O. G. Poluektov, J. Am. Chem. Soc. (Communication),
2007, 129 (12), 3476-3477.
- High-Field EPR Studies of Electron Transfer Intermediates in Photosystem
I, M. C. Thurnauer, O. G. Poluektov, and G. Kothe, Chapter 20 in
Photosystem I: The Plastocyanin:Ferrdoxin Oxidoreductase in
Photosynthesis, Govindjee et al., Eds., Kluwer Academic Press,
Dordrecht, in press.
- Local Polarity and Hydrogen Bonding inside Sec14p Lipid-binding Cavity:
High-Field Multifrequency EPR Studies, T. I. Smirnova, T. G. Chadwick,
M. A. Voinov, O. Poluektov, J. van Tol, A. Ozarowski, G. Schaaf, M.
M.
Ryan, and V. A. Bankaitis, Biophys. J., 2007, 92 (10), 3686-3695.
- Effect of Size and Shape of Nanocrystalline TiO2 on Photogenerated
Charges.
An EPR Study, N. M. Dimitrijevic, Z. V. Saponjic, B. M. Rabatic,
O. G. Poluektov, and T. Rajh, J. Phys. Chem. C Lett., 2007, 111
(40),
14597-14601.
- High-Time Resolution Electron Paramagnetic Resonance - Study of Quantum
Beat Oscillations Obsserved in Photosynthetic Reaction Center Proteins,
G. Kothe, J. R. Norris, O. G. Poluektov, and M. C. Thurnauer, Chapter
18 in
Biophysical Techniques on Photosynthesis, J. Matysik and T. J. Aartsma,
Eds., Springer, 2007, in press.
- Protein Environments and Electron Transfer Processes Probed with
High-Frequency ENDOR, O. G. Poluektov and L. M. Utschig, in The
Purple Photosynthetic Bacteria, L. M. C. N. Hunter, F. Daldal,
M. C. Thurnauer, and J. T. Beatty, Eds., Kluwer Publishers, in press
2007
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