EFFECTS OF SOILS, RIPARIAN ZONES, AND HYDROLOGY ON NUTRIENTS, HERBICIDES, AND BIOLOGICAL RELATIONS IN MIDWESTERN AGRICULTURAL STREAMS. Stephen D. Porter 1, Mitchell A. Harris 2, and Stephen K. Sorenson 3. U.S. Geological Survey, Water Resources Division, 1 Box 26046, MS406, Denver, CO 80225; 2 221 North Broadway Avenue, Urbana, IL 61801; 3 12201 Sunrise Valley Drive, MS412, Reston, VA 20192. Chemical, biological, and habitat conditions were characterized in 70 streams in the Midwest Corn Belt region during August 1997, as part of the U.S. Geological Survey's National Water Quality Assessment (NAWQA) Program. The study was designed to evaluate algal and macroinvertebrate responses to high agricultural intensity in relation to nonpoint sources of nutrients and herbicides, characteristics of basin soils, wooded-riparian vegetation, and hydrology. Concentrations and forms of nutrients, herbicides and their metabolites, and seston constituents varied significantly with regional differences in soil drainage, ground-water and surface-water relations, density of riparian trees, and preceding hydrologic conditions. Dissolved nitrate concentrations were relatively low in streams with high diel productivity. Stream productivity was positively correlated with seston (phytoplankton) chlorophyll concentrations, which were significantly larger in streams in areas with poorly drained soils and low riparian-tree density. Concentrations of dissolved phosphorus were low in streams where periphyton biomass was high. Periphyton biomass was relatively larger in streams with clear water and low abundances of macroinvertebrate scrapers and collector-gatherers. Periphyton biomass decreased rapidly with modest increases in the abundance of macroinvertebrate scrapers. Differences in dissolved oxygen, dissolved organic carbon, and stream velocity explained much of the variance in macroinvertebrate community structure. The total number of macroinvertebrate species and number of mayfly, caddisfly, and stonefly (EPT) taxa were largest in streams with relatively large periphyton biomass in areas with moderately-well drained soils and high riparian-tree density. Keywords: algae, stream productivity, macroinvertebrates, agricultural intensity, landscape factors