Energy Citations Database

Bibliographic Citation

 
Document
For copies of Journal Articles, please contact the Publisher or your local public or university library and refer to the information in the Resource Relation field.
For copies of other documents, please see the Availability, Publisher, Research Organization, Resource Relation and/or Author (affiliation information) fields and/or Document Availability.
Title Synthesis of tris(triphenylsiloxy)yttrium and derivatives: Crystal structure of (Y(OSiPh sub 3 ) sub 3 (THF sub 3 ))ter dot THF
Creator/Author McGeary, M.J. ; Coan, P.S. ; Folting, K. ; Streib, W.E. ; Caoulton, K.G. (Indiaa Univ., Bloomington (USA))
Publication Date1989 Aug 23
OSTI IdentifierOSTI ID: 5043409
Other Number(s)ISSN0020-1669; CODEN: INOCA
Resource TypeJournal Article
Resource RelationInorganic Chemistry ; Vol/Issue: 28:17; DOE Project
Subject400201 -- Chemical & Physicochemical Properties ;400202 -- Isotope Effects, Isotope Exchange, & Isotope Separation; AROMATICS-- CHEMICAL PREPARATION;OXYGEN COMPOUNDS-- CHEMICAL PREPARATION;SILICON COMPOUNDS-- CHEMICAL PREPARATION;YTTRIUM COMPLEXES-- CHEMICAL PREPARATION; CARBON 13;MOLECULAR STRUCTURE;NMR SPECTRA;PROTONS
Related SubjectBARYONS;CARBON ISOTOPES;COMPLEXES;ELEMENTARY PARTICLES;EVEN-ODD NUCLEI;FERMIONS;HADRONS;ISOTOPES;LIGHT NUCLEI;NUCLEI;NUCLEONS;ORGANIC COMPOUNDS;SPECTRA;STABLE ISOTOPES;SYNTHESIS;TRANSITION ELEMENT COMPLEXES
Description/Abstract The synthesis of (Y(OSiPh{sub 3}){sub 3}){sub n} (1) has been accomplished by the reaction of Y(N(SiMe{sub 3}){sub 2}){sub 3} with 3 equivalents of Ph{sub 3}SiOH in toluene.^Two monomeric Lewis base adducts were also formed.^The product 1 was formed as a colorless, feather-like solid, and {sup 1}H and {sup 13}C NMR spectra gave data consistent with the structure of this compound as an aggregate presumably involving bridging Ph{sub 3}SiO{sup {minus}} ligands.^The x-ray structure of the compounds is also reported.
Country of PublicationUnited States
LanguageEnglish
FormatPages: 3283-3284
System Entry Date2001 May 13

Top