David L. Bryce
Laboratory of Chemical Physics
National Institute of Diabetes and Digestive and Kidney Diseases
National Institutes of Health
Building 5, Room B1-27
9000 Rockville Pike
Bethesda, MD 20892
Tel.: 301-496-7098
Fax: 301-496-0825
E-mail: dbryce@speck.niddk.nih.gov
RESEARCH INTERESTS
Experimental and theoretical aspects of developing improved methods for
accurate biomolecular structure determination via NMR spectroscopy; solid-state
NMR spectroscopy of low-frequency quadrupolar nuclei; quantum chemical calculation
and interpretation of NMR interaction tensors.
EDUCATION
Ph.D. in Chemistry, Dalhousie University, Halifax, Canada (2002).
Supervisor: Prof. R. E. Wasylishen
Thesis entitled "Insights from Across the Periodic Table into NMR Chemical
Shift, Electric Field Gradient, and Spin-Spin Coupling Tensors: New Information
from Solid-State NMR and Computational Chemistry"
B. Sc. (Hons) in Chemistry, Queen's University, Kingston, Canada (1998).
Honours project supervisor: Prof. R. P. Lemieux
RELEVANT EXPERIENCE AND ACTIVITIES
Member, Chemical Institute of Canada
Member, Canadian Society for Chemistry
Natural Sciences and Engineering Research Council (NSERC) of Canada Post-Doctoral
Fellow
Supervisor: Dr. Ad Bax
National Institutes of Health, Bethesda, MD, USA, 2003-present.
Post-Doctoral Fellow
Supervisor: R. E. Wasylishen
Department of Chemistry, University of Alberta, Canada, 2002.
Five-Time External User at the High-Field Magnetic Resonance Facility,
Environmental Molecular Sciences Laboratories
Pacific Northwest National Laboratories, Richland, WA, USA, 2001-2002.
SELECTED HONOURS AND AWARDS
NIH Fellows Award for Research Excellence,
2004.
CAGS/UMI Distinguished Dissertation Award (Engineering,
Medical Sciences, Natural Sciences), 2003.
NSERC Doctoral Prize, 2003.
Kenneth T. Leffek Prize for Best Ph. D. Thesis in Chemistry, Dalhousie
University, 2002.
NSERC of Canada Post-Doctoral Fellowship Recipient, 2002.
NSERC of Canada Post-Graduate Scholarship Recipient, 1998-2002.
Izaak Walton Killam Scholar, 1998-2002.
Walter C. Sumner Foundation Scholar, 2000-2002.
Canadian Society for Chemistry Medal, Queen's University, 1998.
PUBLICATIONS
Publications
with the Bax Group
Previous Publications:
23. David L. Bryce, Klaus Eichele, and Roderick E. Wasylishen "An 17O
NMR and Quantum Chemical Study of Monoclinic and Orthorhombic Polymorphs
of Triphenylphosphine Oxide" Inorg. Chem., 2003, 42, 5085-5096.
22. David L. Bryce and Roderick E. Wasylishen "Microwave Spectroscopy
and Nuclear Magnetic Resonance Spectroscopy - What is the Connection?" Acc.
Chem. Res., 2003, 36, 327-334.
21. Michelle A. M. Forgeron, David L. Bryce, Roderick E. Wasylishen,
and Roland Roesler "A Solid-State Multinuclear Magnetic Resonance Investigation
of Hexamethylborazine" J. Phys. Chem. A, 2003, 107, 726-735.
20. David L. Bryce and Roderick E. Wasylishen "Evaluation of the Influence
of Anisotropic Indirect Nuclear Spin-Spin Coupling Tensors on Effective
Residual Dipolar Couplings for Model Peptides" J. Biomol. NMR, 2003, 25,
73-78.
19. Roderick E. Wasylishen and David L. Bryce "A Revised Experimental
Absolute Magnetic Shielding Scale for Oxygen" J. Chem. Phys., 2002, 117,
10061-10066.
18. Juha Vaara, Jukka Jokisaari, Roderick E. Wasylishen, and David L.
Bryce "Spin-Spin Coupling Tensors as Determined by Experiment and Computational
Chemistry" Prog. Nucl. Magn. Reson. Spectrosc., 2002, 41, 233-304.
17. David L. Bryce and Roderick E. Wasylishen "A 95Mo and
13C Solid-State NMR and Relativistic DFT Investigation of Mesitylenetricarbonylmolybdenum(0)
- A Typical Transition Metal Piano-Stool Complex" Phys. Chem. Chem. Phys.
2002, 4, 3591-3600.
16. David L. Bryce and Roderick E. Wasylishen "Insight into the Structure
of Silver Cyanide from 13C and 15N Solid-State NMR
Spectroscopy" Inorg. Chem. 2002, 41, 4131-4138.
15. David L. Bryce and Roderick E. Wasylishen "Interpretation of Indirect
Nuclear Spin-Spin Coupling Tensors for Polyatomic Xenon Fluorides and Group
17 Fluorides: Results from Relativistic Density Functional Calculations"
Inorg. Chem. 2002, 41, 3091-3101.
14. David L. Bryce, Roderick E. Wasylishen, Jochen Autschbach, and Tom
Ziegler "Periodic Trends in Indirect Nuclear Spin-Spin Coupling Tensors:
Relativistic Density Functional Calculations for Interhalogen Diatomics"
J. Am. Chem. Soc. 2002, 124, 4894-4900.
13. David L. Bryce and Roderick E. Wasylishen "Ab Initio Characterization
of Through-Space Indirect Nuclear Spin-Spin Coupling Tensors for Fluorine-X
(X=F,C,H) Spin Pairs" J. Mol. Struct. 2002, 602-603, 463-472.
12. David L. Bryce, Guy M. Bernard, Myrlene Gee, Michael D. Lumsden,
Klaus Eichele, and Roderick E. Wasylishen "Practical Aspects of Modern
Routine Solid-State Multinuclear Magnetic Resonance Spectroscopy: One-Dimensional
Experiments" Can. J. Anal. Sci. Spect. 2001, 46, 46-82.
11. David L. Bryce and Roderick E. Wasylishen "The First Chromium-53
Solid-State Nuclear Magnetic Resonance Spectra of Diamagnetic Chromium(0)
and Chromium(VI) Compounds" Phys. Chem. Chem. Phys. 2001, 3, 5154-5157.
10. David L. Bryce, Myrlene Gee, and Roderick E. Wasylishen "High-Field
Chlorine NMR Spectroscopy of Solid Organic Hydrochloride Salts: A Sensitive
Probe of Hydrogen Bonding Environment" J. Phys. Chem. A 2001, 105, 10413-10421
.
9. David L. Bryce and Roderick E. Wasylishen "Modeling 2h
Jiso(N, N) in Nucleic Acid Base Pairs: Ab Initio Characterization
of the 2h J(N, N) Tensor in the Methyleneimine Dimer
as a Function of Hydrogen Bond Geometry" J. Biomol. NMR 2001, 19, 371-375.
8. David L. Bryce, Roderick E. Wasylishen, and Myrlene Gee "Characterization
of Tricoordinate Boron Chemical Shift Tensors: Definitive High-Field Solid-State
NMR Evidence for Anisotropic Boron Shielding" J. Phys. Chem. A 2001, 105,
3633-3640.
7. David L. Bryce and Roderick E. Wasylishen "Ab Initio Calculations
of NMR Parameters For Diatomic Molecules: An Exercise In Computational Chemistry"
J. Chem Educ. 2001, 78, 124-133.
6. David L. Bryce and Roderick E. Wasylishen "Symmetry Properties of
Indirect Nuclear Spin-Spin Coupling Tensors: First Principles Results for
ClF3 and OF2" J. Am. Chem. Soc. 2000, 122, 11236-11237.
5. Roderick E. Wasylishen, David L. Bryce, Corey J. Evans, and Michael
C. L. Gerry "Hyperfine Structure in the Rotational Spectrum of GaF.
A Comparison of Experimental and Calculated Spin-Rotation and Electric
Field Gradient Tensors" J. Mol. Spectrosc. 2000, 204, 184-194.
4. David L. Bryce and Roderick E. Wasylishen "Dipolar-Chemical Shift
and Rotational Resonance 13C NMR Studies of the Carboxyl-Methylene
Spin Pair in Solid Phenylacetic Acid and Potassium Hydrogen Bisphenylacetate"
J. Phys. Chem. A 2000, 104, 7700-7710.
3. David L. Bryce and Roderick E. Wasylishen "Indirect Nuclear Spin-Spin
Coupling Tensors in Diatomic Molecules: A Comparison of Results Obtained
by Experiment and First Principles Calculations" J. Am. Chem. Soc. 2000,
122, 3197-3205.
2. David L. Bryce and Roderick E. Wasylishen "Rotational Resonance in
Solid State NMR", an invited refereed contribution to the Encyclopedia of
Spectroscopy and Spectrometry, Lindon, J. C., Tranter, G. E.; Holmes, J.
L.; Academic Press Ltd.; 2000, pp 2136-2144.
1. David L. Bryce and Roderick. E. Wasylishen. "Beryllium-9 NMR Study
of Solid Bis(2,4-pentanedionato-O,O')beryllium and Theoretical Studies of
9Be Electric Field Gradient and Chemical Shielding Tensors.
The First Evidence for Anisotropic Beryllium Shielding" J. Phys. Chem. A
1999, 103, 7364-7372.
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