ACE 1999 Leg 1 Readme File Ship: NOAA research vessel Ronald H. Brown Cruise Start: Norfolk, VA, January 14, 1999 Cruise End: Capetown, South Africa, February 8, 1999 Chief Scientist: Tim Bates System Operator: Bob Castle Method: Infrared absorption of dried gas. For details of the system see: Measurement of fugacity of Carbon Dioxide in surface water and air using continuous sampling methods. Wanninkhof and Thoning, 1993 in Marine Chemistry 44, 189-205, And: Feely, R.A., R. Wanninkhof, H.B. Milburn, C.E. Cosca, M. Stapp, and P.P. Murphy, A new automated underway system for making high precision pCO2 measurements onboard research ships, Analytica Chim. Acta, 377, 185-191, 1998. The three standard gases come from CMDL in Boulder and are directly traceable to the WMO scale. Sampling Cycle: The system runs on an hourly cycle during which 3 standard gases, 3 air samples from the bow tower and 8 surface water samples (from the equilibrator head space) are analyzed on the following schedule: Mins. after hour Sample 4 Low Standard 8 Mid Standard 12 High Standard 16.5 Water 21 Water 25.5 Water 30 Water 34 Air 38 Air 42 Air 46.5 Water 51 Water 55.5 Water 60 Water Units: All xCO2 values are reported in parts per million (ppm) and fCO2 values are reported in microatmospheres (uatm) assuming 100 % humidity at the equilibrator temperature. Notes for Leg 1: 1. Data prior to 1/16 @ 1730 (about 1 day's worth) was removed due to a clog in one of the vent lines leading to the equilibrator which was causing bad readings. 2. On 1/17 from 0430 to 0630 the system was down for repairs to one of the solenoids. 3. On 1/26 from 1630 to 1830 the system was down for installation of new version of the software (version 2.6) and other minor repairs. 4. On 1/27 from 2000 to 2130 the system was down for resurfacing and recalibration of the YSI dissolved oxygen sensor. For questions or comments contact: Bob Castle 4301 Rickenbacker Causeway Miami, FL 33149 305-361-4418 castle@aoml.noaa.gov