Energy Citations Database

Bibliographic Citation

 
Document
For copies of Journal Articles, please contact the Publisher or your local public or university library and refer to the information in the Resource Relation field.
For copies of other documents, please see the Availability, Publisher, Research Organization, Resource Relation and/or Author (affiliation information) fields and/or Document Availability.
Title Synthesis and reactions of diazocarbonyl compounds. I. Reaction of 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-phthalimidoalkan-2-ones with hydrazine hydrate. Synthesis of 1-diazo-3-, 1-diazo-4, and 1-diazo-5-arenesulfamoyl-alkan-2-ones
Creator/Author Sipyagin, A.M. ; Kartsev, V.G.
Publication Date1986 Jul 20
OSTI IdentifierOSTI ID: 6191672
Other Number(s)CODEN: JOCYA
Resource TypeJournal Article
Resource RelationJ. Org. Chem. USSR (Engl. Transl.) ; Vol/Issue: 22:2; Translated from Zh. Org. Khim.; 22: No.2, 401-409(Feb 1986)
Research OrgBranch of the Institute of Chemical Physics, Chernogolovka, USSR
Subject400201 -- Chemical & Physicochemical Properties ;640302 -- Atomic, Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory; DIAZO COMPOUNDS-- NMR SPECTRA;DIAZO COMPOUNDS-- STRUCTURAL CHEMICAL ANALYSIS;DIAZO COMPOUNDS-- SYNTHESIS;KETONES-- NMR SPECTRA;KETONES-- STRUCTURAL CHEMICAL ANALYSIS;KETONES-- SYNTHESIS; ACTIVATION ENERGY;CHEMICAL SHIFT;CHLORINATED AROMATIC HYDROCARBONS;CHLOROFORM;COUPLING CONSTANTS;DEUTERIUM COMPOUNDS;DMSO;HYDRATES;HYDRAZIDES;HYDRAZINE;HYPERFINE STRUCTURE;INFRARED SPECTRA;J-J COUPLING;METHYLENE CHLORIDE;MOLECULAR STRUCTURE;ORGANIC SULFUR COMPOUNDS;PROTONS;ULTRAVIOLET SPECTRA;VIBRATIONAL STATES
Related SubjectAROMATICS;BARYONS;CHLORINATED ALIPHATIC HYDROCARBONS;COUPLING;ELEMENTARY PARTICLES;ENERGY;ENERGY LEVELS;EXCITED STATES;FERMIONS;HADRONS;HALOGENATED ALIPHATIC HYDROCARBONS;HALOGENATED AROMATIC HYDROCARBONS;HYDROGEN COMPOUNDS;INTERMEDIATE COUPLING;NITROGEN COMPOUNDS;NUCLEONS;ORGANIC CHLORINE COMPOUNDS;ORGANIC COMPOUNDS;ORGANIC HALOGEN COMPOUNDS;ORGANIC NITROGEN COMPOUNDS;ORGANIC SULFUR COMPOUNDS;SPECTRA;SULFOXIDES
Description/Abstract The reaction of hydrazine hydrate with 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-phthalimidoalkan-2-ones containing a substituent at the ..cap alpha.. position to the phthalimide group in the hydrocarbon chain leads to the formation of 1-diazo-3- and 1-diazo-4-(2-hydrazidophenylcarbamoyl)alkan-2-ones.^On heating in the presence of an excess of hydrazine hydrate the reaction products are 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-aminoalkan-2-ones.^Various 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-arenesulfamoyl-alkan-2-ones were synthesized in the reaction of arenesulfonyl chlorides with 1-diazo-3-, 1-diazo-4-, and 1-diazo-5-aminoalkan-2-ones in the presence of triethylamine.
Country of PublicationUnited States
LanguageEnglish
FormatPages: 353-361
System Entry Date2001 May 13

Top