Proper Segregation of Chemical Classes
Partial
List of Incompatible chemicals
(Toxic Hazards)
Substances in the left hand column should be stored and handled so that they cannot possibly accidentally contact corresponding substances in the center column, because toxic materials (right hand column) would be produced.
Arsenical Materials Any Reducing Agent Arsine | ||
---|---|---|
Azides | Acids | Hydrogen Azide |
Cyanides | Acids | Hydrogen Cyanide |
Hypochlorites | Acids | Chlorine or Hypochlorous Acid |
Nitrates | Sulfuric Acid | Nitrogen Dioxide |
Nitric acid | Copper,
Brass, Heavy Metals |
Nitrogen Dioxide |
Nitrites | Acids | Nitrous Fumes |
Phosphorus | Caustic
Alkalies/ Reducers |
Phosphine |
Selenides | Reducers | Hydrogen Selenide |
Sulfides | Acids | Hydrogen Sulfide |
Tellurides | Reducers | Hydrogen Telluride |
Reactive Chemicals
Reactive chemicals are substances which, under certain ambient or induced conditions, enter into violent reactions with spontaneous generation of large quantities of heat, light, gases (flammable and non-flammable), or toxicants that can be destructive to lives and property. Types of reactive chemicals have been loosely categorized:
Explosives
In general, protect explosive substances from shock, elevated temperatures, rapid temperature changes, and other reactive chemicals, Some examples: nitroglycerin, nitrocellulose, and organic peroxides. Many substances, when mixed, are potentially explosive (such as hydrazines and nitric acid).
Oxidizing and Reducing Substances
In many oxidizing and reducing reactions, both agents must be present. In some cases, one or the other substance may create a hazard by coming into contact with a normally innocuous substance. These reactions tend to generate heat and are often explosive, e.g., glycerol and potassium permanganate blended at room temperature for a few minutes react violently producing fire. The following examples of typical oxidizers may:
Increase
Rate of Combustion |
|
---|---|
Aluminum nitrate | Perchloric acid 60% or less |
Ammonium persulfate | Potassium chlorate |
Barium chlorate | Potassium dichromate |
Barium peroxide | Potassium nitrate |
Calcium chlorate | Potassium persulfate |
Calcium nitrate | Silver nitrate |
Calcium peroxide | Silver nitrite |
Cupric nitrate | Sodium perborate |
Hydrogen peroxide | Sodium perchlorate |
Lead nitrate | Sodium persulfate |
Lithium hypochlorite | Strontium chlorate |
Lithium peroxide | Strontium nitrate |
Magnesium nitrate | Strontium nitrite |
Magnesium perchlorate | Thorium nitrite |
Magnesium peroxide | Uranium nitrate |
Nickel nitrate | Zinc chlorate |
Nitric acid 70% or less | Zinc peroxide |
Cause
Spontaneous Ignition |
|
Calcium hypochlorite | Sodium chlorite (>40%) |
Chromic acid | Sodium peroxide |
Hydrogen peroxide (27.5-52%) | Sodium permanganate |
Nitric acid | Trichloroisocyanuric acid |
Potassium bromate | Sodium dichloroisocyanurate |
Potassium permanganate | |
Decompose
with Catalyst or Heat |
|
Ammonium dichromate | Perchloric acid (60-72.5%) |
Hydrogen peroxide (52-91%) | Potassium dichloroisocyanurate |
Calcium hypochlorite (>50%) | Sodium dichloroisocyanurate |
Cause
Explosive Reaction when exposed to Catalyst, Heat, Shock, or Friction |
|
Ammonium perchlorate | Perchloric acid |
Ammonium permanganate | Potassium superoxide |
Water Sensitive Substances
These chemicals react with water, steam, and moisture in the air to evolve heat and/or flammable or explosive gases. Isolate water-sensitive substances from other reactive compounds, and store in a cool, waterproof area. Some substances that liberate only hear are: strong acids and bases, acid anhydrides and sulfides. Some substances that liberate flammable gases when exposed to water are: alkali metals, hydrides, nitrites, carbides, and anhydrous metallic salts.
Air Reactive Substances
These materials are capable of rapid release of energy by themselves, as by self-reaction or polymerization, for example white phosphorous. Also included in this category are substances that can be easily ignited by common sources of heat when mixed with air, for example: alkali metals, ammonium nitrate, ammonium perchlorate, ammonium permanganate, benzoyl peroxide, boron hydrides, dinitrobenzene, lithium hydride, sulfur.
Acid Reactive Substances
These chemicals react with acid to evolve heat, flammable and/or explosive gases, and toxicants. Some examples are: alkali metals, hydroxides, carbides, nitrites, arsenic and related elements, cyanides, sulfides, and structural alloys (most metals).
Special Organic Compounds
These compounds are unstable and may decompose spontaneously or through contact with the immediate environment (air, water, and other reactants). Some examples: diazonium compounds, diazomethane, chlorination intermediates, butadiene, nitration intermediates, organic sulfates, polymerization reactions, and highly nitrated compounds.
Pyrophoric Agents
Pyrophoric agents burn when exposed to air. In general, they require absolute protection against air. Examples: phosphorus and activated zinc.
Incompatible Chemicals
The following is a partial listing of incompatible chemicals. A more complete listing may be found in NFPA and various laboratory and chemical reference manuals.
CHEMICAL |
IS
INCOMPATIBLE WITH |
---|---|
ACETIC ACID | Chromic acid, nitric acid, hydroxyl-containing compounds, ethylene glycol, perchloric acid, peroxides, and permanganates |
ACETONE | Concentrated sulfuric and nitric acid mixtures or chloroform and bases |
ACETYLENE | Copper tubing, halides, silver, mercury and their compounds |
ALKALI METALS | Aluminum, calcium, lithium, magnesium, potassium and sodium with water or chlorinated hydrocarbon, carbon dioxide, halogens |
AMMONIA, ANHYDROUS | Mercury, halogens, calcium hypochlorite, hydrogen fluoride |
ANILINE | Nitric acid and hydrogen peroxide |
AZIDES | Acids |
BROMINE | Ammonia, acetylene, butadiene, butane, hydrogen, sodium carbide, turpentine |
CHLORATES | Ammonium salts, acids, metal powders, sulfur, finely divided organic and combustible materials |
CHROMIC ACID | Acetic acid, alcohol, camphor, flammable liquids, glycerol, naphthalene |
CHLORINE | Ammonia, acetylene, butadiene, benzene and other petroleum fractions, hydrogen, sodium carbides, powdered metals |
COPPER SALTS | Acetylene, hydrogen peroxide |
CYANIDES | Acids |
ETHYLENEDIAMINE | Greater than 3 percent with methylene chloride (explosive) |
FLAMMABLE LIQUIDS | Ammonium nitrate, chromic acid, hydrogen peroxide, halogens, nitric acid, sodium peroxide |
HYDROCARBONS | (Butane, Halogens, chromic acid, peroxides Propane, Benzene) |
HYDROGEN PEROXIDE | Copper, chromium, iron, most metals and their salts, flammable fluids, aniline, and nitromethane |
HYDROGEN SULFIDE | Nitric acid and oxidizing gases |
IODINE | Acetylene, ammonia |
CHEMICAL |
IS INCOMPATIBLE
WITH |
MERCURY | Acetylene, hydrogen |
METHYLENE CHLORIDE | Greater than 3 percent ethylenediamine (explosive) |
NITRIC ACID | Acetic, chromic and hydrochloric acids, aniline, carbon, hydrogen sulfide, flammable fluids, or gases which are readily nitrated |
OXYGEN | Oils, grease, hydrogen, flammable liquids, solids, and gases |
OXALIC ACID | Mercury, silver |
PERCHLORIC ACID | Acetic anhydride, alcohol, organic materials, e.g., wood, paper, grease, and oils |
PHOSPHORUS | Air, alkalis, oxygen, reducing agents |
PHOSPHORUS PENTOXIDE | Water |
SODIUM | Carbon dioxide, carbon tetrachloride, water |
SODIUM PEROXIDE | Any oxidizable substances; acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerol, ethylene glycol, ethyl acetate, methanol |
SULFURIC ACID | Potassium chlorate, potassium perchlorate, potassium permanganate |