GeoSoilEnviroCARS, The University of Chicago The University of Kentucky, College of Agriculture Environmental Sciences Department, Brookhaven National Laboratory



Welcome to X26A
Information For Users

X26A Recent News
X26A Beamtime Schedule
X26A Contact Information
X26A Configuration Info
X26A Beamline Status
X26A Downloads
X26A Computing

X26A Publications
X26A Science Highlights
X26A Acknowledgement

NSLS WebSite
NSLS PASS
BNL WebSite
BNL Visitor's Guide
X27A Microprobe
CARS at the APS

Recent Publications by X26A Users

2008

Flynn, G., Sutton, S., and Lanzirotti, A. (2008) A Synchrotron-Based Facility for the In-Situ Location, Chemical and Mineralogical Characterization of ~10 micrometer Particles Captured in Aerogel, Advances in Space Research, In Press.

Gallien, J., Khodja, H., Herzog, G., Taylor, S., Koepsell, E., Daghlian, C., Flynn, G., Sitnitsky, I., Lanzirotti, A., Sutton, S., and Keller, L. (2008) Characterization of Carbon- and Nitrogen-Rich Particle Fragments Captured from Comet 81P/Wild 2, Meteoritics & Planet. Sci., v. 43, p. 335-352

Gerson, A., Anastasio, C., Crowe, S., Fowle, D., Guo, B., Kennedy, I., Lombi, E., Nico, P., Marcus, M., Martin, R., Naftel, S., Nelson, A., Paktunc, D., Roberts, J., Weisener, C., and Werner, M. (2008) Chapter 7 Frontiers in assessing the role of chemical speciation and natural attenuation on the Bioavailability of Contaminants in the Terrestrial Environment. In: A.E. Hartemink, A.B. McBratney and Ravendra Naidu, Editor(s), Developments in Soil Science, Elsevier, 2008, Volume 32, Chemical Bioavailability in Terrestrial Environment, Pages 99-136.

Grafe, M., Tappero, R., Marcus, M., and Sparks, D. (2008) Arsenic Specitation in Multiple Metal Environments: II. Micro-Spectroscopic Investigation of a CCA Contaminated Soil, J. Colloid Interface Sci., v. 321, p. 1-20.

Knox, A., Brigmon, R., Kaplan, D., and Paller, M. (2008) Interactions Among Phosphate Amendments, Microbes and Uranium Mobility in Contaminated Sediments, Sci. Total Environ., v. 395, p. 63-71.

Komlos, J., Mishra, B., Lanzirotti, A., Myneni, S., and Jaffé, P. (2008) Real–Time Speciation of Uranium During Active Bioremediation and U(IV) Reoxidation, J. Environ. Eng., v. 134, p. 77-149.

Lanzirotti, A., Sutton, S., Flynn, G., Newville, M., and Rao, W. (2008) Chemical Composition and Heterogeneity of Wild 2 Cometary Particles Determined by Synchrotron X-ray Fluorescence. Meteoritics and Planetary Science, v. 43, p. 187-214.

Lev, S., Landa, E., Szlavecz, K., Casey, R., and Snodgrass, J. (2008) Application of Synchrotron Methods to Assess the Uptake of Roadway-Derived Zn by Earthworms in an Urban Soil, Miner. Mag., v. 72, p. 191-195.

Linkous, D., Flinn, J., Koh, J., Lanzirotti, A., Bertsch, P., Jones, B., Giblin, L., and Fredrickson, C. (2008) Evidence That the ZNT3 Protein Controls the Total Amount of Elemental Zinc in Synaptic Vesicles, J. Histochem. Cytochem., v. 56, p. 3-6.

Rakovan, J., Luo, Y., and Borkiewicz, O. (2008) Synchrotron Microanalytical Methods in the Study of Trace and Minor Elements in Apatite, Mineralogia Polonica, v. 39, p. 31-40.

Salt, D., Baxter, I., and Lahner, B. (2008) Ionomics and the Study of the Plant Ionome, Annu. Rev. Plant Biol., v. 59, p. 709-733.

Schroth, A., Bostick, B., Kaste, J., and Friedland, A. (2008) Lead Sequestration and Species Redistribution During Soil Organic Matter Decomposition, Environ. Sci. Tech., v. 42, p. 3627-3633.

Tokunaga, T., Wan, J., Kim, Y., Sutton, S., Newville, M., Lanzirotti, A., and Rao, W. (2008) Simultaneous X-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction. Environmental Science and Technology, v.42, p.2839–2844.

Unrine, J., Bertsch, P., and Hunyadi, S. (2008) Bioavailability, Trophic Transfer and Toxicity of Manufactured Metal and Metal Oxide Nanoparticles in Terrestrial Environments, Nanoscience and Nanotechnology: Environmental and Health Impacts, p. 345-360, John Wiley & Sons, Hoboken.

Wan, J., Tokunaga, T., Kim, Y., Wang, Z., Lanzirotti, A., Saiz, E., and Serne, R. (2008) Effect of Saline Waste Solution Infiltration Rates on Uranium Retention and Spatial Distribution in Hanford Sediments, Environ. Sci. Tech., v. 42, p. 1973–1978.


2007

Alexandratos, V., Elzinga, E., and Reeder, R. (2007) Arsenate uptake by calcite: Macroscopic and spectroscopic characterization of adsorption and incorporation mechanisms, Geochim. Cosmochim. Acta, v. 71, p. 4172-4187.

Crowe, S., Roberts, J., Weisener, C., and Fowle, D. (2007) Alteration of Iron-Rich Lacustrine Sediments by Dissimilatory Iron-Reducing Bacteria, Geobiology, v. 5, p. 63-73.

Flynn, G., Lanzirotti, A., Sutton, S., and Sitnisky, I. (2007) Chemical compositions of five large cluster IDPs. Lunar and Planetary Science , Vol XXXVIII, p. 2290, sponsored by Lunar and Planetary Institute.

Gallien, J., Khodja, H., Herzog, G., Taylor, S., Koepsell, E., Daghlian, C., Flynn, G., Sitnitsky, I., Lanzirotti, A., Sutton, S., and Keller, L. (2007) Characterization of three carbon- and nitrogen-rich particles from comet 81P/Wild 2. Lunar and Planetary Science , Vol XXXVIII, p. 1605, sponsored by Lunar and Planetary Institute.

Kaplan, D., Powell, B., Duff, M., Demirkanli, D., Denham, M., Field, R., and Molz, F. (2007) Influence of Sources on Plutonium Mobility and Oxidation State Transformations in Vadose Zone Sediments, Environ. Sci. Tech., v. 41, p. 7417-7423.

Lengyel, I., Flinn, J., Peto, T., Linkous, D., Cano, K., Bird, A., Lanzirotti, A., Fredrickson, C., and van Kuijk, F. (2007) High concentration of zinc in sub-retinal pigment epithelial deposits. Experimental Eye Research, v. 84, p. 772-780.

Miller, L., Wang, Q., Smith, R., Zhong, H., Elliott, D., and Warren, J. (2007) A New Sample Substrate for Imaging and Correlating Organic and Trace Metal Composition in Biological Cells and Tissues. Anal. Bioanal. Chem, v. 387, p. 1705-1715.

Salt, D., Baxter, I., and Lahner, B. (2008) Ionomics and the Study of the Plant Ionome, Annu. Rev. Plant Biol., 59: 709-733 (2008)

Tang, Y., Elzinga, E., Lee, Y., and Reeder, R. (2007) Coprecipitation of chromate with calcite: Batch experiments and X-ray absorption spectroscopy. Geochimica et Cosmochimica Acta, v. 71, p. 1480-1493.

Tokunaga, T., Wan, J., Lanzirotti, A., Sutton, S., Newville, M. and Rao, W. (2007) Long-Term Stability of Organic Carbon-Stimulated Chromate Reduction in Contaminated Soils and Its Relation to Manganese Redox Status. Environmental Science & Technology,v. 41, p. 4326-4331.

Treiman, A., Dyar, M., McCanta, M., Noble, S., and Pieters, C. (2007) Martian Dunite NWA 2737: Petrographic Constraints on Geological History, Shock Events, and Olivine Color, J. Geophys. Res., 112: E04002.

Wan, J., Tokunaga, T. K., Kim, Y., Wang, Z., Lanzirotti, A., Saiz, E., and Serne, R. J. (2008) Effect of Saline Waste Solution Infiltration Rates on Uranium Retention and Spatial Distribution in Hanford Sediments. Environmental Science and Technology (in press).

Yang, L. and Donahoe, R. (2007) The form, distribution and mobility of arsenic in soils contaminated by arsenic trioxide, at sites in southeast U.S.A. Applied Geochemistry, v. 22, p. 320-341.


2006

Arai, Y., Lanzirotti, A., Sutton, S., Newville, M., Dyer, J., and Sparks, D. (2006) Spatial and Temporal Variability of Arsenic Solid-State Speciation in Historically Lead Arsenate Contaminated Soils. Environ. Sci. & Tech., 40, 673-679.

Brown, G. E., S. R. Sutton, and G. Calas (2006) User facilities around the world. Elements, 2, 9-14.

Brownlee, D., et al. (2006) Comet 81P/Wild 2 Under a Microscope. Science, 314, 1711-1716.

Cempirek, J., Novak, M., Ertl, A., Hughes, J., Rossman, G., and Dyar, M. (2006) Fe-bearing Olenite with Tetrahedrally Coordinated Al from an Abyssal Pegmatite at Kutná Hora, Czech Republic: Structure, Crystal Chemistry, Optical and XANES Spectra. Can. Mineral., 44: 23-30.

Corriveau, M. (2006) Characterization of Arsenic-bearing Near-surface and Airborne Particulates from Gold-mine Tailings in Nova Scotia, Canada. M.Sc. Thesis. Queen's University , Kingston.

Flynn, G., et al. (2006) Elemental Compositions of Comet 81P/Wild 2 Samples Collected by Stardust. Science, 314, 1731-1735.

Hendy, E., Lanzirotti, A., Rasbury, T., and Lough, J. (2006) Synchrotron µ-XRF mapping of elemental distributions across coral skeleton micro-architecture. Geochim. Cosmochim. Acta, 70, 246.

Kaste, J., Bostick, B., Friedland, A., Schroth, A., and Siccama, T., (2006) Fate and Speciation of Gasoline-Derived Lead in Organic Horizons of the Northeastern USA, Soil Sci. Soc. Am. J., v. 70, p. 1688-1698.

Kim, S., Punshon, T., Lanzirotti, A., Li, L., Alonso, J., Ecker, J., Kaplan, J., and Guerinot, M.L. (2006) Localization of Iron in Arabidopsis Seed Requires the Vacuolar Membrane Transporter VIT1. Science, 314, 1295-1298.

Lanzirotti, A. and Sutton, S. (2006) Synchrotron X-ray microbeam techniques in assessing metal bioavailability in the environment. Geochim. Cosmochim. Acta, 70, 343.

Leri, A., Hay, M., Lanzirotti, A., Rao, W., and Myneni, S. (2006) Quantitative Determination of Absolute Organohalogen Concentrations in Environmental Samples by X-ray Absorption Spectroscopy. Analytical Chemistry, 78, 5711-5718.

Martin, R., Naftel, S., Macfie, S., Jones, K., Feng, H., and Trembley, C. (2006) High variability of the metal content of tree growth rings as measured by synchrotron micro x-ray fluorescence spectrometry. X-Ray Spectrometry, 35, 57-62.

Martínez, C. E., Bazilevskaya, K. A., and Lanzirotti, A. (2006) Zinc Coordination to Multiple Ligand Atoms in Organic-Rich Surface Soils. Environmental Science & Technology, 40, 5688-5695.

Miller, L., Wang, Q., Telivala, T., Smith, R., Lanzirotti, A., and Miklossy, J. (2006) Synchrotron-Based Infrared and X-Ray Imaging Shows Focalized Accumulation of Cu and Zn Co-localized with Beta-Amyloid Deposits in Alzheimer's Disease. Journal of Structural Biology, 155, 30-37.

Poussart, P., Myneni, S. and Lanzirotti, A. (2006) Tropical dendrochemistry: A novel approach to estimate age and growth from ringless trees. Geophysical Research Letters, 33: L17711.

Reeder, R., and Lanzirotti, A. (2006) Accessing user facilities and making your research experience successful. X-Ray Spectrometry, Elements, 2, 31-36.

Reeder, R., Schoonen, M., and Lanzirotti, A. (2006) Metal Speciation and Its Role in Bioaccessibility and Bioavailability. In Sahai, N. and Schoonen, M., eds., Reviews in Mineralogy and Geochemistry v. 64: Medical Mineralogy and Geochemistry, p.59-113.

Sutton, S. R. (2006) User research facilities in the earth sciences. Elements, 2, 7-8.

Sutton, S. R., M. W. Caffee, and M. T. Dove (2006) Synchrotron radiation, neutron and mass spectrometry techniques at user facilities. Elements, 2, 15-21.

Walker. S. (2006) The Solid-Phase Speciation of Arsenic in Roasted and Weathered Sulfides at the Giant Gold Mine, Yellowknife, NWT. Application of Synchrotron MicroXANES and MicroXRD at the Grain Scale. Ph.D. Thesis. Queen's University, Kingston, Canada.

Zolensky, M., et al. (2006) Mineralogy and Petrology of Comet 81P/Wild 2 Nucleus Samples. Science, 314, 1735-1739.


2005

Andrade, C., Preharaj, T., Jamieson, H., and Fortin, D. (2005) The potential for geochemical and microbial remobilization of arsenic from sediments in Yellowknife Bay, Great Slave Lake: Progress. Geological Sciences, Queen's University , Kingston. Prepared for Indian and Northern Affairs Canada.

Cheng, M., Levy, M., Schulze,D., and Huber, D. (2005) Mn Transition States During Infection and Early Pathogenesis in Rice Blast Relative to Resistance and Susceptibility. Phytopathology, 95, S19.

Flinn, J., D. Hunter, D.H. Linkous, A. Lanzirotti, L Smith, J. Brightwell and B.F. Jones (2005) Enhanced zinc consumption causes memory deficits and increased brain levels of zinc. Physiology and Behavio, v. 83, p. 793-803.

Fthenakis, V. M., M. Fuhrmann, J. Heiser, A. Lanzirotti, J. Fitts and W. Wang (2005) Emissions and Encapsulation of Cadmium in CdTe PV Modules During Fires. Progress in Photovoltaics: Research and Applications, 13, 713-723.

Fuhrmann, M. and A. Lanzirotti (2005) 241Am, 137Cs, Sr and Pb uptake by tobacco as influenced by application of Fe chelators to soil . Journ. of Environmental Radioactivity, 82, 33-50.

Ginder-Vogel, M., Borch, T., Mayes, M., Jardine, P., and Fendorf, S. (2005) Chromate Reduction and Retention Processes within Arid Subsurface Environments. Environmental Science and Technology, v.39, p.7833-7839.

Jackson, B., Williams, P., Lanzirotti, A., and Bertsch, P. (2005) Evidence for biogenic pyromorphite formation by the nematode Caenorhabditis elegans. Environmental Science & Technology, v. 39, p. 5620-5625.

Jones, K., Feng, H., Lanzirotti, A., and Mahajan, D. (2005) Mapping metal catalysts using synchrotron computed microtomography (CMT) and micro-X-ray fluorescence (µXRF). Topics in Catalysis, v. 32, p. 263-272.

Jones, K., Feng, H., Lanzirotti, A., and Mahajan, D. (2005) Synchrotron X-ray microprobe and computed microtomography for characterization of nanocatalysts. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 241, 331-334.

Miller, L., Smith, R., Ruppel, M., Ott, C., and Lanzirotti, A. (2005) Development and applications of an epifluorescence module for synchrotron x-ray fluorescence microprobe imaging. Review of Scientific Instruments, 76, 066107-1 - 066107-5.

Negra, C., Ross, D., and Lanzirotti, A. (2005) Soil Manganese Oxides and Trace Metals: Competitive Sorption and Microfocused Synchrotron X-ray Fluorescence Mapping . Soil Science Society of America Journal, 69, 353-361.

Negra, C., Ross, D., and Lanzirotti, A. (2005) Oxidizing Behavior of Soil Manganese: Interactions among Abundance, Oxidation State, and pH . Soil Science Society of America Journal, 69, 87-95.

Punshon, T., Lanzirotti, A., Harper, S., Bertsch, P., and Burger, J. (2005) Distribution and Speciation of Metals in Annual Rings of Black Willow. Journal of Environmental Quality, 34, 1165-1173.

Punshon, T., B.P. Jackson, A. Lanzirotti, W. Hopkins, P.M. Bertsch, and J. Burger (2005) Application of synchrotron x-ray absorption spectroscopy to determining metal speciation and distribution in biological tissues. Spectroscopy Letters, 38: 343-363 .

Ruppel, M. (2005) Development and Applications of an Epifluorescence Module for Synchrotron X-ray Fluorescence Imaging. Masters Thesis. Stony Brook University, Stony Brook.

Telivala, T. (2005) Effect of Metal Ions on the Secondary Structure of Amyloid beta (Ab) in Alzheimer's disease. Masters Thesis Thesis. SUNY at Stony Brook, Stony Brook.

Thompson, I., Huber, D., Guest, C., and Schulze, D. (2005) Fungal manganese oxidation in a reduced soil. Environmental Microbiology, 7, 1480-1487.

Tokunaga, T., Wan, J., Pena, J., Brodie, E., Firestone, M., Hazen, T., Sutton, S., Lanzirotti, A., and Newville, M. (2005) Uranium Reduction in Sediments Under Diffusion-Limited Transport of Organic Carbon, Environmental Science & Technology, 39, 7077-7083.

Vantelon, D., Lanzirotti, A., Scheinost, A., and Kretzschmar, R. (2005) Spatial distribution and speciation of lead around corroding bullets in a shooting range soil studied by micro-X-ray fluorescence and absorption spectroscopy. Environmental Science & Technology, 39, 4808-4815.

Walker, S.R., Jamieson, H.E., Lanzirotti, A., Andrade, C.F., and Hall, G. (2005) The speciation of arsenic in iron oxides in mine wastes from the Giant gold mine, N.W.T.: application of synchrotron micro-XRD and micro-XANES at the grain scale. Canadian Mineralogist, v. 43, p. 1205-1224.

Wang, Q., Kretlow, A., Beekes, M., Naumann, D., and Miller, L. (2005) In situ characterization of prion protein structure and metal accumulation in scrapie-infected cells by synchrotron infrared and X-ray imaging. Vibrational Spectroscopy, 38, 61-69.


2004

Chouparova, E., Lanzirotti, A., Feng, H., Jones, K., Marinkovic, N., Whitson, C., and Philp, P. (2004) Characterization of PetroleumDeposits Formed in a Producing Well by Synchrotron Radiation-Based Microanalyses. Energ. Fuel., 18: 1199-1212

Cole, J.M., Rasbury. E.T., Montańez, I.P., Pedone, V.A., Lanzirotti, A., and Hanson, G.N. (2004) Petrographic and trace element analysis of uranium-rich tufa calcite, middle Miocene Barstow Formation, California, USA. Sedimentology, 51, 433–453.

Duff, M. C., D. B. Hunter, D. T. Hobbs, S. D. Fink, Z. Dai, and J. P. Bradley (2004) Mechanisms of Strontium and Uranium Removal from High-Level Radioactive Waste Simulant Solutions by the Sorbent Monosodium Titanate. Environ. Sci. Technol., 38, 5201-5207.

Flynn, G. J., and D. D. Durda (2004) Chemical and mineralogical size segregation in the impact disruption of inhomogeneous, anhydrous meteorites. Planetary and Space Science, 52, 1129-1140.

McCanta, M.C., Rutherford, M.J., Dyar, M.D., and Delaney, J.S. (2004) Iron partitioning between basaltic melts and clinopyroxene as a function of oxygen fugacity. Amer. Mineral., 89, 1685-1693.

Treiman, A., Lanzirotti, A., and Xirouchakis, D. (2004) Ancient Water on Asteroid 4 Vesta: Evidence from a Quartz Veinlet in the Serra de Magé Eucrite Meteorite. Earth and Planetary Science Letters, 219, 189-199.


2003

Aerts, A., B. Velde, K. Janssens, W. Dijkman (2003) Change in silica sources in Roman and post-Roman glass. Spectrochim. Acta B., 58: 659-667.

Arai, Y., Lanzirotti, A., Sutton, S., Davis, J., and Sparks, D. (2003) Arsenic Speciation and Reactivity in Poultry Litter. Environmental Science and Technology, 37, 4083-4090.

Cole, J.M., Nienstedt, J., Spataro, G., Rasbury, E.T, Lanzirotti, A., Celestian, A.J., Nilsson, M., Hanson, G.N. (2003) Phosphor imaging as a tool for in situ mapping of ppm levels of uranium and thorium in rocks and minerals. Chemical Geology, 193, 127-136.

Flynn, G., Keller, L., Wirick, S., Jacobsen, C., and Sutton, S. (2003) Analysis of interplanetary dust particles by soft and hard x-ray microscopy. J. Phys. IV., 104: 367-372.

Howe, J.A., Loeppert, R., DeRose, V., Hunter, D.B., and Bertsch, P. (2003) Localization and Speciation of Chromium in Subterranean Clover Using XRF, XANES, and EPR Spectroscopy. Environmental Science and Technology, 37, 4091-4097.

Jones, B., Conko, K., Flinn, J., Linkous, D., Lanzirotti, A., Frederickson, C., Bertsch, P., Friedlich, A., and Bush, A. (2003) Effects of Enhanced Zinc in Drinking Water on Brain and Memory, Natural Science and Public Health: Prescription for a Better Environment. U. S. Geological Survey, Reston. Prepared for U. S. Geological Survey, Department of Interior, Open File Report 03-0097.

Kwiatek, W., Hanson, A., Paluszkiewicz, C., Galka, M., Gajda, M., Cichocki, T. (2003) Srixe and Xanes Application to Iron Oxidation State Determination in Prostate Tissue Sections. J. Alloys Compd., 362: 83-87.

Le Bozec, N., Joiret, S., Thierry, D., Persson, D. (2003) The role of chromate conversion coating in the filiform corrosion of coated aluminium alloys. Journal of Electrochem. Soc., 150: B561-B566.

Li, H., Lee, L., Schulze, D., and Guest, C. (2003) Role of Soil Manganese in the Oxidation of Aromatic Amines. Environ. Sci. Tech., 37: 2686-2693.

Mayanovic, R.A., Jayaneti, S., Anderson, A.J., Bassett, W.A., and Chou, I. (2003) Relaxation of the structure of simple metal ion complexes in aqueous solutions at up to supercritical conditions. Journal of Chemical Physics, 118, 719-727.

Neufeld, A. (2003) Investigations using a Kelvin Probe Instrument and Solid State Electrochemical Techniques: The Initiation Mechanism of Corrosion of Zinc and the Solid-Solid Electrochemical Transformation of CuTCNQ (TCNQ=Tetracyanoquinodimethane). Ph.D. Thesis. Monash University, Melbourne.

Punshon, T., Bertsch, P., Lanzirotti, A., McLeod, K., and Burger, J. (2003) Geochemical signature of sediment remobilization a contaminated wetland revealed by spatially resolved X-ray microanalysis of annual rings of salix nigra. Environ. Sci. and Tech., 37, 1766-1774.

Roberts, D., Ford, R., and Sparks, D. (2003) Kinetics and Mechanisms of Zn Complexation on Metal Oxides using EXAFS Spectroscopy. J. Colloid Interface Sci., 263: 364-376.

Roberts, D., Scheinost, A., and Sparks, D. (2003) Zinc speciation in contaminated soils combing direct and indirect characterization methods. Geochemical and Hydrological Reactivity of Heavy Metals in Soils, p. 187-227, Lewis Publishers, Boca Raton.

Sunil, D., H. Gafney, M. Rafailovich, J. Sokolov, R. Gambino, and D. Huang (2003). Iron and iron oxide particle growth in porous Vycor glass; correlation with optical and magnetic properties. J. Non-Cryst. Solids, v. 319: p. 154-162.

Tokunaga, T., Olson, K., and Wan, J. (2003) Moisture characteristics of Hanford gravels: Bulk, grain-surface, and intragranular components. Vadose Zone J., 2: 322-329.

Tokunaga, T., Wan, J., Firestone, M., Hazen, T., Olson, K., Herman, D., Sutton, S., and Lanzirotti, A. (2003) In Situ Reduction of Chromium(VI) in Heavily Contaminated Soils through Organic Carbon Amendment, J. Environ. Qual.. v. 32, 1641-1649.

Tokunaga, T., J. Wan, T. Hazen, E. Schwartz, M. Firestone, S. Sutton, M. Newville, K. Olson, A. Lanzirotti, and W. Rao (2003) Distribution of chromium contamination and microbial activity in soil aggregates. J. Environ. Qual.. v. 32, 541-549.


2002

Arai, Y. and Sparks, D. (2002) Residence Time Effects on Arsenate Surface Speciation at the Aluminum Oxide-water Interface. Soil Sci., 167: 303-314.

Bosze, S., and J. Rakovan (2002) Surface Structure Controlled Sectoral Zoning of the Rare Earth Elements in Fluorite from Long Lake, N.Y. and Bingham, N.M. Geochim. Cosmochim. Acta, 66, 997-1009

Dobrowolski, Z., Drewniak, T., Kwiatek, K., and Jakubik, P. (2002) Trace Elements Distribution in Renal Cell Carcinoma Depending on Stage of Disease. Eur. Urol., 42, 475-480

Duff, M., J. Coughlin, D. Hunter (2002) Uranium Co-precipitation with Iron Oxide Minerals, Geochim. Cosmochim. Acta, 66, 3533-3547.

Dyar, M.D., Gunter, M.E., Delaney, J.S., Lanzirotti, A., and Sutton, S.R. (2002) Systematics in the structure and XANES spectra of pyroxenes, amphiboles, and micas as derived from oriented single crystals. Canadian Mineralogist, 40, 1375-1393.

Dyar, M. (2002) Mossbauer and optical spectra of micas. Advances in Micas, 313-349, A. Mottana and F. Sassi (eds.), Mineralogical Society of America, Washington, DC, USA.

Dyar, M., E. Lowe, C. Guidotti, J. Delaney (2002) Fe3+ and Fe2+ partitioning among silicates in metapelites: A synchrotron micro-XANES study, Am. Mineral., 87, 514-522.

Dyar, M.D., Gunter, M.E., Delaney, J.S., Lanzirotti, A., and Sutton, S.R. (2002) Use of the spindle stage for orientation of single crystals for microXAS: Isotropy and anisotropy in Fe-XANES spectra. American Mineralogist, 87, 1500-1504.

Elzinga, E.J., and R. Reeder (2002) X-ray absorption spectroscopy study of Cu2+ and Zn2+ adsorption complexes at the calcite surface: Implications for site-specific metal incorporation preferences during calcite crystal growth. Geochim. Cosmochim. Acta, 66, 3943-3954.

Fredrickson, J. K., J. Zachara, D. Kennedy, C. Liu, M. Duff, D. Hunter, A. Dohnalkova, (2002) Influence of Mn oxides on the reduction of U(VI) by the metal-reducing bacterium Shewanella putrefaciens, Geochim. Cosmochim. Acta, 66, 3247-3262.

Guest, C., D. Schulze, I. Thompson, D. Huber, (2002) Correlating Manganese X-Ray Absorption Near-Edge Structure Spectra with Extractable Soil Manganese, Soil Sci. Soc. Am. J., 66, 1172-1181.

Lanzirotti, A., and Miller, L. M. (2002) Imaging and microspectroscopy at the National Synchrotron Light Source. Synchrotron Radiation News, 15, 17-26.

Mottana, A., A. Marcelli, G. Cibin, M. Dyar, (2002) X-ray absorption spectroscopy of micas Advances, in Micas, 46, 371-412, A. Mottana and F. Sassi (eds.), Mineralogical Society of America, Washington, DC, USA.

Righter, K., M.D. Dyar, J.S. Delaney, T.W. Vennemann, and R.L. Hervig (2002) Distribution of OH, O, CL, and F in biotite from volcanic rocks and correlations with octahedral cations. Amer. Mineral., 87 (1): 142-153.

Sutton, S. R., Bertsch, P. M., Newville, M., Rivers, M., Lanzirotti, A., and Eng, P. (2002) Microfluorescence and microtomography analyses of heterogeneous earth and environmental materials. In Fenter, P., Rivers, M., Sturchio, N., and Sutton, S., eds., Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Science, Mineralogical Society of America Reviews in Mineralogy and Geochemistry v. 49.

Twilley, J. (2002) Pigment Analyses for the Grave Stelae and Architectural Fragments from Chersonesos. Color in Ancient Greece, the Role of Color in Ancient Greek Art and Architecture 700-31 B.C., p. 171-178, 302-303, Aristotle University of Thessaloniki - Lambrakis Research Foundation, Thessaloniki.

Vaniman, D. T., S.J. Chipera, D.L. Bish, M.C. Duff and D.B. Hunter (2002) Crystal Chemistry of Clay - Mn Oxide Associations in Soils, Fractures, and Matrix of the Bandelier Tuff, Pajarito Mesa, New Mexico. Geochimica et Cosmochimica Acta, 66, 1349-1374.

Vasquez, M., G. Halada, C. Clayton, (2002) The application of synchrotron-based spectroscopic techniques to the study of chromate conversion coatings, Electrochim. Acta, 47, 3105-3115.

Xirouchakis, D., Draper, D.S, Schwandt, C.S., and Lanzirotti, A. (2002) Crystallization conditions of Los Angeles, a basaltic Martian meteorite. Geochimica et Cosmochimica Acta, 66, 1861-1874.


2001

Anderson, A.J., Clark, A.H., and Gray, S., (2001) The occurrence and origin of zabuyelite (Li2CO3) in spodumene-hosted fluid inclusions: implications for the internal evolution of rare-element granitic pegmatites. Canadian Mineralogist, 39, 1513-1527.

Banas, A., Kwiatek, W.M., Zajac, W. (2001) Trace element analysis of tissue section by means of synchrotron radiation: the use of GNUPLOT for SRIXE spectra analysis. Journal of Alloys and Compounds, 328, 135-138.

Becker, A., W. Klöck, K. Friese, P. Schreck, H.-C. Treutler, B. Spettel, M.C. Duff and W. Eisenächer (2001) Lake Süßer See as a Natural Sink for Heavy Metals from Copper Mining. J. Geochem. Exploration, 74 (1-3): 205-217

Bertsch, P. M., and D. B. Hunter (2001) Applications of Synchrotron-Based X-ray Microprobes. Chem. Rev., 101 (6), 1809 -1842.

Davenport, A. J., M. P. Ryan, M. C. Simmonds, P. Ernst, R. C. Newman, S. R. Sutton, and J. S. Colligon (2001) In situ synchrotron x-ray microprobe studies of passivation thresholds in Fe-Cr alloys. Jour. Electrochem. Soc., 148 (6): B217-B221.

Duff, M. (2001) Speciation and Transformations of Sorbed Pu on Geologic Materials: Wet Chemical and Spectroscopic Observations Radioactivity in the Environment, in A. Kudo, Elsevier Sci. Limited, New York, NY, USA1, 1, 139-157.

Duff, M. C., D.B. Hunter, I.R. Triay, P.M. Bertsch, J. Kitten and D.T. Vaniman (2001) Comparison of Two Micro-Analytical Methods for Detecting the Spatial Distribution of Sorbed Pu on Geologic Materials. J. Contam. Hydrol., 47. 211-218

Dyar, M. D., J. S. Delaney, and S. R. Sutton (2001) Fe XANES spectra of iron-rich micas. Eur. Jour. Min., Mica Special Issue, 13 (6): 1079-1098.

Kwiatek, W.M., Galka, M., Hanson, A.L., Paluszkiewicz, C., and Cichocki, T. (2001) XANES as a tool for iron oxidation state determination in tissues. Journal of Alloys and Compounds, 328, 276-282.

Kwiatek, W.M., Kubica, B., Paluszkiewicz, C., Galka, M. (2001) Trace element analysis by means of synchrotron radiation, XRF, and PIXE: selection of sample preparation procedure. Journal of Alloys and Compounds, 328, 283-288.

Lanzirotti, A., Jones, K.W., Clarkson, T.W., and Grandjean, P. (2001) Human health risks of methyl mercury. National Synchrotron Light Source Activity Report 2001, 97-99.

Martin, R.R., Sham, T.K., Won, G.W., Jones, K.W., Feng, H. (2001) Synchrotron X-ray fluorescence and secondary ion mass spectrometry in tree ring microanalysis: applications to dendroanalysis. X-ray Spectrometry, 30, 338-341.

Naftel, S., R. Martin, K. Jones, H. Feng, M. Savard, C. Begin, (2001) Synchrotron Radiation Analysis of a Smelter Impacted Tree Ring Sample, Can. J. Anal. Sci. Spectros., 46, 118-122.

Naftel, S., Martin, R., Sham, T., Macfie, S., and Jones, K. (2001) Micro-synchrotron x-ray fluorescence of cadmium-challanged corn roots. J. Electron. Spectrosc. Relat. Phenom., 119, 235-239.

Paluszkiewicz, C., and Kwiatek, W. (2001) Analysis of human cancer prostate tissue using FTIR microspectroscopy and SRIXE techniques. J. Mol. Struct., 565-566, 329-334.

Pfister, T., H. Feng, E. Wimmer, K. Jones, (2001) Synchrotron Radiation-Induced X-Ray Emission to Identify Metal Ions in Preparations of Purified Protein, BioTechniques, 31, 2-7.

Reeder, R.J., Nugent, M., Tait, C.D., Morris, D.E., Heald, S.M., Beck, K.M., Hess, W.P. and Lanzirotti, A. (2001) Coprecipitation of Uranium(VI) with Calcite: XAFS, Micro-XAS, and Luminescence Characterization. Geochimica et Cosmochimica Acta, 65, 3491-3503

Ross, D. S., H.C. Hales, and A.Lanzirotti (2001) Sensitivity of soil Mn-oxides: XANES spectroscopy of moist soils causes reduction. Soil Sci. Soc. Amer. J., 65, 744-752.

Ross, D. S., H.C. Hales, and A.Lanzirotti (2001) Sensitivity of soil Mn-oxides: drying and storage causes reduction. Soil Sci. Soc. Of Amer. J., 65, 736-743.

Scheinost, A., Stanjek, H., Schulze, D., Gasser, U., and Sparks, D (2001) Structural environment and oxidation state of Mn in goethite-groutite solid-solutions. American Mineralogist, 86, 139-146.

Vanko, D.A., M. Bonnin-Mosbah, P. Philippot, E. Rodder and S.R. Sutton (2001) Fluid Inclusions in Quartz from Oceanic Hydrothermal Specimens and the Bingham, Utah, Porphyry-Cu Deposit: A Study with PIXE and SXRF, Chemical Geology, (173) 1-3, 227-238.


2000

Astheimer, R., B. Kristin, G. E. Brown, Jr., J. Hoy, K. W. Jones, N. C. Sturchio, S. R. Sutton, G. A. Waychunas, N. B. Woodward (2000) Inside Rocks. Geotimes, American Geological Institute, 20-23.

Bassett, W.A., Anderson, A. J., Mayanovic, R. A., and Chou, I.-Ming (2000) Hydrothermal diamond anvil cell for XAFS studies of first-row transition elements in aqueous solution up to supercritical conditions. Chemical Geology, 167, 3-10.

Bender, J., M.C. Duff, P. Phillips and M. Hill (2000) Bioremediation and Bioreduction of U(VI) in Groundwaters by Microbial Mats. Environ. Sci. Technol., 34(15), 3235-3241.

Dalpe, C. and D. R. Baker (2000) Experimental investigation of large-ion-lithophile-element-, high-field-strength-element- and rare-earth-element-partitioning between calcic amphibole and basaltic melt: the effects of pressure and oxygen fugacity. Contrib. Mineral. Petrol., 140: 233-250.

Duff, M. C. (2000) Speciation and Transformations of Sorbed Pu on Geologic Materials: Wet Chemical and Spectroscopic Observations. In Plutonium in the Environment. In: Environmental Radioactivity Series 1, Elsevier Sci. Limited and Kyoto University, Osaka, Japan, 464 pp.

Duff, M. C., D.E. Morris, D.B. Hunter and P.M. Bertsch (2000) Spectroscopic Characterization of Uranium in Evaporation Basin Sediments. Geochim. Cosmochim. Acta, 46, 1535-1550.

Dyar, M. D., M. Wiedenbeck, L. Cross, J.S. Delaney, C.A. Francis, E.S. Grew, C.V. Guidotti, R.L. Hervig, J.M. Hughes, W. Leeman, A.V. McGuire, R.L. Paul, J.D. Robertson, and M. Yates (2000) Mineral standards for microanalysis of light elements. Geoanalysis 2000, Pont ŕ Mousson, Lorraine France.

Flynn, G. J., S.R. Sutton, A Lanzirotti (2000) A Comparison of the Selenium Contents of Sulfides from Interplanetary Dust Particles and Meteorites. Meteoritics and Planetary Science, 35, A54.

Fredrickson, J. K., J.M. Zachara, D.W. Kennedy, M.C. Duff, Y.A. Gorby, S.W. Li and K.M. Krupka (2000) Reduction of U(VI) in Goethite (a-FeOOH) Suspensions by a Dissimilatory Metal-Reducing Bacterium. Geochim. Cosmochim. Acta, 64, 3085-3098.

Herzog, G. F., G. J. Flynn, S. R. Sutton, J. S. Delaney, A. N. Krot, and A. Meibom (2000) Low Gallium and Germanium Contents in Metal grains from the Bencubbib-Like Meteorite Queen Alexndr Range 94411 Determined by Synchrotron X-Ray Fluorescence Analysis. Meteoritics and Planetary Science, 35, A71.

Isaacs, H. S., C. S. Jeffcoate, A. J. Aldykiewicz, M. P. Ryan, M. Kaneko, G. Shea-McCarthy (2000) Scanning Volta Potentials and Polarization Measurements of Metals in Irradiated Air. Electrochem. Solid-State Letters, 3, 253-255.

Jones, K. W., and H.Feng (2000) Microanalysis of materials using synchrotron radiation. In T.K.Sham, ed., Chemical Applications of Synchrotron Radiation, World Sci Pub., NJ.

King, P. L., R.L. Hervig, J.R. Holloway, J.S. Delaney, and M.D. Dyar (2000) Partitioning of Fe3+/Fe total between amphibole and basanitic melt as a function of oxygen fugacity. Earth Planet. Sci. Lett., 178, 97-112.

Mann, S. E., M.C. Ringo, G. Shea-McCarthy, J.E. Penner-Hahn, and C.E. Evans (2000) Element-Specific Detection in Capillary Electrophoresis using X-ray Fluroescence Spectroscopy.Anal. Chem., 72, 1754-1758.

Marques, J. J. (2000) Trace Element Distributions in Brazilian Cerrado Soils at the Landscape and Micrometer Scales. Ph.D. Dissertation, Purdue University.

Marques, J. J., D.G. Schulze, N. Curi, and S.A. Mertzman (2000) Trace Elements in Oxisols from the Brazilian Cerrado: I. Landscape Scale Relationships,” Soil Science Society of America annual meeting.

Steele, I.M; Cabri, L.J.; Gaspar, J.; McMahon, G.; Marquez, M.A., Vascocellos, A.A.Z. (2000) Comparative analysis of sulfides for gold using SXRF and SIMS. Canadian Mineralogist, 38, 1-10.

Tokunaga, T. K., J. Wan, and S. R. Sutton (2000) Transient film flow on rough fracture surfaces. Water Resources Research, 36, 1737-1746.


Selected pre-2000

Bertsch, P. M., and D. B. Hunter (1998) Elucidating fundamental mechanisms in soil and environmental chemistry: The role of advanced analytical and spectroscopic methods. Soil Sci. Soc. America Special Publication 55, “Future Prospects for Soil Chemistry,” 103-122.

Bloodaxe, E.S., Hughes, J.M., Dyar, M.D., Grew, E.S., and Guidotti, C.V. (1999) Tourmaline: Linking structure and chemistry. Am. Min., 84, 922-928.

Delaney, J. S., M. D. Dyar, S. R. Sutton, and S. Bajt (1998) Redox ratios with relevant resolution: Solving an old problem using the synchrotron microXANES probe. Geology 26, 139-142.

Duff, M. C., D.B. Hunter, I.R. Triay, P.M. Bertsch, D.T. Reed, S.R. Sutton, G. Shea-McCarthy, J. Kitten, P. Eng, S.J. Chipera and D.T. Vaniman (1999) Mineral Associations and Average Oxidation States of Sorbed Pu on Tuff. Environ. Sci. Technol., 33, 2163-2169.

Duff, M. C., D.B. Hunter, P.M. Bertsch and C. Amrhein (1999) Factors Influencing Uranium Reduction and Solubility in Evaporation Pond Sediments. Biogeochemistry, 45, 95-114.

Duff, M. C., M. Newville, D.B. Hunter, P.M. Bertsch, S.R. Sutton, I.R. Triay, D.T. Vaniman, P. Eng and M.L. Rivers (1999) Micro-XAS Studies with Sorbed Plutonium on Tuff. J. Synchrotron Radiation, 6, 350-352.

Durda, D. D., and G. J. Flynn (1999) Experimental Study of the Impact Disruption of a Porous, Inhomogeneous Target. Icarus, 142, 46-55.

Dyar, M. D., J. Delaney, S. R. Sutton and M. Schaefer (1998) Fe3+ distribution in oxidized olivine: A synchrotron micro-XANES study. Am. Mineral., 83, 1361-1365.

Flynn, G. J., and S. R. Sutton (1998) Trace element contents of L2011 cluster fragments: Implications for comet Schwassman-Wachmann-3 as the source of L2011 cluster particles. Meteoritics, 33, A49-A50.

Flynn, G. J., S. R. Sutton, K. Kehm, and C. M. Hohenberg (1998) Volatile components of large and small IDPs from L2036: Comparison of Zn and He heating indicators. Meteoritics, 33, A51.

Fuhrmann, M., S. Bajt and M. Schoonen (1998) Sorption processes on iodine on minerals. Applied Geochemistry, 13, 127-141.

Halada, G.P., C.R. Clayton, M.J. Vasquez, J.R. Kearns, M.W. Kendig, S.L. Jeanjaquet, G.G. Peterson and G. Shea-McCarthy (1998) Spatially Resolved Microchemical Analysis of Chromate Conversion Coated Aluminum Alloys and Constituent Intermetallic Particles. In Critical Factors in Localized Corrosion III --Jerome Kruger 70th Birthday Symposium, The Electrochemical Society.

Hunter, D.B. and P.M. Bertsch (1998) In Situ Examination of Uranium Contaminated Soil Particles by Micro-X-Ray Absorption and Micro-Fluorescence Spectroscopies. Journal of Radioanalytical and Nuclear Chemistry, 234, 237-242.

Hunter, D.B., W.P. Gates, P.M. Bertsch and K.M. Kemner (1999) Degradation of Tetraphenylboron at Hydrated Smectite Surfaces Studied by Time Resolved IR and X-Ray Absorption. Mineral Water Interfacial Reactions: Kinetics and Mechanisms. Eds. D.L. Sparks and T.J. Grundl. American Chemical Society Symposium Series, Volume 715, Chapter 14, 282-300.

Jones, K. W. (1999) Application of Synchrotron Radiation in the Geological and Environmental Sciences. In K.Janssens, A.Rindby, and F.Adams, Microscopic X-ray Fluorescence Analysis, J. Wiley & Sons, Sussex, 434 pp.

Lanzirotti, A. (1995) Yttrium Zoning in Metamorphic Garnets. Geochimica et Cosmochimica Acta, v.59, p.4105-4110.

Lanzirotti, A., and Hanson, G. N. (1997) An Assessment of the Utility of Staurolite in the U-Pb Dating of Metamorphism. Contributions to Mineralogy and Petrology, v.129, p.352-365.

Martin, R. R., T.K.Sham, K.W.Jones, and R.Protz (1998) Secondary ion mass spectrometry and synchrotron x-ray fluorescence in the study of the variation in metal content with time in tree rings. Canadian Journ. Of Forest Res., 28, 1464-1470.

Mosbah, M., Duraud, J.P., Métrich, N., Wu, Z., Delaney, J.S., San Miguel, A. (1999) Micro-XANES with synchrotron radiation: a complementary tool of micro-PIXE and micro-SXRF for the determination of oxidation state of elements. Application to geological materials. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 158, 214-220

Reeder, R. J., and J. Rakovan (1999) Surface structural controls on trace element incorporation during crystal growth. In Growth, Dissolution and Pattern-formation in Geosystems, B. Jamtveitand P. Meakin (eds.), 143-162. Kluwer Academic Publishers.

Ringo, M. C., M.S. Huhta, G. Shea-McCarthy, J.E. Penner-Hahn, C.E. Evans (1999) On-Line X-ray Fluorescence Detection for Capillary Electrophoresis Separations. Nucl. Instr. Meth. B, 149, 177-181.

Sturchio, N. C., M. R. Antonio, L. Soderholm, S. R. Sutton, and J. C. Brannon (1998) Tetravalent uranium in calcite. Science, 281, 971-973.

Sutton, S. R., and M. L. Rivers (1999) Hard x-ray synchrotron microprobe techniques and applications. In CMS Workshop Lectures, Vol. 9, Synchrotron Methods in Clay Science, D. G. Schulze, Stucki, J. W., and Bertsch, P. M. eds., 146-163, The Clay Minerals Society, Boulder, CO.

Sutton, S. R., G. J. Flynn, M. Rivers, P. Eng, M. Newville, G. Shea-McCarthy, and A. Lanzirotti (1999) Trace Element Chemical Analysis with Synchrotron-Based X-Ray Microprobes. Meteoritics & Planet. Sci., 34, A113-114.

Tokunaga, T., S. R. Sutton, S. Bajt and P. Nuessle (1998) Selenium diffusion and reduction at the water-sediment boundary: Micro-XANES spectroscopy of reactive transport. Environ. Sci. Tech., 32, 1092-1098.

Wu, Z., Bonnin-Mosbah, M., Duraud, J., Metrich, N., and Delaney, J. (1999) XANES studies of Fe-bearing glasses. J. Synch. Rad., 6, 344-346.

Yun, W., S.T. Pratt, R.M. Miller, Z. Chai, D.B. Hunter, A.G. Jarstfer, K.M. Kemner, B. Lai, H.-R. Lee, D.G. Legnini, W. Rodriguez, and C.I. Smith (1998) Hard X-Ray Imaging and Microspectroscopy of micorrhizal symbionts. J. Synchrotron Research, 5, 1390-1395.


Beamline X26A receives support the following organizations:

Basic Energy Sciences Geosciences Research Program Office of Biological and Environmental Research

NASA Space Sciences