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Chemical Datasheet

CYANAMIDE

Chemical Identifiers | Hazards | Response Recommendations | Physical Properties | Regulatory Information | Alternate Chemical Names

Chemical Identifiers

UN/NA Number - The United Nations-North America number (also called UN number or DOT number). 4-digit number identifying an individual chemical or group of chemicals with similar characteristics. Required on shipping papers; often shown on placards or labels. This numbering system was developed by the U.S. Department of Transportation, and then became the UN standard system for classifying hazardous materials.

CAS Number - Chemical Abstracts Service registry number. Unique identification number assigned to this chemical by the American Chemical Society.

CHRIS Code - 3-letter code used by the U.S. Coast Guard to identify individual chemicals included in its CHRIS (Chemical Hazards Response Information System) manual.

DOT Hazard Label - U.S. Department of Transportation hazard warning label for the chemical (such as flammable liquid or corrosive). This label must be displayed on shipped packages, railroad tank cars, and tank trucks according to specifications described in 49 CFR 172.

NFPA 704 - Text description of the diamond-shaped placard, which contains codes indicating the level of the chemical's health, flammability, and reactivity hazards, along with special hazards such as water- and air-reactivity. (The NFPA 704 diamond is also shown at the top of the datasheet.) See a guide to the NFPA diamond.

General Description - Brief description of the chemical's general appearance, behavior, and hazardousness.

List of data sources.
UN/NA Number CAS Number CHRIS Code DOT Hazard Label
none
  • 420-04-2
none data unavailable
NFPA 704: data unavailable
General Description
Colorless deliquescent crystals. Mp: 45ºC; bp: 260ºC. Density: 1.282 g cm-3. Quite soluble in water (77 g / 100 g solution at 15ºC). Soluble in butanol, methyl ethyl ketone, ethyl acetate, alcohols, phenols, amines, ethers. Note: The term “cyanamide” is also used to refer to the important compound calcium cyanamide, which is a different chemical.

Hazards

Reactivity Alerts - Special alerts if the chemical is especially reactive (see list of reactivity alerts).

Air & Water Reactions - Special alerts if the chemical reacts with air, water, or moisture.

Fire Hazard - Description of the chemical's fire hazards (such as flammability, explosion risk, or byproducts that may evolve if the chemical is burned).

Health Hazard - Description of the chemical's health hazards (such as toxicity, flammability, or corrosivity).

Reactivity Profile - Description of the chemical's potential reactivity with other chemicals, air, and water. Also includes any other intrinsic reactive hazards (such as polymerizable or peroxidizable).

Reactive Groups - List of reactive groups that the chemical is assigned to, based on its known chemistry. Reactive groups are categories of chemicals that react in similar ways because their chemical structures are similar. Reactive groups are used to predict reactivity when you add a chemical to MyChemicals. Read more about reactive groups.

List of data sources.
Reactivity Alerts
Air & Water Reactions
No rapid reaction with air Slow reaction with water or mositure in air
Fire Hazard
No information available.
Health Hazard
Exposure Routes: inhalation, skin absorption, ingestion, skin and/or eye contact

Symptoms: Irritation eyes, skin, respiratory system; eye, skin burns; miosis, salivation, lacrimation (discharge of tears), twitching; Antabuse-like effects

Target Organs: Eyes, skin, respiratory system, central nervous system (NIOSH, 2003)
Reactivity Profile
CYANAMIDE is the amide of cyanic acid. Non-flammable but combustible (flash point: 140ºC). Decomposes on warming above 49ºC. Emits toxic fumes of CN- and NOx when heated to decomposition or on contact with acids or acid fumes (Hazardous Chemicals Desk Reference, p. 353 (1987)). Contact with moisture, acids or bases may cause a violent reaction at temperatures above about 40ºC. Dry solid may polymerize at temperatures above 122ºC. Rapid or explosive polymerization may occur during the evaporation of aqueous solutions. Reacts explosively with strong oxidizing agents and strong reducing agents. Attacks various metals (International Chemical Safety Card).
Belongs to the Following Reactive Group(s)

Response Recommendations

Firefighting - Response recommendations if the chemical is on fire (or near a fire).

Non-Fire Response - Response recommendations if the chemical isn't on fire (or near a fire).

Protective Clothing - Recommendations for protective gear and, in some cases, a table of breakthrough times for protective materials.

First Aid - Recommended first aid treatment for people exposed to the chemical.

List of data sources.
Firefighting
No information available.
Non-Fire Response
No information available.
Protective Clothing
Skin: Wear appropriate personal protective clothing to prevent skin contact.

Eyes: Wear appropriate eye protection to prevent eye contact.

Wash skin: The worker should immediately wash the skin when it becomes contaminated.

Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premise.

Provide: Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substance; this is irrespective of the recommendation involving the wearing of eye protection. Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2003)
First Aid
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.

Skin: If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.

Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible.

Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2003)

Physical Properties

This section contains physical properties, flammability limits, and toxic thresholds for this chemical (see definitions of each property). More property data is available for common chemicals.

Guide to toxic levels of concern (AEGLs, ERPGs, TEELs, and IDLH).

List of data sources.
Molecular Formula:
  • NH2CN
Flash Point: 286.0 ° F (NIOSH, 2003)
Lower Explosive Limit: data unavailable
Upper Explosive Limit: data unavailable
Autoignition Temperature: data unavailable
Melting Point: 113.0 ° F (NIOSH, 2003)
Vapor Pressure: data unavailable
Vapor Density: data unavailable
Specific Gravity: 1.28 (NIOSH, 2003)
Boiling Point: 500.0 ° F at 760 mm Hg (Decomposes) (NIOSH, 2003)
Molecular Weight: 42.1 (NIOSH, 2003)
Water Solubility: 78.0 % at 59° F (NIOSH, 2003)
AEGL: data unavailable
ERPG: data unavailable
TEEL-1 TEEL-2 TEEL-3
6.0 mg/m3 30.0 mg/m3 35.0 mg/m3
(SCAPA, 2008)
IDLH: data unavailable

Regulatory Information

Regulatory Names - Names under which this chemical is regulated under several U.S. federal laws: CAA (Clean Air Act of 1990), CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act of 1980, also known as Superfund), EPCRA (Emergency Planning and Community Right-to-Know Act, also known as SARA Title III), and RCRA (Resource Conservation and Recovery Act of 1976).

CAA RMP - Indicates whether this chemical is regulated under Section 112(r) of the Clean Air Act, which lists about 100 toxic, flammable, or explosive hazardous substances. (Section 112(r) mandates the Risk Management Plan regulations.) For listed chemicals, the Threshold Quantity (from 40 CFR 68) is also shown. Facilities that use more than the threshold quantity of a listed chemical in a process are subject to the CAA accidental release prevention provisions.

CERCLA - Indicates whether this chemical is listed as a hazardous substance under CERCLA. For listed chemicals, the Reportable Quantity (from 40 CFR 302) is also shown. Facilities that spill more than the reportable quantity of a listed chemical must report it to federal, state, and local governments.

EHS (EPCRA 302) - Indicates whether this chemical is listed as an Extremely Hazardous Substance under Section 302 of EPCRA. For listed chemicals, the Threshold Planning Quantity (from 40 CFR 355) is also shown. Facilities that store more than the threshold quantity of an EHS chemical must meet the reporting, community right-to-know, and emergency planning requirements of EPCRA.

TRI (EPCRA 313) - Indicates whether this chemical is listed as a toxic chemical under Section 313 (Toxics Release Inventory) of EPCRA. Facilities that manufacture, store, or use significant amounts of Section 313 chemicals may be required to submit annual reports about any releases into the environment (see 40 CFR 372).

RCRA Chemical Code - 4-character identification code assigned to this substance under RCRA.
Regulatory Names: none
CAA RMP: Not a regulated chemical.
CERCLA: Not a regulated chemical.
EHS (EPCRA 302): Not a regulated chemical.
TRI (EPCRA 313): Not a regulated chemical.
RCRA Chemical Code: none

Alternate Chemical Names

This section provides a listing of alternate names for this chemical, including trade names, synonyms, and foreign names.