US 7,393,984 B1 | ||
Method for production of cumene hydroperoxide | ||
Vladimir Zakoshansky, Long Grove, Ill. (US); Irina Vassilieva, St. Petersburg (Russian Federation); Andrey Budarev, St. Petersburg (Russian Federation); Vasiliy Trubaev, St. Petersburg (Russian Federation); and Sergey Korchagin, Novokuznetsk (Russian Federation) | ||
Assigned to ILLA International, LLC, Reno, Nev. (US) | ||
Filed on Nov. 01, 2007, as Appl. No. 11/934,032. | ||
Int. Cl. C07C 409/14 (2006.01) |
U.S. Cl. 568—569 | 20 Claims |
1. A continuous method for producing cumene hydroperoxide (CHP) through cumene oxidation by air oxygen in at least one sequential
reactor, comprising the steps of
(a) providing said at least one sequential reactor, at least one reactor thereof comprising at least one airlift-type tray
and at least one air-free area;
(b) conducting the cumene oxidation reaction in said at least one sequential reactor, in one of said at least one sequential
reactor until a predetermined threshold CHP concentration is reached;
(c) during said step (b), fracturing a first plurality of air bubbles formed during the cumene oxidation reaction having a
first oxygen contact area, by said at least one airlift-type tray, to generate a greater plurality of smaller air bubbles
having a second oxygen contact area greater than said first oxygen contact area and having a longer residence time in said
at least one sequential reactor, thereby accelerating the cumene oxidation reaction;
(d) discharging an oxidate, resulting from said accelerated cumene oxidation reaction, from said at least one of said air-free
areas of said at least one sequential reactor;
(e) selectively causing contact between said oxidate and an aqueous base solution, to remove at least one reaction inhibitor,
such that after said contact, said oxidate comprises an aqueous phase and an organic phase, wherein said step (e) is performed
at least once; and
(f) selectively physically separating said aqueous phase from said organic phase and:
(1) when said at least one sequential reactor comprises a single reactors recycling said organic phase to said single reactor
to perform said steps (a) to (f) until a predetermined required CHP concentration is achieved, and
(2) when said at least one sequential reactor comprises a plurality of sequential reactors, passing said organic phase to
a next plural sequential reactor to perform said steps (a) to (f) until said predetermined required CHP concentration is achieved,
and recycling said organic phase to a first of said plural sequential reactors when said step (a) has been performed in a
east plural sequential reactor, and said predetermined required CHP concentration has not yet been achieved.
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