|
Environmental SRMs
NIST has many Standard
Reference Materials (SRMs) that may be useful to those in the organic
environmental community. The SRMs that are currently available are listed
in the following tables.
- Table
1. NIST Natural Matrix SRMs for the Determination of Organic Contaminants
in Environmental Samples
- Table
2. NIST Calibration Solution SRMs for the Determination of Organic
Environmental Contaminants
- Table
3. Analytes in NIST Solution SRMs for PAHs and Aliphatic Hydrocarbons
- Table
4. Analytes in NIST Calibration Solution SRMs for Polychlorinated
Biphenyl (PCB) Congeners
- Table
5. Analytes in NIST Calibration Solution SRMs for Chlorinated Pesticides
- Table
6. NIST Reference Materials (RMs) for Organic Environmental Analysis
- Table
7. NIST RMs and SRMs for Moisture Determination
For additional information
or ordering of NIST Standard Reference Materials, please contact:
Standard
Reference Materials Program
National Institute of Standards and Technology
100 Bureau Drive, Mailstop 2320
Gaithersburg, MD USA 20899-2320
Telephone (301) 975-6776
Fax (301) 948-3730
Telex TRT 197674NIST UT
If you need paper
copies of any of the following certificates, please contact the ACD Webmaster
by telephone at 301-975-3108, by facsimile at 301-926-8671, by email at
acd_webmaster@nist.gov, or by mail at NIST, 100 Bureau Drive, Stop 8390,
Gaithersburg, MD 20899-8390.
Table 1. NIST Natural Matrix SRMs for the Determination of Organic
Contaminants in Environmental Samples
SRM No. |
Title |
Date Issued |
Certified Constituents |
Reference (Noncertified) Constituents |
1580 |
Organics in Shale Oil |
1980 |
PAHs (5); Phenols (3)PANH (1) |
Phenols (6); PANH (1) |
1581 |
Polychlorinated Biphenyls in Oils |
1982 |
Aroclor 1242/1260 |
|
1582 |
Petroleum Crude Oil |
1984 |
PAHs (5); PASH (1) |
PAHs (5); Phenols (2); PANH (1) |
1588a |
Organics in Cod Liver Oil |
1998a |
PCBs (24); Pesticides (4) |
PCDDs/PCDFs (7)
PCBs (34); Pesticides (3)
|
1589a |
Polychlorinated Biphenyls in Human Serum |
in preparation |
|
|
1597 |
Complex Mixture of PAHs from Coal Tar |
1987 |
PAHs (12) |
PAHs/PASH/PANH (18) |
1648 |
Urban Particulate Matter |
1978 |
Trace elements (9) |
Trace elements (25); PAH (13) |
1649a |
Urban Dust |
1998b |
PAHs (22); PCBs (35); Pesticides (8) |
PAHs (22);
Pesticide (1, mutagenic activity);
PCDD/PCDFs (17);
Trace elements (32);
Particle size;
Total organic carbon
|
1650 |
Diesel Particulate Material |
1985 |
PAHs (5) Nitro-PAHs (1) |
PAHs (6); Nitro-PAHs (3); PAQ (1) |
1650a |
Diesel Particulate Matter |
2000 |
|
|
1939a |
Polychlorinated Biphenyls (Congeners) in River Sediment |
1998c |
PCBs (20);
Pesticides (3)
|
PCBs (4) |
1941a |
Organics in Marine Sediment |
1994 |
PAHs (23); PCBs (21) Pesticides (6) |
PAHs (14); PCBs (7); Pesticides (3) Aliphatics (17); Trace Elements
(27) |
1944 |
New York/New Jersey Waterway Sediment |
1999 |
PAHs (24); PCBs (35); Pesticides (4) Trace Elements (9) |
PAHs (32); Pesticides (7); Trace elements (20);
PCDDs/PCDFs (17)
Particle size;
Total organic carbon
|
1945 |
Organics in Whale Blubber (Frozen) |
1993 |
PCBs (27); Pesticides (15) |
PCBs (2); Pesticides (2) |
1974a |
Organics in Mussel Tissue (Mytilus edulis) (Frozen) |
1995 |
PAHs (15); PCBs (20) Pesticides (7) |
Aliphatics (16); Trace Elements (28) PAHs (18); PCBs (4); Pesticides
(4) Methylmercury |
1975 |
Diesel Particulate Extract |
1999 |
PAHs (8) |
PAHs (29)
Nitro-PAHs |
2974 |
Organics in Mussel Tissue (Mytilus edulis) (Freeze Dried) |
1997 |
PAHs (14); PCBs (20); Pesticides (7); Methylmercury;
Mercury |
PAHs (17); PCBs (4); Pesticides (4); Trace Elements (8) |
2976 |
Mussel Tissue (Trace elements and Methylmercury) |
1997 |
Methylmercury (8);
Trace elements |
Trace elements (2) |
PANH = Polycyclic aromatic nitrogen heterocycles
PCDD = Polychlorinated dibenzodioxins
PAQ = Polycyclic aromatic quinones
PCDF = Polychlorinated dibenzofurans
PASH = Polycyclic aromatic sulfur heterocycles
aFirst issued in 1989; revised in 1998.
bFirst issued in 1982; recertified in 1998.
cFirst issued in 1990; recertified in 1998.
Table 2. NIST Calibration Solution SRMs for the Determination
of Organic Environmental Contaminants
SRM No. |
Title |
Date Issued |
Certified Constituents |
Noncertified Constituents |
1491 |
Aromatic Hydrocarbons in Hexane/Toluene |
1989 |
PAHs (23) |
PAHs (1) |
1492 |
Chlorinated Pesticides in Hexane |
1992 |
Pesticides (15) |
|
1493 |
Chlorinated Biphenyl Congeners in 2,2,4-Trimethylpentane |
1995 |
PCBs (18) |
PCBs (2) |
1494 |
Aliphatic Hydrocarbons in 2,2,4-Trimethylpentane |
* |
Hydrocarbons (20) |
|
1584 |
Priority Pollutant Phenols in Methanol |
1984 |
Phenols (10) |
Phenols (1) |
1586 |
Isotopically Labeled and Unlabeled Priority Pollutants in Methanol |
1984 |
Priority pollutants (10) |
|
1587 |
Nitrated PAHs in Methanol |
1985 |
Nitro-PAHs (6) |
Nitro-PAHs (1) |
1596 |
Dinitropyrene Isomers and 1-Nitropyrene in Methylene Chloride |
1987 |
Nitro-PAHs (4) |
|
1614 |
Dioxin (2,3,7,8-TCDD) in Iso-octane |
1985 |
Dioxins (2) |
Dioxins (2) |
1639 |
Halocarbons (in Methanol) for Water Analysis |
1983 |
Halocarbons (7) |
|
1647d |
Priority Pollutant PAHs (in Acetonitrile) |
1992a |
PAHs (16) |
|
2260 |
Aromatic Hydrocarbons in Toluene (Nominal Concentration 60 g/mL) |
1991 |
PAHs (23) |
PAHs (1) |
2261 |
Chlorinated Pesticides in Hexane (Nominal Concentration 2 g/mL) |
1992 |
Pesticides (15) |
|
2262 |
Chlorinated Biphenyl Congeners in 2,2,4-Trimethylpentane (Nominal
Concentration 2 g/mL) |
1995 |
PCBs (25) |
PCBs (4) |
2269 |
Perdeuterated PAH-I |
* |
Perdeuterated PAHs (5) |
|
2270
|
Perdeuterated PAH-II |
* |
Perdeuterated PAHs (6) |
|
2273 |
DDTs and Metabolites in Solution |
* |
DDTs and Metabolites (7) |
|
2274 |
PCB Congener Solution-II |
* |
PCBs (11) |
|
2275 |
Chlorinated Pesticide Solution-II |
* |
Pesticides (9) |
|
2276 |
Three Planar PCBs in Solution |
* |
PCBs (3) |
|
* Certification in progress.
a
SRM 1647 was first issued in 1981.
Table 3. Analytes in NIST Solution SRMs for PAHs
and Aliphatic Hydrocarbons
Polycyclic Aromatic Hydrocarbons in SRMs 1491
and 2260
(~4-8 and 50-70 g/mL) |
|
Naphthalenea |
2-Methylnaphthalene |
1-Methylnaphthalene |
Biphenyl |
2,6-Dimethylnaphthalene |
Acenaphthylenea |
Acenaphthenea |
1,6,7-Trimethylnaphthalene |
Fluorenea |
Phenanthrenea |
Anthracenea |
1-Methylphenanthrene |
Fluoranthenea |
Pyrenea |
Benz[a]anthracenea |
Chrysenea |
Benzo[b]fluoranthenea |
Benzo[k]fluoranthenea |
Benzo[e]pyrene |
Benzo[a]pyrenea |
Perylene |
Indeno[1,2,3-cd]pyrenea |
Dibenz[a,h]anthracenea |
Benzo[ghi]perylenea |
|
Perdeuterated PAHs in SRM 2269
(~5-50 g/mL) |
|
biphenyl-d10 |
phenanthrene-d10 |
fluoranthene-d10 |
benz[a]anthracene-d12 |
dibenz[a,h]anthracene-d14 |
|
Perdeuterated PAHs in SRM 2270
(~5-50 g/mL) |
naphthalene-d8 |
acenaphthene-d10 |
pyrene-d10 |
benzo[a]pyrene-d12 |
perylene-d12 |
benzo[ghi]perylene-d12 |
|
Aliphatic Hydrocarbons |
in SRM 1494 |
(~6-130 g/mL) |
|
n-Decane (n-C10) |
n-Undecane (n-C11) |
n-Dodecane (n-C12) |
n-Tridecane (n-C13) |
n-Tetradecane (n-C14) |
n-Pentadecane (n-C15) |
n-Hexadecane (n-C16) |
n-Heptadecane (n-C17) |
n-Octadecane (n-C18) |
n-Nonadecane (n-C19) |
n-Eicosane (n-C20) |
n-Docosane (n-C22) |
n-Tetracosane (n-C24) |
n-Hexacosane (n-C26) |
n-Octacosane (n-C28) |
n-Triacontane (n-C30) |
n-Dotriacontane (n-C32) |
n-Tetratriacontane (n-C34) |
Pristane |
Phytane |
|
aAnalytes in SRM 1647d (~1-20 g/mL) |
Table 4. Analytes in NIST Calibration Solution SRMs for Polychlorinated
Biphenyl (PCB) Congeners
PCB Congeners in SRMs 1493
and 2262(~0.2
and 2 g/mL) |
PCB 1 |
2-Chlorobiphenyla |
PCB 8 |
2,4'-Dichlorobiphenyl |
PCB 18 |
2,2',5-Trichlorobiphenyl |
PCB 28 |
2,4,4'-Trichlorobiphenylb |
PCB 29 |
2,4,5-Trichlorobiphenyla |
PCB 44 |
2,2',3,5'-Tetrachlorobiphenyl |
PCB 50 |
2,2',4,6-Tetrachlorobiphenyla |
PCB 52 |
2,2',5,5'-Tetrachlorobiphenylb |
PCB 66 |
2,3',4,4'-Tetrachlorobiphenyl |
PCB 77 |
3,3',4,4'-Tetrachlorobiphenylb |
PCB 87 |
2,2',3,4,5'-Pentachlorobiphenyla |
PCB 101 |
2,2',4,5,5'-Pentachlorobiphenylb |
PCB 104 |
2,2',4,6,6'-Pentachlorobiphenyla |
PCB 105 |
2,3,3',4,4'-Pentachlorobiphenyl |
PCB 118 |
2,3',4,4',5-Pentachlorobiphenyl |
PCB 126 |
3,3',4,4',5-Pentachlorobiphenyl |
PCB 128 |
2,2',3,3',4,4'-Hexachlorobiphenyl |
PCB 138 |
2,2',3,4,4',5'-Hexachlorobiphenylb |
PCB 153 |
2,2',4,4',5,5'-Hexachlorobiphenylb |
PCB 154 |
2,2',4,4',5,6'-Hexachlorobiphenyla |
PCB 170 |
2,2',3,3',4,4',5-Heptachlorobiphenyl |
PCB 180 |
2,2',3,4,4',5,5'-Heptachlorobiphenyl |
PCB 187 |
2,2',3,4',5,5',6-Heptachlorobiphenyl |
PCB 188 |
2,2',3,4',5,6,6'-Heptachlorobiphenyla |
PCB 195 |
2,2',3,3',4,4',5,6-Octachlorobiphenyl |
PCB 201 |
2,2',3,3',4,5',6,6'-Octachlorobiphenyla |
PCB 206 |
2,2',3,3',4,4',5,5',6-Nonochlorobiphenyl |
PCB 209 |
Decachlorobiphenyl |
|
PCB Congeners in SRM 2274
(~2 g/mL) |
PCB 31 |
2,4',5-Trichlorobiphenyl |
PCB 49 |
2,2',4,5'-Tetrachlorobiphenyl |
PCB 95 |
2,2',3,5',6-Pentachlorobiphenyl |
PCB 99 |
2,2',4,4',5-Pentachlorobiphenyl |
PCB 110 |
2,3,3',4',6-Pentachlorobiphenyl |
PCB 149 |
2,2',3,4',5',6-Hexachlorobiphenyl |
PCB 151 |
2,2',3,5,5',6-Hexachlorobiphenyl |
PCB 156 |
2,3,3',4,4',5-Hexachlorobiphenyl |
PCB 169 |
3,3',4,4',5,5'-Hexachlorobiphenyl |
PCB 183 |
2,2',3,4,4',5',6-Heptachlorobiphenyl |
PCB 194 |
2,2',3,3',4,4',5,5'-Octachlorobiphenyl |
|
PCB Congeners in SRM 2276
(~2 g/mL) |
PCB 77 |
3,3',4,4'-Tetrachlorobiphenyl |
PCB 126 |
3,3',4,4',5-Pentachlorobiphenyl |
PCB 169 |
3,3',4,4',5,5'-Hexachlorobiphenyl |
a Analytes not in SRM 1493
b Analytes in SRM 1585 (~1-30 g/mL)
PCB 3 (4-Chlorobiphenyl) and PCB 15 (4,4'-Dichlorobiphenyl) are also in
SRM 1585
Table 5. Analytes in NIST Calibration Solution SRMs for Chlorinated
Pesticides
Chlorinated Pesticides in SRMs 1492
and 2261
(~0.2 and 2 g/mL) |
Hexachlorobenzene |
gamma-HCH |
Heptachlor |
Aldrin |
Heptachlor epoxide |
cis-Chlordane |
trans-Nonachlor |
Dieldrin |
Mirex |
2,4'-DDE |
4,4'-DDE |
2,4'-DDD |
4,4'-DDD |
2,4'-DDT |
4,4'-DDT |
|
Chlorinated Pesticides in SRM 1583 (~0.5-1.3 g/mL) |
gamma-HCH |
delta-HCH |
Aldrin |
Heptachlor epoxide |
4,4'-DDE |
4,4'-DDT |
|
Chlorinated Pesticides in SRM 2275
(~2 g/mL) |
alpha-HCH |
beta-HCH |
Oxychlordane |
cis-Nonachlor |
trans-Chlordane |
Endrin |
Endosulfan I |
Endosulfan II |
Endosulfan sulfate |
Table 6. NIST Reference Materials (RMs) for Organic Environmental
Analysis
RM No. |
Title |
Date Issued |
Reference Values |
8469 |
4,4'-DDT |
1992 |
1 (purity of neat material) |
8467 |
4,4'-DDE |
1992 |
1 (purity of neat material) |
8466 |
Lindane (gamma-HCH) |
1992 |
1 (purity of neat material) |
8470 |
1,2,3-Trichlorobenzene and 4,4'-Dibromooctafluorobiphenyl
(DBOFB) in Hexane |
* |
2 |
8471 |
Hexamethylbenzene in Hexane |
* |
1 |
8472 |
Tetrachloro-m-xylene in Hexane |
* |
1 |
* = Certification in progress
Table 7. NIST Reference Materials (RMs)
and Standard Reference Materials (SRMs) for the Determination of Trace
Levels of Water
RM/SRM No. |
Title |
Date Issued |
Reference Values |
2890 |
Water Saturated Octanol |
1998 |
1 |
8506a |
Moisture in Transformer Oil |
1992 |
1 |
8507 |
Moisture in Mineral Oil (93 mg/kg) |
1992 |
1 |
8508 |
Moisture in Methanol (325 mg/kg) |
|
|
8510 |
Moisture in Methanol |
1997 |
1 |
|
Moisture in Crude Oil |
|
|
Return
to OAMG Home
Top
of Document
Date
created: November 21, 2002
Last updated:
April 15, 2003
Contact: acd_webmaster@nist.gov
|
|