202003huaouy0journalOriginalHuang, Z.[Zhongqi]Ouyang, G.[Gangfeng]Liu, F.[Faqiang]Xu, Z.[Zhuyuan]Zhang, X.[Xiliang]Zhang, W.[Weiqing]J. Chem. Eng. Data20032003-11-17Solid and Liquid Phase Equilibria in Mixtures of 1,8-Cineole with Phenol, Cyclohexanol, and an n-AlkanolSolid-liquid phase diagrams have been constructed for 1,8-cineole with phenol or cyclohexanol or an n-alkanol. Solid addition compounds with the empirical formulas C10H18O*C6H5OH and C10H18O*C6H11OH were formed. Compound formation is attributed to hydrogen bonding. No solid addition compounds form in (1,8-cineole + methanol, + ethanol, + 1-propanol, or + 1-butanol).(Solid + liquid) equilibriumSolid-compound18-cineole481521-152311,8-cineoleC10H18O1Commercial source1992Gas chromatography2Fractional distillation299.724Gas chromatography2phenolC6H6O1Commercial source199.53Gas chromatography2Fractional distillation299.674Gas chromatography3cyclohexanolC6H12O1Commercial source199.53Gas chromatography2Fractional distillation299.754Gas chromatography4methanolCH4O1Commercial source199.53Gas chromatography2Fractional distillation299.954Gas chromatography5ethanolC2H6O1Commercial source199.53Gas chromatography2Fractional distillation299.974Gas chromatography61-propanolC3H8O1Commercial source199.53Gas chromatography2Fractional distillation299.984Gas chromatography71-butanolC4H10O1Commercial source199.53Gas chromatography2Fractional distillation299.994Gas chromatography11Principal objective of the workRDCTRC11/14/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa1101.341274.42521Principal objective of the workRDCTRC11/14/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa1101.341313.65531Principal objective of the workRDCTRC11/14/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa1101.341298.3541Principal objective of the workRDCTRC11/14/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa1101.341175.49551Principal objective of the workRDCTRC11/14/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa1101.341159.12561Principal objective of the workRDCTRC11/14/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa1101.341147.09571Principal objective of the workRDCTRC11/14/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa1101.341184.4352111Principal objective of the workJCEJCE7/27/20031Eutectic composition: mole fractionDerived from phase diagram analysis2CrystalDirect value, XCrystal1Crystal of intercomponent compound 1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561.2832111Principal objective of the workJCEJCE7/27/20031Eutectic temperature, KDerived from phase diagram analysisCrystalDirect value, XCrystal1Crystal of intercomponent compound 1LiquidAir at 1 atmospherePressure, kPaCrystal101.3256125642111Principal objective of the workJCEJCE7/27/20031Eutectic composition: mole fractionDerived from phase diagram analysis2Crystal of intercomponent compound 1Direct value, XCrystal of intercomponent compound 1Crystal2LiquidAir at 1 atmospherePressure, kPaCrystal of intercomponent compound 1101.32561.62532111Principal objective of the workJCEJCE7/27/20031Eutectic temperature, KDerived from phase diagram analysisCrystal of intercomponent compound 1Direct value, XCrystal of intercomponent compound 1Crystal2LiquidAir at 1 atmospherePressure, kPaCrystal of intercomponent compound 1101.32561244.642111Principal objective of the workJCEJCE7/27/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal2Pressure, kPa101.341Mole fraction2Liquid1.650441252.5151.700341266.3951.749641278.3551.799641288.6351.849741297.1251.899941304.1551.949941309.451151313.6552111Principal objective of the workJCEJCE8/4/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal of intercomponent compound 1Pressure, kPa101.341Mole fraction2Liquid1.300241258.0151.350541262.7151.399641266.8351.449841269.7351.500241270.4451.549941266.4951.599841254.9852111Principal objective of the workJCEJCE8/4/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa101.341Mole fraction2Liquid1001274.4251.050431271.6351.099831268.6851.149741265.4951.200241262.1351.249741258.3753111Principal objective of the workJCEJCE7/27/20031Eutectic composition: mole fractionDerived from phase diagram analysis3CrystalDirect value, XCrystal1Crystal of intercomponent compound 1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561.44233111Principal objective of the workJCEJCE7/27/20031Eutectic temperature, KDerived from phase diagram analysisCrystalDirect value, XCrystal1Crystal of intercomponent compound 1LiquidAir at 1 atmospherePressure, kPaCrystal101.3256124943111Principal objective of the workJCEJCE7/27/20031Eutectic composition: mole fractionDerived from phase diagram analysis3Crystal of intercomponent compound 1Direct value, XCrystal of intercomponent compound 1Crystal3LiquidAir at 1 atmospherePressure, kPaCrystal of intercomponent compound 1101.32561.75633111Principal objective of the workJCEJCE7/27/20031Eutectic temperature, KDerived from phase diagram analysisCrystal of intercomponent compound 1Direct value, XCrystal of intercomponent compound 1Crystal3LiquidAir at 1 atmospherePressure, kPaCrystal of intercomponent compound 1101.32561222.243111Principal objective of the workJCEJCE7/27/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal3Pressure, kPa101.341Mole fraction3Liquid1.767541227.0551.799541239.7651.849741257.7151.900141273.1851.949941286.3451151298.353111Principal objective of the workJCEJCE8/4/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal of intercomponent compound 1Pressure, kPa101.341Mole fraction3Liquid1.44964125251.4741255.551.499941257.3351.5441255.551.550341254.6851.600541248.9851.650241241.6751.741232.9551.74941223.4753111Principal objective of the workJCEJCE8/4/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa101.341Mole fraction3Liquid1001274.4251.050431272.7351.100241271.0751.150741269.1151.200241266.7151.250341264.0651.302441260.7851.349841257.4551.400341253.554111Principal objective of the workJCEJCE7/27/20031Eutectic temperature, KDerived from phase diagram analysisCrystalDirect value, XCrystal4Crystal1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561175.544111Principal objective of the workJCEJCE7/27/20031Eutectic composition: mole fractionDerived from phase diagram analysis4CrystalDirect value, XCrystal4Crystal1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561.99534111Principal objective of the workJCEJCE7/27/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa101.341Mole fraction4Liquid1001274.4251.051231271.951.10541270.1751.151241268.9851.206341267.5951.253241266.2851.317241264.1551.356841262.7651.402641261.0351.451941259.3251.501741257.7451.551541256.4251.601741255.2951.651341254.1151.700441252.4651.744741250.0151.800341244.5951.850141236.1251.941222.5151.9541201.6551.970141190.5654111Principal objective of the workJCEJCE8/4/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal4Pressure, kPa101.341Mole fraction4Liquid1151175.4955111Principal objective of the workJCEJCE7/27/20031Eutectic temperature, KDerived from phase diagram analysisCrystalDirect value, XCrystal5Crystal1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561159.145111Principal objective of the workJCEJCE7/27/20031Eutectic composition: mole fractionDerived from phase diagram analysis5CrystalDirect value, XCrystal5Crystal1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561.99935111Principal objective of the workJCEJCE7/27/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa101.341Mole fraction5Liquid1001274.4251.050731272.0251.101941270.551.153141269.351.208241267.8851.260141266.451.306341264.8851.351141263.2751.401941261.4751.454141259.8551.500841258.5951.554641257.7251.599441257.1651.650941256.4151.700241255.2251.751441252.4351.801141246.9651.850241237.3751.900241221.1851.949841196.2651.974841179.3455111Principal objective of the workJCEJCE8/4/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal5Pressure, kPa101.341Mole fraction5Liquid1151159.1256111Principal objective of the workJCEJCE7/27/20031Eutectic temperature, KDerived from phase diagram analysisCrystalDirect value, XCrystal6Crystal1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561147.146111Principal objective of the workJCEJCE7/27/20031Eutectic composition: mole fractionDerived from phase diagram analysis6CrystalDirect value, XCrystal6Crystal1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561.99936111Principal objective of the workJCEJCE7/27/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa101.341Mole fraction6Liquid1001274.4251.052931271.9151.101741270.3451.152141268.9351.200741267.5651.25141266.0251.302741264.0151.352541261.8851.401841259.751.451641257.5251.50141255.651.541441254.2151.600941252.3251.649841250.6251.700241248.1151.751341244.0151.800141237.3451.850441226.2251.941209.0151.950141182.951.973941166.6556111Principal objective of the workJCEJCE8/4/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal6Pressure, kPa101.341Mole fraction6Liquid1151147.0957111Principal objective of the workJCEJCE7/27/20031Eutectic temperature, KDerived from phase diagram analysisCrystalDirect value, XCrystal7Crystal1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561184.447111Principal objective of the workJCEJCE7/27/20031Eutectic composition: mole fractionDerived from phase diagram analysis7CrystalDirect value, XCrystal7Crystal1LiquidAir at 1 atmospherePressure, kPaCrystal101.32561.98737111Principal objective of the workJCEJCE7/27/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal1Pressure, kPa101.341Mole fraction7Liquid1001274.4251.059231271.6751.102841270.1551.153141268.6251.201141267.0651.250841265.4451.303541263.6351.351741261.7151.401741259.6451.450841257.6451.501141255.4751.551341253.2751.60024125151.650641248.2651.700641245.0151.750541240.6151.798241234.7151.850441225.6151.899841213.1951.948341196.257111Principal objective of the workJCEJCE8/4/20031Solid-liquid equilibrium temperature, KVisual observationLiquidDirect value, XLiquidCrystal7Pressure, kPa101.341Mole fraction7Liquid1151184.435