Bibliographic Citation
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Title | Synthesis and reactions of diazocarbonyl compounds. I. Reaction of 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-phthalimidoalkan-2-ones with hydrazine hydrate. Synthesis of 1-diazo-3-, 1-diazo-4, and 1-diazo-5-arenesulfamoyl-alkan-2-ones |
Creator/Author | Sipyagin, A.M. ; Kartsev, V.G. |
Publication Date | 1986 Jul 20 |
OSTI Identifier | OSTI ID: 6191672 |
Other Number(s) | CODEN: JOCYA |
Resource Type | Journal Article |
Resource Relation | J. Org. Chem. USSR (Engl. Transl.) ; Vol/Issue: 22:2; Translated from Zh. Org. Khim.; 22: No.2, 401-409(Feb 1986) |
Research Org | Branch of the Institute of Chemical Physics, Chernogolovka, USSR |
Subject | 400201 -- Chemical & Physicochemical Properties ;640302 -- Atomic, Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory; DIAZO COMPOUNDS-- NMR SPECTRA;DIAZO COMPOUNDS-- STRUCTURAL CHEMICAL ANALYSIS;DIAZO COMPOUNDS-- SYNTHESIS;KETONES-- NMR SPECTRA;KETONES-- STRUCTURAL CHEMICAL ANALYSIS;KETONES-- SYNTHESIS; ACTIVATION ENERGY;CHEMICAL SHIFT;CHLORINATED AROMATIC HYDROCARBONS;CHLOROFORM;COUPLING CONSTANTS;DEUTERIUM COMPOUNDS;DMSO;HYDRATES;HYDRAZIDES;HYDRAZINE;HYPERFINE STRUCTURE;INFRARED SPECTRA;J-J COUPLING;METHYLENE CHLORIDE;MOLECULAR STRUCTURE;ORGANIC SULFUR COMPOUNDS;PROTONS;ULTRAVIOLET SPECTRA;VIBRATIONAL STATES |
Related Subject | AROMATICS;BARYONS;CHLORINATED ALIPHATIC HYDROCARBONS;COUPLING;ELEMENTARY PARTICLES;ENERGY;ENERGY LEVELS;EXCITED STATES;FERMIONS;HADRONS;HALOGENATED ALIPHATIC HYDROCARBONS;HALOGENATED AROMATIC HYDROCARBONS;HYDROGEN COMPOUNDS;INTERMEDIATE COUPLING;NITROGEN COMPOUNDS;NUCLEONS;ORGANIC CHLORINE COMPOUNDS;ORGANIC COMPOUNDS;ORGANIC HALOGEN COMPOUNDS;ORGANIC NITROGEN COMPOUNDS;ORGANIC SULFUR COMPOUNDS;SPECTRA;SULFOXIDES |
Description/Abstract | The reaction of hydrazine hydrate with 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-phthalimidoalkan-2-ones containing a substituent at the ..cap alpha.. position to the phthalimide group in the hydrocarbon chain leads to the formation of 1-diazo-3- and 1-diazo-4-(2-hydrazidophenylcarbamoyl)alkan-2-ones.^On heating in the presence of an excess of hydrazine hydrate the reaction products are 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-aminoalkan-2-ones.^Various 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-arenesulfamoyl-alkan-2-ones were synthesized in the reaction of arenesulfonyl chlorides with 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-aminoalkan-2-ones in the presence of triethylamine. |
Country of Publication | United States |
Language | English |
Format | Pages: 353-361 |
System Entry Date | 2001 May 13 |
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