Chlorine Pentafluoride. [Science. 1963]

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1: Science. 1963 Sep 13;141(3585):1039-1040. Links

Chlorine Pentafluoride.

Smith DF.

The bonding in the halogen polyfluorides is similar to that in the xenon fluorides. Since XeF(4) exists, the previously unreported ClF(5) should exist. This compound has been prepared by heating ClF(3) in the presence of fluorine at high pressure. Chlorine pentafluoride is a square pyramidal molecule. It has a lower melting point than ClF(3) and a higher vapor pressure. It is also less reactive than ClF(3).

PMID: 17739492 [PubMed - as supplied by publisher]

Bonding in Xenon Fluorides and Halogen Fluorides. [Science. 1963]
Xenon Difluoride and the Nature of the Xenon-Fluorine Bond. [Science. 1963]
The action of an arsenic pentafluoride--chlorine trifluoride complex on rats. [Toxicol Appl Pharmacol. 1962]
Xenon Fluorides: Fluorine-19 Nuclear Magnetic Resonance Spectra. [Science. 1963]
Xenon Hexafluoride: Preparation of Pure Form and Melting Point. [Science. 1964]

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