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Method Summary

Method Source Hach Company
Method Number8202
Revision Information2003
Method NameDescriptive Name: Phenolphthalein (Total) Acidity of Water

Official Name: Phenolphthalein (Total) Acidity

MediaMedia: WATER
SubcategoryInorganic
Citation Hach Water Handbook (1997)
Method DownloadThis is a proprietary method.
Please visit the method owner's site for method documentation
Summary of MethodBromophenol blue indicator is used to titrate the sample with sodium hydroxide to a colorimetric end point. Bromophenol blue gives a better end point than methyl orange indicator. Titration to pH 3.7 determines strong mineral acidity (also referred to a methyl orange acidity. The results are expressed in mg/L as calcium carbonate (CaCO3) at a specified pH.
Scope and ApplicationFor water, wastewater, and seawater
Applicable Concentration Range10-4000 mg/L as CaCO3
InterferencesHighly colored or turbid samples may mask the color change at the end point. Use a pH meter for these samples, titrating to pH 3.7 for methyl orange acidity.
QC Requirements 
Sample HandlingCollect samples in clean plastic or glass bottles. Fill completely and cap tightly. Minimize agitation or prolonged exposure to air. Samples may be stored at least 24 hours by cooling to 4deg C. or below if they cannot be analyzed immediately. Warm to room temperature before analyzing.
Max Holding Time24 hours @ 4deg. C.
Relative Cost/EffortLess than $50
Sample Prep Method(s) 
 

Method Phenolphthalein (Total) Acidity of Water has 1 analytes associated with it.

Analyte


Detection
Level


Bias Precision Pct False
Positive
pH
(E-10139)
10 mg/LN/AN/A 
export_analytes
Precision Descriptor Notes -
Detection Level Note -
 
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