US 7,396,474 B2
Dual injection of two polymeric filtration aids for gypsum removal from phosphoric acid/gypsum slurry
Louis Irwin, Winter Haven, Fla. (US)
Assigned to Arr-Maz Products, LP, Mulberry, Fla. (US)
Filed on Nov. 08, 2005, as Appl. No. 11/269,357.
Prior Publication US 2007/0102368 A1, May 10, 2007
Int. Cl. B01D 37/03 (2006.01)
U.S. Cl. 210—778  [210/727; 210/734; 423/321.1] 5 Claims
OG exemplary drawing
 
1. A polymeric filtration aid method for gypsum removal from phosphoric acid/gypsum slurry, the method comprising:
a dual injection process where two different polymers are separately injected into a phosphoric acid/gypsum slurry at a different time, followed by filtration of gypsum solids from a liquid phosphoric acid,
wherein said phosphoric acid/gypsum slurry is produced from western phosphate ore obtained from mines in Idaho, and wherein the two different polymers are respectively comprised of different polymer chemistries of filtration aid A and B respectively, the polymer chemistry of filtration aid A being selected from the group consisting of non-ionic and anionic polymers produced from acrylamide and acrylic acid monomers, and the polymer chemistry of filtration aid B being selected from the group consisting of sulfonated polymers, wherein the sulfonated polymers comprise acrylamide tertialy-butyl (ATBS) and acrylamide or acrylic acid copolymers.