Bibliographic record and links to related information available from the Library of Congress catalog.
Note: Contents data are machine generated based on pre-publication provided by the publisher. Contents may have variations from the printed book or be incomplete or contain other coding.
Contents Preface ix Acknowledgements xi 1. General Introduction 2. Alkyl- and Arylcarbodiimides 2.1. Introduction 2.2. Synthesis of Alkyl- and Arylcarbodiimides 2.2.1. From Thioureas, Isothioureas and Selenoureas . 2.2.2. By Dehydration of Ureas 2.2.3. From Isocyanates 2.2.3.1. By Catalytic Conversion 2.2.3.2. By Aza-Wittig Reactions 2.2.3.3. From Phosphoramidates 2.2.4. From Cyanamides 2.2.5. By Nitrene Rearrangement 2.2.6. From Haloformamidines or Carbonimidoyl Dihalides 2.2.7. By Thermolysis Reactions 2.2.8. By Other Methods 2.2.9. References 2.3. Reactions of Alkyl- and Arylcarbodiimides 2.3.1. Oligomerization and Polymerization 2.3.2. Cycloaddition Reactions 2.3.2.1. [2+2] Cycloaddition Reactions Across C=N Bonds 2.3.2.2. [2+2] Cycloaddition Reactions Across C-C Multiple Bonds . 2.3.2.3. [2+2] Cycloaddition reactions Across Other Bonds 2.3.2.4. [2+3] Cycloaddition Reactions 2.3.2.5. [2+4] Cycloaddition Reactions 2.3.3. Reaction of Ylides with Carbodiimides 2.3.4. Insertion Reactions 2.3.5. Nucleophilic Reactions 2.3.5.1. Reactions with Water, Alcohols and Phenols 2.3.5.2. Reactions with Carboxylic and Inorganic Acids 2.3.5.3. Reactions with H2S, H 2 Se, Thioalcohols and Thiophenols 2.3.5.4. Reactions with Ammonia, Amines, Amine Derivatives and Azides 2.3.6. Heterocycles from Carbodiimides 2.3.7. Use of Carbodiimides in Condensation Reactions 2.3.7.1. Mediation of Esterification of Acids 2.3.7.2. Formation of ?-Lactams, Peptides and Oligonucleotides 2.3.7.3. As Catalysts in the Formation of Polyamides 2.3.8. Other Reactions 2.3.9. References 3. Unsaturated Carbodiimides 3.1. Introduction 3.2. Synthesis of Unsaturated Carbodiimides 3.2.1. From Thioureas 3.2.2. From Unsaturated Isocyanates 3.2.3. From Unsaturated Iminophosphoranes and Isocyanates or Isothiocyanates 3.2.4. By Other Methods 3.3. Reactions of Unsaturated Carbodiimides 3.3.1. Polymerization Reactions. 3.3.2. Cycloaddition Reactions 3.3.3. Other Reactions 3.4. References 4. Halogenated Carbodiimides 4.1. Introduction 4.2. Synthesis of Halogenated Carbodiimides 4.2.1. From à-Haloisocyanates 4.2.2. By Halogenation of Carbodiimides 4.2.3. From Carbonimidoyl Dichlorides or Imidoyl Chlorides 4.2.4. By Other Methods 4.3. Reactions of Halogenated Carbodiimides 4.3.1. Cycloaddition Reactions 4.3.2. Nucleophilic Reactions 4.3.3. Other Reactions 4.4. References 5. Acyl-, Thioacyl- and Imidoylcarbodiimides. 5.1. Introduction 5.2. Synthesis of Acyl-, Thioacyl- and Imidoylcarbodiimides 5.2.1. From Thioureas 5.2.2. From Ureas 5.2.3. From Isocyanates 5.2.4. From Chloroformamidines or Carbonimidoyl Dichlorides 5.2.5. From Cyanamides 5.2.6. From Other Carbodiimides 5.2.7. By Other Methods 5.3. Reactions of Acyl-, Thioacyl- and Imidoylcarbodiimides 5.3.1. Cycloaddition Reactions 5.3.2. Other Reactions 5.4. References 6. Silicon Substituted Carbodiimides 6.1. Introduction 6.2. Synthesis of Silicon Substituted Carbodiimides 6.2.1. From Cyanamides 6.2.2. From Ureas 6.2.3. From Isocyanates and Isothiocyanates 6.2.4. From Silylamines 6.2.5. From Other Carbodiimides 6.2.6. By Other Methods 6.3. Reactions of Silcon Substituted Carbodiimides 6.3.1. Oligomerization Reactions 6.3.2. Cycloaddition Reactions 6.3.3. Other Reactions 6.4. References 7. Nitrogen Substituted Carbodiimides 7.1. Introduction 7.2. Synthesis of Nitrogen Substituted Carbodiimides 7.3. Reactions of Nitrogen Substituted Carbodiimides 7.4. References 8. Phosphorus Substituted Carbodiimides 8.1. Introduction 8.2. Synthesis of Phosphorus Substituted Carbodiimides 8.2.1. From Thioureas 8.2.2. From Iminophosphoranes 8.2.3. From Carbonimidoyl Dichlorides 8.2.4. From Cyanamides 8.2.5. From Other Carbodiimides 8.3. Reactions of Phosphorus Substituted Carbodiimides 8.4. References 9. Sulfur Substituted Carbodiimides 9.1. Introduction 9.2. Synthesis of Sulfur Substituted Carbodiimides 9.2.1. From Thioureas or Ureas 9.2.2. From Carbonimidoyl Dichlorides or Imidoyl Chlorides 9.2.3. By Fragmentation Reactions 9.2.4. From Cyanamides 9.2.5. From Other Carbodiimides 9.2.6. By Other Methods 9.3. Reactions of Sulfur Substituted Carbodiimides 9.4. References 10. Metal Substituted Carbodiimides 10.1. Introduction 10.2. Synthesis of Metal Substituted Carbodiimides 10.2.1. From Cyanamides 10.2.2. From Isocyanates 10.2.3. From Other Carbodiimides 10.2.4. By Other Methods 10.2.5. Synthesis of Metal Carbodiimide Adducts 10.3. Reactions of Metal Substituted Carbodiimides 10.4. References 11. Cyclic Carbodiimides 11.1. Introduction 11.2. Synthesis of Cyclic Carbodiimides 11.2.1. From Thioureas 11.2.2. By Nitrene Rearrangement 11.2.3. From Bisaryliminophosphoranes and Isocyanates or Isothiocyanates 11.3. Reactions of Cyclic Carbodiimides 11.3.1. Nucleophilic Reactions 11.3.2. Oligomerization Reactions 11.3.3. Cycloadiition Reactions 11.3.4. Other Reactions 11.4. References 12. Polymeric Carbodiimides 12.1. Introduction 12.2. Isocyanate Terminated Polycarbodiimides 12.3. Oligomeric Carbodiimides 12.4. Linear Homopolymers via Addition Across the C=N Bond 12.5. Polymers Derived from Unsaturated Carbodiimides 12.6. Linear Polymers 12.7. Crosslinked Homo- and Copolymers 12.8. Modification of Polymers with Carbodiimides 12.8.1. Crosslinking of Polymers 12.8.2. Modification of Linear Polymers 12.8.3. Modification of Crosslinked Polymers 13. Applications of Carbodiimides 13.1. Introduction 13.2. Application in Organic Synthesis 13.3. Biological Applications 13.3.1. Antibiotic Synthesis 13.3.2. Protein and DNA Synthesis 13.3.3. Modification of Proteins 13.3.4. Crosslinking of Proteins 13.3.5. Carbodiimides in Pharmaceuticals, Herbicides and Pesticides 13.4. Polymer and Industrial Applications 13.4.1. Use in Polymer Synthesis 13.4.2. Use in Polymer Applications 13.4.3. Polymer Modifications 13.4.4. Carbodiimides as Stabilizers 13.4.5. Carbodiimides in Dye Applications 13.4.6. Other Applications 13.5. References
Library of Congress Subject Headings for this publication:
Carbodiimides.