Bibliographic Citation
| Document | For copies of Journal Articles, please contact the Publisher or your local public or university library and refer to the information in the Resource Relation field. For copies of other documents, please see the Availability, Publisher, Research Organization, Resource Relation and/or Author (affiliation information) fields and/or Document Availability. |
|---|---|
| Title | Pressure-dependent electron attachment and breakdown strengths of unary gases and synergism of binary gas mixtures: A relationship |
| Creator/Author | Hunter, S.R. ; Christophorou, L.G. |
| Publication Date | 1985 May 01 |
| OSTI Identifier | OSTI ID: 5994939 |
| DOE Contract Number | AC05-84OR21400 |
| Other Number(s) | CODEN: JAPIA |
| Resource Type | Journal Article |
| Resource Relation | J. Appl. Phys. ; Vol/Issue: 57:9 |
| Research Org | Atomic, Molecular, and High Voltage Physics Group, Health and Safety Research Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 |
| Subject | 400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987) ;400201 -- Chemical & Physicochemical Properties ;640304 -- Atomic, Molecular & Chemical Physics-- Collision Phenomena; CARBON FLUORIDES-- BREAKDOWN;CARBON FLUORIDES-- ELECTRON ATTACHMENT;CARBON FLUORIDES-- ION-MOLECULE COLLISIONS;CARBON FLUORIDES-- IONIZATION;FLUORINATED ALIPHATIC HYDROCARBONS-- BREAKDOWN;FLUORINATED ALIPHATIC HYDROCARBONS-- ELECTRON ATTACHMENT;FLUORINATED ALIPHATIC HYDROCARBONS-- ION-MOLECULE COLLISIONS;FLUORINATED ALIPHATIC HYDROCARBONS-- IONIZATION;SULFUR FLUORIDES-- BREAKDOWN;SULFUR FLUORIDES-- ELECTRON ATTACHMENT;SULFUR FLUORIDES-- ION-MOLECULE COLLISIONS;SULFUR FLUORIDES-- IONIZATION; BINARY MIXTURES;DIELECTRIC MATERIALS;ELECTRIC POTENTIAL;PRESSURE DEPENDENCE |
| Related Subject | CARBON COMPOUNDS;COLLISIONS;DISPERSIONS;FLUORIDES;FLUORINE COMPOUNDS;HALIDES;HALOGEN COMPOUNDS;HALOGENATED ALIPHATIC HYDROCARBONS;ION COLLISIONS;MATERIALS;MIXTURES;MOLECULE COLLISIONS;ORGANIC COMPOUNDS;ORGANIC FLUORINE COMPOUNDS;ORGANIC HALOGEN COMPOUNDS;SULFUR COMPOUNDS |
| Description/Abstract | The relationship between the pressure-dependent electron attachment rate constants which have been observed in 1-C/sub 3/F/sub 6/ and in several perfluoroalkanes and the uniform field breakdown strengths (E/N)/sub lim/ in these gases is discussed.^Also discussed are the various types of synergistic behavior in (E/N)/sub lim/ which have been observed in binary dielectric gas mixtures.^For the latter, a new mechanism is outlined which explains the synergism observed in several gas mixtures where the (E/N)/sub lim/ values of the mixtures are greater than those of the individual gas constituents, which we call positive synergism.^Model calculations are presented which support this mechanism and can be used to explain the pressure-dependent synergistic effects which have been reported in 1-C/sub 3/F/sub 6//SF/sub 6/ and other gas mixtures.^Experimentally observed ion--molecule reaction processes for several gases are discussed which support the proposed mechanism.^Based on this mechanism, we outline several conditions which must be fulfilled in order to observe positive synergistic behavior in dielectric gas mixtures. |
| Country of Publication | United States |
| Language | English |
| Format | Pages: 4377-4385 |
| System Entry Date | 2001 May 13 |
Top | |
 |
Information
Bridge • Energy
Citations Database • E-print
Network • R&D
Accomplishments
About OSTI Science.gov • USA.gov • USAJOBS • Grants • Regulations.gov |
 |
|---|
Last Updated: 02/16/2009