Bibliographic Citation
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Title | Synthesis of tris(triphenylsiloxy)yttrium and derivatives: Crystal structure of (Y(OSiPh sub 3 ) sub 3 (THF sub 3 ))ter dot THF |
Creator/Author | McGeary, M.J. ; Coan, P.S. ; Folting, K. ; Streib, W.E. ; Caoulton, K.G. (Indiaa Univ., Bloomington (USA)) |
Publication Date | 1989 Aug 23 |
OSTI Identifier | OSTI ID: 5043409 |
Other Number(s) | ISSN0020-1669; CODEN: INOCA |
Resource Type | Journal Article |
Resource Relation | Inorganic Chemistry ; Vol/Issue: 28:17; DOE Project |
Subject | 400201 -- Chemical & Physicochemical Properties ;400202 -- Isotope Effects, Isotope Exchange, & Isotope Separation; AROMATICS-- CHEMICAL PREPARATION;OXYGEN COMPOUNDS-- CHEMICAL PREPARATION;SILICON COMPOUNDS-- CHEMICAL PREPARATION;YTTRIUM COMPLEXES-- CHEMICAL PREPARATION; CARBON 13;MOLECULAR STRUCTURE;NMR SPECTRA;PROTONS |
Related Subject | BARYONS;CARBON ISOTOPES;COMPLEXES;ELEMENTARY PARTICLES;EVEN-ODD NUCLEI;FERMIONS;HADRONS;ISOTOPES;LIGHT NUCLEI;NUCLEI;NUCLEONS;ORGANIC COMPOUNDS;SPECTRA;STABLE ISOTOPES;SYNTHESIS;TRANSITION ELEMENT COMPLEXES |
Description/Abstract | The synthesis of (Y(OSiPh{sub 3}){sub 3}){sub n} (1) has been accomplished by the reaction of Y(N(SiMe{sub 3}){sub 2}){sub 3} with 3 equivalents of Ph{sub 3}SiOH in toluene.^Two monomeric Lewis base adducts were also formed.^The product 1 was formed as a colorless, feather-like solid, and {sup 1}H and {sup 13}C NMR spectra gave data consistent with the structure of this compound as an aggregate presumably involving bridging Ph{sub 3}SiO{sup {minus}} ligands.^The x-ray structure of the compounds is also reported. |
Country of Publication | United States |
Language | English |
Format | Pages: 3283-3284 |
System Entry Date | 2001 May 13 |
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