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Title: Kinetic isotope effects for hydrogen abstraction from various saturated hydrocarbons by deuterium atoms in the gas phase
Journal: Ber. Bunsenges. Phys. Chem.
Volume: 90
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986FUJ/GAU375
Reaction:
Cyclopentane + D → Cyclopentyl + HD
Reaction order:
2
Reference reaction:
Cyclopentane-d10 + D → D2 + Cyclopentyl-d9
Reference reaction order:
2
Temperature:
363 - 463
K
Pressure: 1.80E5 bar
Rate expression:
6.3x10-1±6.3x10-2 e8240 [±329 J/mole]/RT
Bath gas:
Ne
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Ultrasonics
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] | |
|---|---|---|
| 363 | 9.66 | |
| 375 | 8.85 | |
| 400 | 7.5 | |
| 425 | 6.49 | |
| 450 | 5.7 | |
| 463 | 5.36 |