[[pp. 68037-68086]] Standards of Performance for New Stationary Sources: Volatile
[Federal Register: December 9, 1998 (Volume 63, Number 236)]
[Proposed Rules]
[Page 68037-68086]
From the Federal Register Online via GPO Access [wais.access.gpo.gov]
[DOCID:fr09de98-31]
[[pp. 68037-68086]] Standards of Performance for New Stationary Sources: Volatile
Organic Compound Emissions From the Synthetic Organic Chemical
Manufacturing Industry Wastewater; Supplement to Proposed Rule
[[Continued from page 68036]]
[[Page 68037]]
(ii) The required mass removal is calculated by summing the
required mass removal for all wastewater streams combined for treatment
when complying with Sec. 60.779(g)(1)(i) or (g)(2) of this subpart.
(5) The AMR calculation procedure for non-combustion treatment
processes including closed biological treatment processes. The AMR
shall be calculated as follows:
[GRAPHIC] [TIFF OMITTED] TP09DE98.016
Where:
AMR=Actual mass removal of VOC achieved by treatment process or series
of treatment processes, kilograms per hour.
QMW<INF>a</INF>=Mass flow rate of VOC in wastewater entering the
treatment process or first treatment process in a series of treatment
processes, kilograms per hour.
QMW<INF>b</INF>=Mass flow rate of VOC in wastewater exiting the last
treatment process in a series of treatment processes, kilograms per
hour.
(6) Compare RMR to AMR. When complying with Sec. 60.779(f)(2)(i) or
(f)(3) of this subpart, compare the RMR calculated in Equation WW9 to
the AMR calculated in Equation WW10. Compliance is demonstrated if the
AMR is greater than or equal to the RMR. When complying with
Sec. 60.779(g)(1)(i) or (g)(2) of this subpart, compare the RMR
calculated in Equation WW9a to the AMR calculated in Equation WW10.
Compliance is demonstrated if the AMR is greater than or equal to 95-
percent mass removal.
(f) Open or closed aerobic biological treatment processes: Required
mass removal (RMR) option. This paragraph (f) applies to the use of
performance tests that are conducted for open or closed aerobic
biological treatment processes to demonstrate compliance with the mass
removal provisions for VOC. These compliance options are specified in
Sec. 60.779(f)(2)(i) and (f)(2)(ii) of this subpart. The owner or
operator shall comply with the requirements specified in paragraphs
(f)(1) through (f)(6) of this section. Some compounds may not require a
performance test. Refer to paragraph (h) of this section and Table 14
of this subpart to determine which compounds may be exempt from the
requirements of this paragraph (f).
(1) Concentration in wastewater stream. The concentration of VOC
shall be determined as provided in this paragraph (f)(1). Concentration
measurements to determine RMR shall be taken at the point of
determination or downstream of the point of determination with
adjustment for concentration change made according to Sec. 60.782(b)(6)
of this subpart. Concentration measurements to determine AMR shall be
taken at the inlet and outlet to the treatment process and as provided
in paragraph (a)(7) of this section for a series of treatment
processes. Wastewater samples shall be collected using sampling
procedures which minimize loss of organic compounds during sample
collection and analysis and maintain sample integrity per
Sec. 60.782(b)(5)(ii) of this subpart. The method shall be an
analytical method for wastewater which has that compound as a target
analyte. Samples may be grab samples or composite samples. Samples
shall be taken at approximately equally spaced time intervals over a 1-
hour period. Each 1-hour period constitutes a run, and the performance
test shall consist of a minimum of 3 runs.
(2) Flow rate. Flow rate measurements to determine RMR shall be
taken at the point of determination or downstream of the point of
determination with adjustment for flow rate change made according to
Sec. 60.782(c)(4) of this subpart. Flow rate measurements to determine
AMR shall be taken at the inlet and outlet to the treatment process and
as provided in paragraph (a)(7) of this section for a series of
treatment processes. Flow rate shall be determined using inlet and
outlet flow measurement devices. Where the outlet flow is not greater
than the inlet flow, a flow measurement device shall be used, and may
be used at either the inlet or outlet. Flow rate measurements shall be
taken at the same time as the concentration measurements.
(3) Calculation of RMR for open or closed aerobic biological
treatment processes. The required mass removal of VOC for each Group 1
wastewater stream shall be calculated using the following equation:
[GRAPHIC] [TIFF OMITTED] TP09DE98.017
Where:
RMR=Required mass removal for treatment process or series of treatment
processes, kilograms per hour.
<greek-r>=Density of the Group 1 wastewater stream, kilograms per cubic
meter.
Q=Volumetric flow rate of wastewater stream at the point of
determination, liters per hour.
i=Identifier for a compound.
n=Number of VOC in stream.
C<INF>i</INF>=Concentration of VOC at the point of determination, parts
per million by weight.
Fr<INF>i</INF>=Fraction removal value of a VOC. Follow the procedures
in Sec. 60.778 of this subpart to develop a stream-specific list of
VOC. Follow the procedures in appendix J of this part to determine Fr
values.
10 <SUP>9</SUP>=Conversion factor, mg/kg * l/m <SUP>3</SUP>.
(4) The required mass removal is calculated by adding together the
required mass removal for each Group 1 wastewater stream to be combined
for treatment.
(5) Actual mass removal calculation procedure for open or closed
aerobic biological treatment processes. The actual mass removal (AMR)
shall be calculated using Equation WW12 as specified in paragraph
(f)(5)(i) of this section when the performance test is performed across
the open or closed aerobic biological treatment process only. If
compliance is being demonstrated in accordance with paragraph (a)(7)(i)
of this section, the AMR for the series shall be calculated using
Equation WW13 in paragraph (f)(5)(ii) of this section. (This equation
is for situations where treatment is performed in a series of treatment
processes connected by hard-piping.) If compliance is being
demonstrated in accordance with paragraph (a)(7)(ii) of this section,
the AMR for the biological treatment process shall be calculated using
Equation WW12 in paragraph (f)(5)(i) of this section. The AMR for the
biological treatment process used in a series of treatment processes
calculated using Equation WW12 shall be added to the AMR determined for
each of the other individual treatment processes in the series of
treatment processes.
(i) Calculate AMR for the open or closed aerobic biological
treatment process as follows:
[GRAPHIC] [TIFF OMITTED] TP09DE98.018
Where:
AMR=Actual mass removal of VOC achieved by open or closed biological
treatment process, kilograms per hour.
QMW<INF>a</INF>=Mass flow rate of VOC in wastewater entering the
treatment process, kilograms per hour.
F<INF>bio</INF>=Site-specific fraction of VOC biodegraded.
F<INF>bio</INF> shall be determined as specified in paragraph (h) of
this section and 40 CFR part 63, appendix C. Follow the procedures in
Sec. 60.778 of this subpart to develop a stream-specific list of VOC.
(ii) Calculate AMR across a series of treatment units where the
last treatment
[[Page 68038]]
unit is an open or closed aerobic biological treatment process as
follows:
[GRAPHIC] [TIFF OMITTED] TP09DE98.019
Where:
AMR=Actual mass removal of VOC achieved by a series of treatment
processes, kilograms per hour.
QMW<INF>a</INF>=Mass flow rate of VOC in wastewater entering the first
treatment process in a series of treatment processes, kilograms per
hour.
QMW<INF>b</INF>=Mass flow rate of VOC in wastewater exiting the last
treatment process in a series of treatment processes prior to the
biological treatment process, kilograms per hour.
F<INF>bio</INF>=Site-specific fraction of VOC biodegraded.
F<INF>bio</INF> shall be determined as specified in paragraph (h) of
this section and 40 CFR part 63, appendix C. Follow the procedures in
Sec. 60.778 of this subpart to develop a stream-specific list of VOC.
(6) Compare RMR to AMR. Compare the RMR calculated in Equation WW11
to the AMR calculated in either Equation WW12 or WW13, as applicable.
Compliance is demonstrated if the AMR is greater than or equal to the
RMR.
(g) Open or closed aerobic biological treatment processes: 95-
percent mass removal option. This paragraph (g) applies to performance
tests that are conducted for open or closed aerobic biological
treatment processes to demonstrate compliance with the 95-percent mass
removal provisions for VOC. This compliance option is specified in
Sec. 60.779(g) of this subpart. The RMR for this option is 95-percent
mass removal. The owner or operator shall comply with the requirements
specified in paragraphs (g)(1) of this section to determine AMR,
paragraphs (e)(3)(ii) and (e)(4)(ii) of this section to determine RMR,
and paragraph (g)(2) of this section to determine whether compliance
has been demonstrated. Some compounds may not require a performance
test. Refer to paragraph (h) of this section and Table 14 of this
subpart to determine which compounds may be exempt from the
requirements of this paragraph (g).
(1) The owner or operator shall comply with the requirements
specified in paragraphs (f)(1), (f)(2), and (f)(5) of this section to
determine AMR. References to Group 1 wastewater streams shall be deemed
all wastewater streams combined for treatment for the purposes of this
paragraph (g)(1).
(2) Compare RMR to AMR. Compliance is demonstrated if the AMR is
greater than or equal to RMR.
(h) Site-specific fraction biodegraded (F<INF>bio</INF>). The VOC
are divided into two sets for the purposes of determining whether
F<INF>bio</INF> must be determined, and if F<INF>bio</INF> must be
determined, which procedures may be used to determine compound-specific
kinetic parameters. These sets are VOC in Table 14 of this subpart, and
all other VOC.
(1) Performance test exemption. If a biological treatment process
meets the requirements specified in paragraphs (h)(1)(i) and (h)(1)(ii)
of this section, the owner or operator is not required to determine
F<INF>bio</INF> and is exempt from the applicable performance test
requirements specified in Sec. 60.779 of this subpart.
(i) The biological treatment process meets the definition of
``enhanced biological treatment process'' in Sec. 60.771 of this
subpart.
(ii) At least 99 percent by weight of all VOC that are present in
the aggregate of all wastewater streams using the biological treatment
process to comply with Sec. 60.779 of this subpart are compounds on
Table 14 of this subpart.
(2) F<INF>bio</INF> determination. If a biological treatment
process does not meet the requirement specified in paragraph (h)(1)(i)
of this section, the owner or operator shall determine F<INF>bio</INF>
for the biological treatment process using the procedures in 40 CFR
part 63, appendix C, and paragraph (h)(2)(ii) of this section. If a
biological treatment process meets the requirements of paragraph
(h)(1)(i) of this section but does not meet the requirement specified
in paragraph (h)(1)(ii) of this section, the owner or operator shall
determine F<INF>bio</INF> for the biological treatment process using
the procedures in 40 CFR part 63, appendix C, and paragraph (h)(2)(i)
of this section.
(i) Enhanced biological treatment processes. If the biological
treatment process meets the definition of ``enhanced biological
treatment process'' in Sec. 60.771 of this subpart and the wastewater
streams include one or more compounds not on Table 14 of this subpart
that do not meet the criteria in paragraph (h)(1)(ii) of this section,
the owner or operator shall determine F<INF>bio</INF> for VOC not on
Table 14 of this subpart using any of the procedures specified in 40
CFR part 63, appendix C. (stream-specific list) (The symbol
F<INF>bio</INF> represents the site specific fraction of an individual
VOC that is biodegraded.) The owner or operator shall calculate
F<INF>bio</INF> for the VOC on Table 14 of this subpart using the
defaults provided for first order biodegradation rate constants (K1) of
this subpart and follow the procedure explained in Form III of 40 CFR
part 63, appendix C, or any of the procedures specified in 40 CFR part
63, appendix C.
(ii) Biological treatment processes that are not enhanced
biological treatment processes. For biological treatment processes that
do not meet the definition for ``enhanced biological treatment
process'' in Sec. 60.771 of this subpart, the owner or operator shall
determine the F<INF>bio</INF> for VOC on Table 14 of this subpart and
all other VOC using any of the procedures in 40 CFR part 63, appendix
C, except procedure 3 (inlet and outlet concentration measurements).
(i) Performance tests for control devices other than flares. This
paragraph (i) applies to performance tests that are conducted to
demonstrate compliance of a control device with the efficiency limits
specified in Sec. 60.780(c) of this subpart. If complying with the 95-
percent reduction efficiency requirement, comply with the requirements
specified in paragraphs (i)(1) through (i)(9) of this section. If
complying with the 20 ppm by volume requirement, comply with the
requirements specified in paragraphs (i)(1) through (i)(6) and (i)(9)
of this section. The 20 ppm by volume limit or 95 percent reduction
efficiency requirement shall be measured as either total VOC or as TOC
minus methane and ethane.
(1) Sampling sites. Sampling sites shall be selected using Method 1
or 1A of appendix A of this part, as appropriate. For determination of
compliance with the 95 percent reduction requirement, sampling sites
shall be located at the inlet and the outlet of the control device. For
determination of compliance with the 20 parts per million by volume
limit, the sampling site shall be located at the outlet of the control
device.
(2) Concentration in gas stream entering or exiting the control
device. The concentration of total VOC or TOC
[[Page 68039]]
in a gas stream shall be determined as provided in this paragraph
(i)(2). Samples may be grab samples or composite samples (i.e.,
integrated samples). Samples shall be taken at approximately equally
spaced time intervals over a 1-hour period. Each 1-hour period
constitutes a run, and the performance test shall consist of a minimum
of 3 runs. Concentration measurements shall be determined using Method
18, 40 CFR part 60, appendix A. Alternatively, any other test method
validated according to the procedures in Method 301, 40 CFR part 60,
appendix A may be used.
(3) Volumetric flow rate of gas stream entering or exiting the
control device. The volumetric flow rate of the gas stream shall be
determined using Method 2, 2A, 2C, or 2D, 40 CFR part 60, appendix A,
as appropriate. Volumetric flow rate measurements shall be taken at the
same time as the concentration measurements.
(4) Calculation of TOC concentration. The TOC concentration (CGT)
is the sum of the concentrations of the individual components. If
compliance is being determined based on TOC, the owner or operator
shall compute TOC for each run using the following equation:
[GRAPHIC] [TIFF OMITTED] TP09DE98.020
Where:
CG<INF>T</INF>=Total concentration of TOC (minus methane and ethane) in
vented gas stream, average of samples, dry basis, parts per million by
volume.
CGS<INF>i,j</INF>=Concentration of sample components in vented gas
stream for sample j, dry basis, parts per million by volume.
i=Identifier for a compound.
n=Number of components in the sample.
j=Identifier for a sample.
m=Number of samples in the sample run.
(5) Calculation of total VOC concentration. The owner or operator
determining compliance based on total VOC concentration (CVOC) shall
compute C VOC according to the Equation WW14.
(6) Percent oxygen correction for combustion control devices. If
the control device is a combustion device, comply with the requirements
specified in paragraph (i)(6)(i) of this section to determine oxygen
concentration, and in paragraph (i)(6)(ii) of this section to calculate
the percent oxygen correction.
(i) Oxygen concentration. The concentration of TOC or total VOC
shall be corrected to 3 percent oxygen if the control device is a
combustion device. The emission rate correction factor for excess air,
composite sampling (i.e., integrated sampling) and analysis procedures
of Method 3B, 40 CFR part 60, appendix A shall be used to determine the
actual oxygen concentration (%02d). The samples shall be taken during
the same time that the TOC (minus methane or ethane) or total VOC
samples are taken.
(ii) 3 percent oxygen calculation. The concentration corrected to 3
percent oxygen (CGc), when required, shall be computed using the
following equation:
[GRAPHIC] [TIFF OMITTED] TP09DE98.021
Where:
CG<INF>c</INF>=Concentration of TOC or VOC corrected to 3 percent
oxygen, dry basis, parts per million by volume.
CG<INF>T</INF>=Total concentration of TOC (minus methane and ethane) in
vented gas stream, average of samples, dry basis, parts per million by
volume.
%0<INF>2d</INF>=Concentration of oxygen measured in vented gas stream,
dry basis, percent by volume.
(7) Mass rate calculation. The mass rate of either TOC (minus
methane and ethane) or total VOC shall be calculated using the
following equations. Where the mass rate of TOC is being calculated,
all organic compounds (minus methane and ethane) measured by methods
specified in paragraph (i)(2) of this section are summed using
Equations WW16 and WW17.
[GRAPHIC] [TIFF OMITTED] TP09DE98.022
[GRAPHIC] [TIFF OMITTED] TP09DE98.023
Where:
CG<INF>a,i</INF>, CG<INF>b,i</INF>=Concentration of TOC (minus methane
and ethane) or total VOC, in vented gas stream, entering
(CG<INF>a,i</INF>) and exiting (CG<INF>b,i</INF>) the control device,
dry basis, parts per million by volume.
QMG<INF>a</INF>, QMG<INF>b</INF>=Mass rate of TOC (minus methane and
ethane) or total VOC, in vented gas stream, entering (QMG<INF>a</INF>)
and exiting (QMG<INF>b</INF>) the control device, dry basis, kilograms
per hour.
Mw<INF>i</INF>=Molecular weight of a component, kilogram/kilogram-mole.
QG<INF>a</INF>,QG<INF>b</INF>=Flow rate of gas stream entering
(QG<INF>a</INF>) and exiting (QG<INF>b</INF>) the control device, dry
standard cubic meters per hour.
K<INF>2</INF>=Constant, 41.57 x 10<SUP>-9</SUP> (parts per
million)<SUP>-1</SUP> (gram-mole per standard cubic meter) (kilogram/
gram), where standard temperature (gram-mole per standard cubic meter)
is 20 deg. Celsius.
i=Identifier for a compound.
n=Number of components in the sample.
(8) Percent reduction calculation. The percent reduction in TOC
(minus methane and ethane) or total VOC shall be calculated as follows:
[[Page 68040]]
[GRAPHIC] [TIFF OMITTED] TP09DE98.024
Where:
E=Destruction efficiency of control device, percent.
QMG<INF>a</INF>,QMG<INF>b</INF>=Mass rate of TOC (minus methane and
ethane) or total VOC, in vented gas stream entering and exiting
(QMG<INF>b</INF>) the control device, dry basis, kilograms per hour.
(9) Compare mass destruction efficiency to required efficiency. If
complying with the 95 percent reduction efficiency requirement,
compliance is demonstrated if the mass destruction efficiency
(calculated in Equation WW18) is 95 percent or greater. If complying
with the 20 parts per million by volume limit in Sec. 60.780(c) of this
subpart, compliance is demonstrated if the outlet total organic
compound concentration, less methane and ethane, or total VOC
concentration is 20 parts per million by volume, or less. For
combustion control devices, the concentration shall be calculated on a
dry basis, corrected to 3 percent oxygen.
(j) Compliance demonstration for flares. When a flare is used to
comply with Sec. 60.780(c) of this subpart, the owner or operator shall
comply with the flare provisions in 40 CFR 63.11(b) and table 2A of
this subpart, and with paragraphs (j)(1), (j)(2), and (j)(3) of this
section. An owner or operator is not required to conduct a performance
test to determine percent emission reduction or outlet VOC or TOC
concentration when a flare is used. If a compliance demonstration has
been conducted previously for a flare, using the techniques specified
in paragraphs (h)(1) through (h)(3) of this section, that compliance
demonstration may be used to satisfy the requirements of this paragraph
(j) if either no deliberate process changes have been made since the
compliance demonstration, or the results of the compliance
demonstration reliably demonstrate compliance despite process changes.
(1) The compliance determination shall be conducted as specified in
40 CFR 63.11(b)(4) and table 2A of this subpart, to determine visible
emissions.
(2) Determine the net heating value of the gas being combusted,
using the techniques specified in 40 CFR 63.11(b)(6) and table 2A of
this subpart; and
(3) Determine the exit velocity using the techniques specified in
either 40 CFR 63.11(b)(7)(i) (and 40 CFR 63.11(b)(7)(iii), where
applicable) or 40 CFR 63.11(b)(8), and table 2A of this subpart, as
appropriate.
Sec. 60.784 Reporting requirements.
(a) Owners or operators requesting approval to use alternative
monitoring, recordkeeping, or reporting shall comply with the
provisions in paragraph (b) of this section. Each owner or operator
shall submit the reports specified in paragraphs (a)(1) through (a)(4)
of this section, as applicable:
(1) Reports required by subpart A of part 60 of this part, as
specified in table 2 of this subpart,
(2) Reports of certain subpart A provisions of 40 CFR part 63, as
required by table 2A of this subpart,
(3) Reports required in paragraphs (c) through (g) of this section,
and
(4) Start-up, shutdown, and malfunction reports specified in
Sec. 60.787 of this subpart.
(b) Alternative monitoring and recordkeeping. An owner or operator
may request approval to use alternatives to the continuous operating
parameter monitoring and recordkeeping provisions of this subpart.
(1) Requests for approval to use alternatives to the continuous
monitoring and recordkeeping provisions shall be submitted prior to the
implementation of the alternative monitoring system for which approval
is being requested if not already included in the operating permit
application. The request shall contain the information specified in
paragraphs (b)(3) and (b)(4) of this section, as applicable.
(2) [Reserved]
(3) An owner or operator of an affected facility that does not have
an automated monitoring and recording system capable of measuring
parameter values at least once every 15 minutes and generating
continuous records may request approval to use a non-automated system
with less frequent monitoring.
(i) The requested system shall include manual reading and recording
of the value of the relevant operating parameter no less frequently
than once per hour. Daily average values shall be calculated from these
hourly values and recorded.
(ii) The request shall contain:
(A) A description of the planned monitoring and recordkeeping
system;
(B) Documentation that the affected facility does not have an
automated monitoring and recording system;
(C) Justification for requesting an alternative monitoring and
recordkeeping system; and
(D) Demonstration to the Administrator's satisfaction that the
proposed monitoring frequency is sufficient to represent control device
operating conditions considering typical variability of the specific
process and control device operating parameter being monitored.
(4) An owner or operator may request approval to use an automated
data compression recording system that does not record monitored
operating parameter values at a set frequency (for example once every
15 minutes) but records all values that meet set criteria for variation
from previously recorded values.
(i) The requested system shall be designed to:
(A) Measure the operating parameter value at least once every 15
minutes.
(B) Record at least four values each hour during periods of
operation.
(C) Record the date and time when monitors are turned off or on.
(D) Recognize unchanging data that may indicate the monitor is not
functioning properly, alert the operator, and record the incident.
(E) Compute daily average values of the monitored operating
parameter based on recorded data.
(F) If the daily average is not an excursion, as defined in
paragraphs (d)(3)(i) through (d)(3)(iii) of this section, the data for
that operating day may be converted to hourly average values and the
four or more individual records for each hour in the operating day may
be discarded.
(ii) The request shall contain a description of the monitoring
system and data compression recording system, including the criteria
used to determine which monitored values are recorded and retained, the
method for calculating daily averages, and a demonstration that the
system meets all criteria in paragraph (b)(4)(i) of this section.
(5) [Reserved]
(6) For each waste management unit, treatment process, or control
device used to comply with Secs. 60.774 through 60.775 of this subpart
for which the owner or operator seeks to monitor a parameter other than
those specified in Table 5, Table 7, and Table 8 of this subpart, the
owner or operator shall submit a request for approval to monitor
alternative parameters. The owner or operator who requests approval to
[[Page 68041]]
monitor a different parameter than those listed in Table 5, Table 7,
and Table 8 of this subpart shall submit the information specified in
paragraphs (b)(6)(i), (ii), and (iii) of this section.
(i) A description of the parameter(s) to be monitored to ensure the
waste management unit, treatment process, or control device measure is
operated in conformance with its design and achieves the specified
emission limit, percent reduction, or nominal efficiency, and an
explanation of the criteria used to select the parameter(s).
(ii) A description of the methods and procedures that will be used
to demonstrate that the parameter indicates proper operation of the
waste management unit, treatment process, or control device, the
schedule for this demonstration, and a statement that the owner or
operator will establish, as part of the demonstration, an operating
parameter value for the monitored parameter that indicates proper
operation and maintenance of the unit, process, or device.
(iii) The frequency and content of monitoring, recording, and
reporting if monitoring and recording is not continuous, or if
semiannual reports required under paragraph (d) of this section will
not include reports of daily average values when the monitored
operating parameter is not above or below (as appropriate) the
operating parameter value established in paragraph (c)(7)(ii) of this
section. The rationale for the proposed monitoring, recording, and
reporting system shall be included.
(c) Notification of Compliance Status. Each owner or operator
subject to this subpart shall submit a Notification of Compliance
Status within 150 days after the compliance dates specified in
Sec. 60.770(a) of this subpart. The Notification of Compliance Status
shall include the results of any emission point group determinations,
performance tests, inspections, continuous monitoring system
performance evaluations, values of monitored parameters established
during performance tests, and any other information specified in
paragraphs (c)(1) through (c)(14) of this section used to demonstrate
compliance or required to be included in the Notification of Compliance
Status.
(1) The owner or operator shall identify each designated CPU and
list the components in the designated CPU. The owner or operator shall
identify each affected facility and describe the process wastewater,
maintenance wastewater, and aqueous in-process streams generated by the
affected facility. The information shall clearly link all applicable
CPU, designated CPU, and affected facilities and demonstrate that all
components of a CPU were assigned to a designated CPU.
(2) For each affected facility, the owner or operator shall submit
the information specified in Table 9 of this subpart for each
wastewater stream generated.
(3) For each treatment process identified in Table 9 of this
subpart that receives, manages, or treats a wastewater stream (i.e.,
Group 1 wastewater stream or Group 2 wastewater stream selected by the
owner or operator for control) or residual removed from a wastewater
stream, the owner or operator shall submit the information specified in
Table 10 of this subpart.
(4) For each waste management unit identified in Table 9 of this
subpart that receives or manages a wastewater stream (i.e., Group 1
wastewater stream or Group 2 wastewater stream selected by the owner or
operator for control) or residual removed from a wastewater stream, the
owner or operator shall submit the information specified in Table 11 of
this subpart.
(5) For each waste management unit identified in table 9 of this
subpart, the owner or operator shall include in the Notification of
Compliance Status the compliance option that will be used to comply
with Sec. 60.774 of this subpart, and the applicable provisions of
other subparts that the owner or operator will use to comply with the
compliance option, as allowed in Sec. 60.774 of this subpart.
(6) For each residual removed from a wastewater stream (i.e., Group
1 wastewater stream or Group 2 wastewater stream selected by the owner
or operator for control), the owner or operator shall submit the
information specified in Table 12 of this subpart.
(7) For each control device used to comply with Secs. 60.774,
60.775, and 60.779 of this subpart, the owner or operator shall submit
the information specified in paragraphs (c)(7)(i) and (c)(7)(ii) of
this section.
(i) For each flare, the owner or operator shall submit the
information specified in paragraphs (c)(7)(i)(A) through (c)(7)(i)(C)
of this section.
(A) Flare design (i.e., steam-assisted, air-assisted, or non-
assisted);
(B) All visible emission readings, heat content determinations,
flow rate measurements, and exit velocity determinations made during
the compliance determination as specified by Sec. 60.780(c)(3) of this
subpart; and
(C) Reports of the times and durations of all periods during the
compliance determination when the pilot flame is absent or the monitor
is not operating.
(ii) For each control device other than a flare, the owner or
operator shall submit the information specified in paragraph
(c)(7)(ii)(A) of this section and in either paragraph (c)(7)(ii)(B) or
(c)(7)(ii)(C) of this section.
(A) The information in paragraphs (c)(7)(ii)(A)(1), (2), and (3) of
this section on operating parameter values required to be established
under Sec. 60.781(f) of this subpart for the applicable parameters
specified in Table 8 of this subpart, unless the operating parameter
value has already been established in the operating permit.
(1) The specific operating parameter value of the monitored
parameter(s) for each emission point;
(2) The rationale for the specific operating parameter value for
each parameter for each emission point, including any data and
calculations used to develop the value and a description of why the
value indicates proper operation of the control device.
(i) If a performance test is conducted for a control device, the
operating parameter value shall be based on the parameter values
measured during the performance test supplemented by engineering
analyses and/or manufacturer's recommendations. Performance testing is
not required to be conducted over the entire range of permitted
parameter values.
(ii) If a performance test is not conducted for a control device,
the operating parameter value may be based solely on engineering
analyses and/or manufacturer's recommendations.
(3) A definition of the affected facility's operating day for
purposes of determining daily average values of monitored parameters.
The definition shall specify the times at which an operating day begins
and ends.
(B) The design evaluation specified in Sec. 60.780(d)(2) of this
subpart; or
(C) Results of the performance test specified in Sec. 60.780(d)(1)
of this subpart. Performance test results shall include operating
ranges of key process and control parameters during the performance
test; the value, averaged over the period of the performance test, of
each parameter identified in the operating permit as being monitored in
accordance with Sec. 60.781 of this subpart; and applicable supporting
calculations.
(8) For each treatment process used to comply with this subpart,
the owner or operator shall submit the information specified in
paragraphs (c)(8)(i) and (c)(8)(ii) of this section.
(i) For Items 1 and 2 in Table 7 of this subpart, the owner or
operator shall
[[Page 68042]]
submit the information specified in paragraphs (c)(8)(i)(A) and
(c)(8)(i)(B) of this section.
(A) The information specified in paragraph (c)(6)(ii)(A) of this
section for the operating parameter value required to be established
under Sec. 60.781(f) of this subpart for the monitoring parameters
approved by the Administrator, unless the operating parameter value has
already been established in the operating permit.
(B) Results of the initial measurements of the parameters approved
by the Administrator and any applicable supporting calculations.
(ii) For Item 3 in Table 7 of this subpart, the owner or operator
shall submit the information specified in paragraph (c)(7)(ii)(A) of
this section for the monitored operating parameter values required to
be established under Sec. 60.781(f) of this subpart, unless the
operating parameter value has already been established in the operating
permit.
(9) Except as provided in paragraph (c)(9)(iii) of this section,
for each waste management unit or treatment process used to comply with
this subpart, the owner or operator shall submit the information
specified in either paragraph (c)(9)(i) or (c)(9)(ii) of this section.
(i) The design evaluation and supporting documentation specified in
Sec. 60.779(j)(1) of this subpart.
(ii) Results of the performance test specified in Sec. 60.779(j)(2)
of this subpart. Performance test results shall include operating
ranges of key process and control parameters during the performance
test; the value, averaged over the period of the performance test, of
each parameter identified in the operating permit as being monitored in
accordance with Sec. 60.781(f) of this subpart; and applicable
supporting calculations.
(iii) If the owner or operator elects to use one of the options for
treatment in a RCRA unit specified in Sec. 60.779(h) of this subpart,
the owner or operator is exempt from the requirements specified in
paragraphs (c)(9)(i) and (c)(9)(ii) of this section.
(10) For performance tests and group determinations that are based
on measurements, and for estimates of VOC emissions, the Notification
of Compliance Status shall include one complete test report for each
test method used for a particular kind of emission point. For
additional tests performed for the same kind of emission point using
the same method, the results and any other information required shall
be submitted, but a complete test report is not required. A complete
test report shall include a brief process description, sampling site
description, description of sampling and analysis procedures and any
modifications to standard procedures, quality assurance procedures,
record of operating conditions during the test, record of preparation
of standards, record of calibrations, raw data sheets for field
sampling, raw data sheets for field and laboratory analyses,
documentation of calculations, and any other information required by
the test method.
(11) An owner or operator who transfers a Group 1 wastewater stream
or residual removed from a Group 1 wastewater stream for treatment
pursuant to Sec. 60.773(e) shall include in the Notification of
Compliance Status the name and location of the transferee and a
description of the Group 1 wastewater stream or residual removed from a
Group 1 wastewater stream sent to the treatment facility.
(12) The owner or operator who chooses to comply with the
provisions in Sec. 60.789 of this subpart shall include in the
Notification of Compliance Status a statement specifying which
regulation(s) is being used to comply with this subpart.
(13) Notification that the owner or operator has elected to comply
with the reduced recordkeeping program in 60.785(j) of this subpart.
(14) Notification of the waste management unit compliance option
used to comply with the provisions of this subpart, as specified in
Sec. 60.774 of this subpart, shall be submitted in the Notification of
Compliance Status. If the owner or operator is complying with the
recordkeeping and reporting provisions of a rule other than this
subpart, as specified in Sec. 60.774 of this subpart, a statement
containing this information shall be submitted.
(d) Semiannual reports. Each owner or operator subject to the
provisions of this subpart shall submit to the Administrator semiannual
reports. The reports shall be submitted semiannually no later than 60
calendar days after the end of each 6-month period. The first report
shall be submitted no later than 8 months after the due date of the
notification of initial start-up required by Sec. 60.7(a)(3) of this
part and shall cover the 6-month period beginning on the due date of
the notification of initial start-up.
(1) [Reserved]
(2) The semiannual report shall include reports of all excursions
and all periods when monitoring parameters are above the maximum or
below the minimum established value.
(3) The semiannual report shall include the daily average values of
monitored parameters for all excursions, as defined by paragraphs
(d)(3)(i), (d)(3)(ii), or (d)(3)(iii) of this section. For excursions
caused by lack of monitoring data, the duration of periods when
monitoring data were not collected shall be reported. For a control
device where multiple parameters are monitored, if one or more of the
parameters meets the excursion criteria in paragraphs (d)(3)(i),
(d)(3)(ii), or (d)(3)(iii) of this section, this is considered a single
excursion for the control device.
(i) When the daily average value of one or more monitored
parameters is above the maximum or below the minimum (as appropriate)
established operating parameter value.
(ii) When the period of control device operation is 4 hours or
greater in an operating day and monitoring data are insufficient to
constitute a valid hour of data for at least 75 percent of the
operating hours.
(iii) When the period of control device operation is less than 4
hours in an operating day and more than one of the hours during the
period of operation does not constitute a valid hour of data due to
insufficient monitoring data.
(iv) Monitoring data are insufficient to constitute a valid hour of
data, as used in paragraphs (d)(3)(ii) and (d)(3)(iii) of this section,
if measured values are unavailable for any of the 15-minute periods
within the hour. For data compression systems approved under paragraph
(b)(4) of this section, monitoring data are insufficient to calculate a
valid hour of data if there are less than 4 data values recorded during
the hour.
(4) Each control device is allowed one excused excursion per
semiannual period. The first semiannual period is the 6-month period
covered by the first semiannual report.
(5)(i) Paragraphs (d)(5)(i)(A) through (d)(5)(i)(D) of this section
specify when an excursion is not a violation. In cases where continuous
monitoring is required, the excursion does not count toward the number
of excused excursions for determining compliance.
(A) If a monitored parameter is below the minimum established value
and the affected facility is operated during such period in accordance
with the affected facility's start-up, shutdown, and malfunction plan,
(B) If a monitored parameter is above the maximum established value
and the affected facility is operated during such period in accordance
with the affected facility's start-up, shutdown, and malfunction plan,
(C) If monitoring data are not collected during periods of start-
up, shutdown, or malfunction and the
[[Page 68043]]
affected facility is operated during such period in accordance with the
affected facility's start-up, shutdown, and malfunction plan, or
(D) If cessation of the emissions to which the monitoring applies
occurs during periods of non-operation of the chemical process unit or
portion thereof.
(ii) Nothing in paragraphs (d)(3) through (d)(5) of this section
shall be construed to allow or excuse a monitoring parameter excursion
caused by any activity that violates other applicable provisions of
this subpart.
(iii) Paragraphs (d)(3) through (d)(5) of this section, except
paragraph (d)(5)(i) of this section, shall apply only to emission
points and control devices for which continuous monitoring is required
by this subpart.
(6) The semiannual report shall include results of any performance
tests conducted during the reporting period including one complete
report for each test method used for a particular kind of emission
point tested. For additional tests performed for a similar emission
point using the same method, results and any other information required
shall be submitted, but a complete test report is not required. A
complete test report shall contain a brief process description,
sampling site data, description of sampling and analysis procedures and
any modifications to standard procedures, quality assurance procedures,
record of operating conditions during the test, record of preparation
of standards, record of calibrations, raw data sheets for field
sampling, raw data sheets for field and laboratory analyses,
documentation of calculations, and any other information required by
the test method.
(7) The semiannual report shall include notification that the owner
or operator has elected to comply with the reduced recordkeeping
program in Sec. 60.785(j) of this subpart.
(8) The semiannual report shall include notification that the owner
or operator has elected not to retain the daily average values, as
specified in Sec. 60.785(j)(2)(i) of this subpart.
(9) The semiannual report shall include periods recorded under
Sec. 60.785(f)(10) of this subpart when the vent is diverted from the
control device through a bypass line, with the next semiannual report.
(10) The semiannual report shall include notification of all
occurrences recorded under Sec. 60.785(f)(11) of this subpart in which
the seal mechanism is broken, the bypass line damper or valve position
has changed, or the key to unlock the bypass line damper or valve was
checked out, with the next semiannual report.
(11) The semiannual report shall include notification that
semiannual report information for waste management units will be
submitted with semiannual reports required by another rule that is one
of the compliance options for waste management units as specified in
Sec. 60.784 of this subpart.
(12) The semiannual report shall include notification of each
affected facility that ceases to generate at least one process
wastewater stream or aqueous in-process stream or no longer produces a
primary product that is a SOCMI product.
(e) Semiannual reporting for treatment processes. Except as
provided in paragraph (g) of this section, for each treatment process
used to comply with this subpart, the owner or operator shall submit as
part of the next semiannual report required by paragraph (d) of this
section the information specified in paragraphs (e)(1) and (e)(2) of
this section.
(1) For Item 1 in Table 7 of this subpart, the owner or operator
shall submit the results of measurements that indicate that the
biological treatment unit is outside the parameters established in the
Notification of Compliance Status or operating permit.
(2) For Item 2 in Table 7 of this subpart, the owner or operator
shall submit the monitoring results for each operating day during which
the daily average value of any monitored parameter was above the
maximum or below the minimum operating parameter value established in
the Notification of Compliance Status or operating permit.
(3) For Item 3 in Table 7 of this subpart, the owner or operator
shall submit the monitoring results for each operating day during which
the daily average value of any monitored parameter specified in Item 3
of Table 7 of this subpart was above the maximum or below the minimum
(as appropriate) operating parameter value established in the
Notification of Compliance Status or operating permit.
(f) Semiannual reporting for control devices. Except as provided in
paragraph (g) of this section, for each control device used to comply
with Secs. 60.774 through 60.780 of this subpart, the owner or operator
shall submit as part of the next semiannual report required by
paragraph (d) of this section the information specified in either
paragraph (f)(1) or (f)(2) of this section.
(1) The information specified in Table 13 of this subpart, or
(2) If the owner or operator elects to comply with
Sec. 60.781(e)(2) of this subpart, i.e., an organic monitoring device
installed at the outlet of the control device, the owner or operator
shall submit the monitoring results for each operating day during which
the daily average concentration level or reading is above the maximum
or below the minimum (as appropriate) operating parameter value
established as a requirement of Sec. 60.781(f) of this subpart or
established in the facility's operating permit.
(g) Where the owner or operator obtains approval to use a treatment
process or control device other than one for which monitoring
requirements are specified in Sec. 60.781 of this subpart, or to
monitor parameters other than those specified in Table 7 or 8 of this
subpart, the owner or operator shall comply with the appropriate
reporting requirements established by the Administrator.
Sec. 60.785 Recordkeeping requirements.
(a) Data retention requirements are specified in paragraph (b) of
this section. Each owner or operator shall keep the records specified
in paragraphs (a)(1) through (a)(4) of this section, as applicable:
(1) Records required by subpart A of part 60 of this part, as
specified in table 2 of this subpart,
(2) Records of certain subpart A provisions of 40 CFR part 63, as
required by table 2A of this subpart,
(3) Records required in paragraphs (c) through (j) of this section,
and
(4) Start-up, shutdown, and malfunction records specified in
Sec. 60.787 of this subpart.
(b) Data retention. Unless otherwise specified in this subpart,
each owner or operator of an affected facility shall keep copies of all
applicable records and reports required by this subpart for at least 5
years. All applicable records shall be maintained in such a manner that
they can be readily accessed. Records of the most recent 2 years shall
be retained onsite or shall be accessible to an inspector while onsite.
The records of the remaining 3 years may be retained offsite. Records
may be maintained in hard copy or computer-readable form including, but
not limited to, on paper, microfilm, computer, floppy disk, magnetic
tape, or microfiche.
(c) Miscellaneous records. The owner or operator shall keep the
records specified in paragraphs (c)(1) through (c)(8) of this section.
(1) A record that each waste management unit inspection required by
Sec. 60.774 of this subpart was performed.
[[Page 68044]]
(2) A record that each inspection for control devices required by
Sec. 60.780(f) of this subpart was performed.
(3) For Item 1 and Item 2 of Table 7 of this subpart, the owner or
operator shall keep the records approved by the Administrator.
(4) Except as provided in paragraph (c)(5) of this section,
continuous records of the monitored parameters specified in Item 3 of
Table 7, in Table 8, or in Sec. 60.781(e)(2) of this subpart, as
appropriate.
(5) Where the owner or operator obtains approval to use a treatment
process or control device other than one for which monitoring
requirements are specified in Sec. 60.781 of this subpart, or to
monitor parameters other than those specified in Table 7 or Table 8 of
this subpart, the owner or operator shall comply with the recordkeeping
requirements established by the Administrator as part of the review of
the permit application or other appropriate means.
(6) The owner or operator who is complying with the provisions in
Sec. 60.789(c)(1) of this subpart shall keep a record of the
information used to determine which control, testing, monitoring,
recordkeeping, and reporting requirements are the most stringent.
(7) Documentation of a decision to use a delay of repair due to
unavailability of parts, as specified in Sec. 60.777(c) of this
subpart, shall include a description of the failure, the reason
additional time was necessary (including a statement of why replacement
parts were not kept on site and when the manufacturer promised
delivery), the date when repair would have been completed if parts had
been available, and the date when repair was completed.
(8) The owner or operator shall keep a record of each affected
facility that ceases to generate at least one process wastewater stream
or aqueous in-process stream or no longer produces a primary product
that is a SOCMI product.
(d) Record of notice sent to treatment operator. The owner or
operator transferring a Group 1 wastewater stream or residual removed
from a Group 1 wastewater stream in accordance with Sec. 60.773(e) of
this subpart shall keep a record of the notice sent to the treatment
operator stating that the wastewater stream or residual contains VOC
which are required to be managed and treated in accordance with the
provisions of this subpart.
(e) Control device records. For each control device used to comply
with this subpart, the owner or operator shall keep a record of the
information specified in paragraphs (e)(1) through (e)(3) of this
section.
(1) Identification of all parts of the control device that are
designated as unsafe to inspect, as specified in Sec. 60.786(g) of this
subpart, an explanation stating why the equipment is unsafe to inspect,
and the plan for inspecting the equipment.
(2) Identification of all parts of the control device that are
designated as difficult to inspect, as specified in Sec. 60.786(h) of
this subpart, an explanation stating why the equipment is difficult to
inspect, and the plan for inspecting the equipment.
(3) For each boiler or process heater used to comply with this
subpart, the owner or operator shall keep a record of any changes in
the location at which the vent stream is introduced into the flame
zone.
(f) Continuous records. Owners or operators required to keep
continuous records by any section of this subpart shall keep records as
specified in paragraphs (f)(1) through (f)(11) of this section, unless
an alternative recordkeeping system has been requested and approved
under Sec. 60.784(b) of this subpart, except as provided in
Sec. 60.784(d)(5)(i) of this subpart.
(1) The monitoring system shall measure data values at least once
every 15 minutes.
(2) The owner or operator shall record either:
(i) Each measured data value; or
(ii) Block average values for 15-minute or shorter periods
calculated from all measured data values during each period or at least
one measured data value per minute if measured more frequently than
once per minute.
(3) If the daily average value of a monitored parameter for a given
operating day is below the maximum or above the minimum established
value in the report required by Sec. 60.784(c) of this subpart or the
operating permit, the owner or operator shall either:
(i) Retain block hourly average values for that operating day for 5
years and discard, at or after the end of that operating day, the 15-
minute or more frequent average values and readings recorded under
paragraph (f)(2) of this section; or
(ii) Retain the data recorded in paragraph (f)(2) of this section
for 5 years.
(4) If the daily average value of a monitored parameter for a given
operating day is above the maximum or below the minimum established
value in the report required by Sec. 60.784(c) of this subpart or
operating permit, the owner or operator shall retain the data recorded
that operating day under paragraph (f)(2) of this section for 5 years.
(5) Daily average values of each continuously monitored parameter
shall be calculated for each operating day, and retained for 5 years,
except as specified in paragraphs (f)(6) and (f)(7) of this section.
(i) The daily average shall be calculated as the average of all
values for a monitored parameter recorded during the operating day. The
average shall cover a 24-hour period if operation is continuous, or the
number of hours of operation per operating day if operation is not
continuous.
(ii) The operating day shall be the period defined in the operating
permit or the report required by Sec. 60.784(c) of this subpart. It may
be from midnight to midnight or another daily period.
(6) If all recorded values for a monitored parameter during an
operating day are below the maximum or above the minimum established
value in the report required by Sec. 60.784(c) of this subpart or
operating permit, the owner or operator may record this fact and retain
this record for 5 years rather than calculating and recording a daily
average for that operating day. For these operating days, the records
required in paragraph (f)(3) of this section shall also be retained for
5 years.
(7) Monitoring data recorded during periods identified in
paragraphs (f)(7)(i) through (f)(7)(v) of this section shall not be
included in any average computed under this subpart. Records shall be
kept of the times and durations of all such periods and any other
periods during process or control device operation when monitors are
not operating.
(i) Monitoring system breakdowns, repairs, calibration checks, and
zero (low-level) and high-level adjustments:
(ii) Start-ups;
(iii) Shutdowns;
(iv) Malfunctions;
(v) Periods of non-operation of the chemical process unit (or
portion thereof), resulting in cessation of the emissions to which the
monitoring applies.
(8) For flares, records of the times and duration of all periods
during which all pilot flames are simultaneously absent shall be kept
rather than daily averages.
(9) For carbon adsorbers, the owner or operator shall keep the
records specified in paragraphs (e)(9)(i) and (e)(9)(ii) of this
section instead of daily averages.
(i) Records of the total regeneration stream mass flow for each
carbon bed regeneration cycle.
[[Page 68045]]
(ii) Records of the temperature of the carbon bed after each
regeneration cycle.
(10) Hourly records of whether the flow indicator for bypass lines
specified in Sec. 60.786(f)(1) of this subpart was operating and
whether a diversion was detected at any time during the hour. Also,
records of the times of all periods when the vent is diverted from the
control device or the flow indicator specified in Sec. 60.786(f)(1) of
this subpart is not operating.
(11) Where a seal or closure mechanism is used to comply with
Sec. 60.786(f)(2) of this subpart, hourly records of whether a
diversion was detected at any time are not required. The owner or
operator shall record whether the monthly visual inspection of the
seals or closure mechanisms has been done, and shall record the
occurrence of all periods when the seal mechanism is broken, the bypass
line damper or valve position has changed, or the key for a lock-and-
key type configuration has been checked out, and records of any car-
seal that has broken.
(g) Process knowledge records. If the owner or operator determines
that a wastewater stream is not a Group 1 wastewater stream by using
process knowledge to determine the annual average concentration of a
wastewater stream as specified in Sec. 60.782(b)(3) of this subpart
and/or uses process knowledge to determine the annual average flow rate
as specified in Sec. 60.782(c)(1) of this subpart, the owner or
operator shall keep the documentation of how process knowledge was used
to determine the annual average concentration and/or the annual average
flow rate of the wastewater stream as specified in Sec. 60.782(b)(3) or
(c)(1) of this subpart, as appropriate.
(h) Continuous monitoring system records. For continuous monitoring
systems used to comply with this subpart, records documenting the
completion of calibration checks, and records documenting the
maintenance of continuous monitoring systems that are specified in the
manufacturer's instructions or that are specified in other written
procedures that provide adequate assurance that the equipment would
reasonably be expected to monitor accurately.
(i) [Reserved]
(j) Reduced recordkeeping program. For any parameter with respect
to any item of equipment, the owner or operator may implement the
recordkeeping requirements specified in paragraph (j)(1) or (j)(2) of
this section as alternatives to the continuous operating parameter
monitoring and recordkeeping provisions specified in this subpart. The
owner or operator shall retain for a period of 5 years each record
required by paragraph (j)(1) or (j)(2) of this section.
(1) The owner or operator may retain only the daily average value,
and is not required to retain more frequent monitored operating
parameter values, for a monitored parameter with respect to an item of
equipment, if the requirements of paragraphs (j)(1)(i) through
(j)(1)(vi) of this section are met. An owner or operator electing to
comply with the requirements of paragraph (j)(1) of this section shall
notify the Administrator in the Notification of Compliance Status as
specified in Sec. 60.784(c)(13) of this subpart or, if the Notification
of Compliance Status has already been submitted, in the semiannual
report immediately preceding implementation of the requirements of
paragraph (j)(1) of this section as specified in Sec. 60.784(d)(7) of
this subpart.
(i) The monitoring system is capable of detecting unrealistic or
impossible data during periods of operation other than start-ups,
shutdowns, or malfunctions (e.g., a temperature reading of -200 deg.C
on a boiler), and will alert the operator by alarm or other means. The
owner or operator shall record the occurrence. All instances of the
alarm or other alert in an operating day constitute a single
occurrence.
(ii) The monitoring system generates, updated at least hourly
throughout each operating day, a running average of the monitoring
values that have been obtained during that operating day, and the
capability to observe this running average is readily available to the
Administrator on-site during the operating day. The owner or operator
shall record the occurrence of any period meeting the criteria in
paragraphs (j)(1)(ii)(A) through (j)(1)(ii)(C) of this section. All
instances in an operating day constitute a single occurrence.
(A) The running average is above the maximum or below the minimum
established limits;
(B) The running average is based on at least six 1-hour average
values; and
(C) The running average reflects a period of operation other than a
start-up, shutdown, or malfunction.
(iii) The monitoring system is capable of detecting unchanging data
during periods of operation other than start-ups, shutdowns, or
malfunctions, except in circumstances where the presence of unchanging
data is the expected operating condition based on past experience
(e.g., pH in some scrubbers), and will alert the operator by alarm or
other means. The owner or operator shall record the occurrence. All
instances of the alarm or other alert in an operating day constitute a
single occurrence.
(iv) The monitoring system will alert the owner or operator by an
alarm or other means, if the running average parameter value calculated
under paragraph (j)(1)(ii) of this section reaches a set point that is
appropriately related to the established limit for the parameter that
is being monitored.
(v) The owner or operator shall verify the proper functioning of
the monitoring system, including its ability to comply with the
requirements of paragraph (j)(1) of this section, at the times
specified in paragraphs (j)(1)(v)(A) through (j)(1)(v)(C). The owner or
operator shall document that the required verifications occurred.
(A) Upon initial installation.
(B) Annually after initial installation.
(C) After any change to the programming or equipment constituting
the monitoring system, which might reasonably be expected to alter the
monitoring system's ability to comply with the requirements of this
section.
(vi) The owner or operator shall retain the records identified in
paragraphs (j)(1)(vi)(A) through (j)(1)(vi)(D) of this section.
(A) Identification of each parameter, for each item of equipment,
for which the owner or operator has elected to comply with the
requirements of paragraph (j) of this section.
(B) A description of the applicable monitoring system(s), and of
how compliance will be achieved with each requirement of paragraphs
(j)(1)(i) through (j)(1)(v) of this section. The description shall
identify the location and format (e.g., on-line storage, log entries)
for each required record. If the description changes, the owner or
operator shall retain both the current and the most recent superseded
description, as provided in paragraph (a) of this section, except as
provided in paragraph (j)(1)(vi)(D) of this section.
(C) A description, and the date, of any change to the monitoring
system that would reasonably be expected to impair its ability to
comply with the requirements of paragraph (j)(1) of this section.
(D) Owners and operators subject to paragraph (j)(1)(vi)(B) of this
section shall retain the current description of the monitoring system
as long as the description is current, but not less than 5 years from
the date of its creation. The current description shall, at all times,
be retained on-site or be accessible from a central location by
computer or other means that provides access within 2
[[Page 68046]]
hours after a request. The owner or operator shall retain all
superseded descriptions for at least 5 years after the date of their
creation. Superseded descriptions shall be retained on-site (or
accessible from a central location by computer or other means that
provides access within 2 hours after a request) for at least 6 months
after their creation. Thereafter, superseded descriptions may be stored
off-site.
(2) If an owner or operator has elected to implement the
requirements of paragraph (j)(1) of this section for a monitored
parameter with respect to an item of equipment and a period of 6
consecutive months has passed without an excursion as defined in
paragraph (j)(2)(iv) of this section, the owner or operator is no
longer required to record the daily average value for any operating day
when the daily average value is less than the maximum or greater than
the minimum established limit. With approval by the Administrator,
monitoring data generated prior to the compliance date of this subpart
shall be credited toward the period of 6 consecutive months, if the
parameter limit and the monitoring accomplished during the period prior
to the compliance date was required and/or approved by the
Administrator.
(i) If the owner or operator elects not to retain the daily average
values, the owner or operator shall notify the Administrator in the
next semiannual report as specified in Sec. 60.784(d)(8) of this
subpart. The notification shall identify the parameter and unit of
equipment.
(ii) If, on any operating day after the owner or operator has
ceased recording daily average values as provided in paragraph (j)(2)
of this section, there is an excursion as defined in paragraph
(j)(2)(iv) of this section, the owner or operator shall immediately
resume retaining the daily average value for each operating day and
shall notify the Administrator in the next semiannual report. The owner
or operator shall continue to retain each daily average value until
another period of 6 consecutive months has passed without an excursion
as defined in paragraph (j)(2)(iv) of this section.
(iii) The owner or operator shall retain the records specified in
paragraphs (j)(1)(i) through (j)(1)(iv) of this section, for the
duration specified in paragraph (j) of this section. For any calendar
week, if compliance with paragraphs (j)(1)(i) through (j)(1)(iv) of
this section does not result in retention of a record of at least one
occurrence or measured parameter value, the owner or operator shall
record and retain at least one parameter value during a period of
operation other than a start-up, shutdown, or malfunction.
(iv) For purposes of paragraph (j) of this section, an excursion
means that the daily average value of monitoring data for a parameter
is greater than the maximum, or less than the minimum established
value, except that the daily average value during any start-up,
shutdown, or malfunction shall not be considered an excursion for
purposes of paragraph (j)(2) of this section, if the owner or operator
follows the applicable provisions of the start-up, shutdown, and
malfunction plan required by Sec. 60.787 of this subpart. An excused
excursion, as described in Sec. 60.784(d)(4) of this subpart, shall not
be considered an excursion for purposes of this paragraph (j)(2).
Sec. 60.786 Leak inspection provisions.
(a) For each vapor collection system, closed-vent system, fixed
roof, cover, or enclosure required to comply with this section, the
owner or operator shall comply with the requirements of paragraphs (b)
through (i) of this section, unless otherwise specified in this
subpart.
(b) Except as provided in paragraphs (g) and (h) of this section,
each vapor collection system and closed-vent system shall be inspected
according to the procedures and schedule specified in paragraphs (b)(1)
and (b)(2) of this section and each fixed roof, cover, and enclosure
shall be inspected according to the procedures and schedule specified
in paragraph (b)(3) of this section.
(1) If the vapor collection system or closed vent system is
constructed of hard-piping, the owner or operator shall:
(i) Conduct an initial inspection according to the procedures in
paragraph (c) of this section; and
(ii) Conduct annual visual inspections for visible, audible, or
olfactory indications of leaks.
(2) If the vapor collection system or closed vent system is
constructed of duct work, the owner or operator shall:
(i) Conduct an initial inspection according to the procedures in
paragraph (c) of this section, and
(ii) Conduct annual visual inspections for visible, audible, or
olfactory indications of leaks.
(2) If the vapor collection system or closed vent system is
constructed of duct work, the owner or operator shall:
(i) Conduct an initial inspection according to the procedures in
paragraph (c) of this section; and
(ii) Conduct annual inspections according to the procedures in
paragraph (c) of this section.
(iii) Conduct annual visual inspections for visible, audible, or
olfactory indications of leaks.
(3) For each fixed roof, cover, and enclosure, the owner or
operator shall:
(i) Conduct an initial inspection according to the procedures in
paragraph (c) of this section; and
(ii) Conduct semi-annual visual inspections for visible, audible,
or olfactory indications of leaks.
(c) Each vapor collection system, closed vent system, fixed roof,
cover, and enclosure shall be inspected according to the procedures
specified in paragraphs (c)(1) through (c)(6) of this section.
(1) Inspections shall be conducted in accordance with Method 21, 40
CFR part 60, appendix A, and with the exceptions and modifications
specified in this subpart.
(2) The detection instrument shall meet the performance criteria of
Method 21, 40 CFR part 60, appendix A except the instrument response
factor criteria in Section 3.1.2(a) of Method 21 shall be for the
average composition of the process fluid not each individual VOC in the
stream.
(i) Except as provided in paragraph (c)(2)(ii) of this section, the
detection instrument shall meet the performance criteria of Method 21,
40 CFR part 60, appendix A, except the instrument response factor
criteria in section 3.1.2(a) of Method 21 shall be for the average
composition of the process fluid not each individual VOC in the stream.
For process streams that contain nitrogen, air, or other inerts which
are not organic hazardous air pollutants or VOCs, the average stream
response factor shall be calculated on an inert-free basis.
(ii) If no instrument is available at the plant site that will meet
the performance criteria specified in paragraph (c)(2)(i) of this
section, the instrument readings may be adjusted by multiplying by the
average response factor of the process fluid, calculated on an inert-
free basis as described in paragraph (c)(2)(i) of this section.
(3) The detection instrument shall be calibrated before use on each
day of its use by the procedures specified in Method 21, 40 CFR part
60, appendix A.
(4) Calibration gases shall be as follows:
(i) Zero air (less than 10 parts per million hydrocarbon in air);
and
(ii) Mixtures of methane in air at a concentration less than 10,000
parts per million. A calibration gas other than methane in air may be
used if the instrument does not respond to methane or if the instrument
does not meet the performance criteria specified in
[[Page 68047]]
paragraph (c)(2)(i) of this section. In such cases, the calibration gas
may be a mixture of one or more of the compounds to be measured in the
air.
(5) An owner or operator may elect to adjust or not adjust
instrument readings for background. If an owner or operator elects to
not adjust readings for background, all such instrument readings shall
be compared directly to the applicable leak definition to determine
whether there is a leak. If an owner or operator elects to adjust
instrument readings for background, the owner or operator shall measure
background concentration using the procedures in 40 CFR 63.180(b) and
(c). The owner or operator shall subtract background reading from the
maximum concentration indicated by the instrument.
(6) The arithmetic difference between the maximum concentration
indicated by the instrument and the background level shall be compared
with 500 parts per million for determining compliance.
(d) Leaks, as indicated by an instrument reading greater than 500
parts per million above background or by visual inspections, shall be
repaired as soon as practical, except as provided in paragraph (e) of
this section.
(1) A first attempt at repair shall be made no later than 5
calendar days after the leak is detected.
(2) Repair shall be completed no later than 15 calendar days after
the leak is detected.
(e) Delay of repair of a vapor collection system, closed vent
system, fixed roof, cover, or enclosure for which leaks have been
detected is allowed if the repair is technically infeasible without a
shutdown or if the owner or operator determines that emissions
resulting from immediate repair would be greater than the fugitive
emissions likely to result from delay of repair. Repair of such
equipment shall be complete by the end of the next shutdown.
(f) For each vapor collection system or closed vent system that
contains bypass lines that could divert emissions away from a control
device, the owner or operator shall comply with the provisions of
either paragraph (f)(1) or (f)(2) of this section. Equipment such as
low leg drains, high point bleeds, analyzer vents, open-ended valves or
lines, and pressure relief valves needed for safety purposes are not
subject to this paragraph (f).
(1) Properly install, maintain, and operate a flow indicator that
takes a reading at least once every 15 minutes. Records shall be
generated as specified in Sec. 60.785(f)(10) of this subpart. The flow
indicator shall be installed at the entrance to any bypass line that
could divert emissions away from the control device and to the
atmosphere; or
(2) Secure the bypass line damper or valve in the non-diverting
position with a car-seal or a lock-and-key type configuration. A visual
inspection of the seal or closure mechanism shall be performed at least
once every month to ensure that the damper or valve is maintained in
the non-diverting position and emissions are not diverted through the
bypass line. Records shall be generated as specified in
Sec. 60.785(e)(11) of this subpart.
(g) Any parts of the vapor collection system, closed vent system,
fixed roof, cover, or enclosure that are designated, as described in
paragraph (i)(1) of this section, as unsafe to inspect are exempt from
the inspection requirements of paragraphs (b)(1), (b)(2), and (b)(3)(i)
of this section if:
(1) The owner or operator determines that the equipment is unsafe
to inspect because inspecting personnel would be exposed to an imminent
or potential danger as a consequence of complying with paragraphs
(b)(1), (b)(2), or (b)(3)(i) of this section; and
(2) The owner or operator has a written plan that requires
inspection of the equipment as frequently as practicable during safe-
to-inspect times.
(h) Any parts of the vapor collection system, closed vent system,
fixed roof, cover, or enclosure that are designated, as described in
paragraph (i)(2) of this section, as difficult to inspect are exempt
from the inspection requirements of paragraphs (b)(1), (b)(2), and
(b)(3)(i) of this section if:
(1) The owner or operator determines that the equipment cannot be
inspected without elevating the inspecting personnel more than 2 meters
above a support surface; and
(2) The owner or operator has a written plan that requires
inspection of the equipment at least once every 5 years.
(i) The owner or operator shall record the information specified in
paragraphs (i)(1) through (i)(5) of this section.
(1) Identification of all parts of the vapor collection system,
closed vent system, fixed roof, cover, or enclosure that are designated
as unsafe to inspect, an explanation of why the equipment is unsafe to
inspect, and the plan for inspecting the equipment.
(2) Identification of all parts of the vapor collection system,
closed vent system, fixed roof, cover, or enclosure that are designated
as difficult to inspect, an explanation of why the equipment is
difficult to inspect, and the plan for inspecting the equipment.
(3) For each vapor collection system or closed vent system that
contains bypass lines that could divert a vent stream away from the
control device and to the atmosphere, the owner or operator shall keep
a record of the information specified in either paragraph (i)(3)(i) or
(i)(3)(ii) of this section.
(i) Hourly records of whether the flow indicator specified under
paragraph (f)(1) of this section was operating and whether a diversion
was detected at any time during the hour, as well as records of the
times of all periods when the vent stream is diverted from the control
device or the monitor is not operating.
(ii) Where a seal mechanism is used to comply with paragraph (f)(2)
of this section, hourly records of flow are not required. In such
cases, the owner or operator shall record whether the monthly visual
inspection of the seals or closure mechanisms has been done, and shall
record the occurrence of all periods when the seal mechanism is broken,
the bypass line valve position has changed, or the key for a lock-and-
key type configuration has been checked out, and records of any car-
seal that has broken.
(4) For each inspection during which a leak is detected, a record
of the information specified in paragraphs (i)(4)(i) through
(i)(4)(viii) of this section.
(i) The instrument identification numbers; the name or initials of
the person conducting the inspection; and identification of the
equipment.
(ii) The date the leak was detected and the date of the first
attempt to repair the leak.
(iii) Maximum instrument reading measured by the method specified
in paragraph (d) of this section after the leak is successfully
repaired or determined to be nonrepairable.
(iv) ``Repair delayed'' and the reason for the delay if a leak is
not repaired within 15 calendar days after discovery of the leak.
(v) The name, initials, or other form of identification of the
owner or operator (or designee) whose decision it was that repair could
not be effected without a shutdown.
(vi) The expected date of successful repair of the leak if a leak
is not repaired within 15 calendar days.
(vii) Dates of shutdowns that occur while the equipment is
unrepaired.
(viii) The date of successful repair of the leak.
(5) For each inspection conducted in accordance with paragraph (c)
of this section during which no leaks are detected, a record that the
inspection was performed, the date of the
[[Page 68048]]
inspection, and a statement that no leaks were detected.
(6) For each visual inspection conducted in accordance with
paragraph (b)(1)(ii) or (b)(3)(ii) of this section during which no
leaks are detected, a record that the inspection was performed, the
date of the inspection, and a statement that no leaks were detected.
Sec. 60.787 Additional Requirements--Start-up, Shutdown, Malfunction,
or Nonoperation; Alternative Means of Emission Limitation; and Permits
(a) Applicability of this subpart during periods of start-up,
shutdown, malfunction, or non-operation. Paragraphs (a)(1) through
(a)(4) of this section shall be followed during periods of start-up,
shutdown, malfunction, or non-operation of the affected facility or any
part thereof.
(1) The emission limitations set forth in this subpart and the
emission limitations referred to in this subpart shall apply at all
times except during periods of non-operation of the affected facility
(or specific portion thereof) resulting in cessation of the emissions
to which this subpart applies. The emission limitations of this subpart
and the emission limitations referred to in this subpart shall not
apply during periods of start-up, shutdown, or malfunction. During
periods of start-up, shutdown, or malfunction, the owner or operator
shall follow the applicable provisions of the start-up, shutdown, and
malfunction plan as specified in 40 CFR 63.6(e)(3) and table 2A of this
subpart. However, if a start-up, shutdown, malfunction, or period of
non-operation of one portion of an affected facility does not affect
the ability of a particular emission point to comply with the emission
limitations to which it is subject, then that emission point shall
still be required to comply with the applicable provisions of this
subpart during the start-up, shutdown, malfunction, or period of non-
operation.
(2) The owner or operator shall not shut down items of equipment
that are required or utilized for compliance with this subpart during
periods of start-up, shutdown, or malfunction during times when
emissions, wastewater streams, or residuals are being routed to such
items of equipment, if the shutdown would contravene requirements of
this subpart applicable to such items of equipment. This paragraph
(a)(2) does not apply if the item of equipment is malfunctioning. This
paragraph (a)(2) also does not apply if the owner or operator shuts
down the compliance equipment (other than monitoring systems) to avoid
damage due to a contemporaneous start-up, shutdown, or malfunction of
the affected facility or portion thereof. If the owner or operator has
reason to believe that monitoring equipment would be damaged due to a
contemporaneous start-up, shutdown, or malfunction of the affected
facility or portion thereof, the owner or operator shall provide
documentation to the Administrator, as soon as possible, supporting
such a claim. Once approved by the Administrator, the provision for
ceasing to collect, during a start-up, shutdown, or malfunction,
monitoring data that would otherwise be required by the provisions of
this subpart must be incorporated into the start-up, shutdown,
malfunction plan for that affected facility.
(3) During start-ups, shutdowns, and malfunctions when the emission
limitations of this subpart do not apply pursuant to paragraphs (a)(1)
and (a)(2) of this section, the owner or operator shall implement, to
the extent reasonably available, measures to prevent or minimize excess
emissions. For purposes of this paragraph (a)(3), the term ``excess
emissions'' means emissions in excess of those that would have occurred
if there were no start-up, shutdown, or malfunction and the owner or
operator complied with the relevant provisions of this subpart. The
measures to be taken shall be identified in the applicable start-up,
shutdown, and malfunction plan, and may include, but are not limited
to, air pollution control technologies, recovery technologies, work
practices, pollution prevention, monitoring, and/or changes in the
manner of operation of the affected facility. Back-up control devices
are not required, but may be used if available.
(b) Start-up, shutdown, and malfunction plan. The owner or operator
of an affected facility shall develop and implement a written start-up,
shutdown, and malfunction plan as specified in 40 CFR 63.6(e)(3) and
table 2A of this subpart. This plan shall describe, in detail,
procedures for operating and maintaining the affected facility during
periods of start-up, shutdown, and malfunction and a program for
corrective action for malfunctioning process and air pollution control
equipment used to comply with this subpart. A provision for ceasing to
collect, during a start-up, shutdown, or malfunction, monitoring data
that would otherwise be required by the provisions of this subpart may
be included in the start-up, shutdown, and malfunction plan only if the
owner or operator has demonstrated to the Administrator that the
monitoring system would be damaged or destroyed if it were not shut
down during the start-up, shutdown, or malfunction. The affected
facility shall keep the start-up, shutdown, and malfunction plan on-
site.
(1) Records of start-up, shutdown, and malfunction. The owner or
operator shall keep the records specified in paragraphs (b)(1)(i) and
(b)(1)(ii) of this section.
(i) Records of the occurrence and duration of each start-up,
shutdown, and malfunction of operation of process equipment or control
devices or recovery devices or continuous monitoring systems used to
comply with this subpart during which excess emissions (as defined in
paragraph (a)(3) of this section) occur.
(ii) For each start-up, shutdown, or malfunction during which
excess emissions (as defined in paragraph (a)(3) of this section)
occur, records reflecting whether the procedures specified in the
affected facility's start-up, shutdown, and malfunction plan were
followed, and documentation of actions taken that are not consistent
with the plan. For example, if a start-up, shutdown, and malfunction
plan includes procedures for routing a control device to a backup
control device, records shall be kept of whether the plan was followed.
These records may take the form of a ``checklist,'' or other form of
recordkeeping that confirms conformance with the start-up shutdown, and
malfunction plan for the event.
(2) Reports of start-up, shutdown, and malfunction. For the
purposes of this subpart, the start-up, shutdown, and malfunction
reports shall be submitted on the same schedule as the semiannual
reports required under Sec. 60.784(d) of this subpart. Said reports
shall include the information specified in paragraphs (b)(1)(i) and
(b)(1)(ii)of this section and shall contain the name, title, and
signature of the owner or operator or other responsible official who is
certifying its accuracy.
(b) Alternative means of emission limitation. If, in the judgment
of the Administrator, an alternative means of emission limitation will
achieve a reduction in VOC emissions at least equivalent to the
reduction in VOC achieved under any design, equipment, work practice,
or operational standards in this subpart, the Administrator will
publish a notice permitting the use of the alternative means for
purposes of compliance with that requirement.
(1) The notice may condition the permission on requirements related
to the operation and maintenance of the alternative means.
[[Page 68049]]
(2) Any notice under paragraph (b) of this section shall be
published only after public notice and an opportunity for a hearing.
(3) Any person seeking permission to use an alternative means of
compliance under this section shall collect, verify, and submit to the
Administrator information showing that the alternative means achieves
equivalent emission reductions.
(c) Permit. Each owner or operator of an affected facility subject
to this subpart shall obtain a permit under 40 CFR part 70 or part 71
from the appropriate permitting authority. If EPA has approved a State
operating permit program under 40 CFR part 71, the permit shall be
obtained from the State authority. If the State operating permit
program has not been approved, the owner or operator shall apply to the
EPA regional office pursuant to 40 CFR part 70.
Sec. 60.788 [Reserved]
Sec. 60.789 Relationship to other regulations.
(a) The owner or operator who is subject to the provisions of this
section shall include in the Notification of Compliance Status a
statement specifying the options being used to comply with the
provisions of this section.
(b) Relationship to benzene waste. After the compliance dates
specified in Sec. 60.770 of this subpart, the owner or operator of a
Group 1 or Group 2 wastewater stream that is also subject to the
provisions of 40 CFR part 61, subpart FF is required to comply with the
provisions of both this subpart and 40 CFR part 61, subpart FF.
Alternatively, the owner or operator may elect to comply with the
provisions of paragraphs (b)(1) and (b)(2) of this section, which shall
constitute compliance with the provisions of 40 CFR part 61, subpart
FF.
(1) Comply with the provisions of this subpart; and
(2) For any Group 2 wastewater stream or organic stream whose
benzene emissions are subject to control through the use of one or more
treatment processes or waste management units under the provisions of
40 CFR part 61, subpart FF on or after September 12, 1994, comply with
the requirements of this subpart for Group 1 wastewater streams.
(c) Relationship to RCRA. After the compliance dates specified in
Sec. 60.770 of this subpart, the owner or operator of any Group 1 or
Group 2 wastewater stream that is also subject to provisions in 40 CFR
parts 260 and 272 shall comply with the requirements of either
paragraph (c)(1) or (c)(2) of this section.
(1) For each Group 1 or Group 2 wastewater stream, the owner or
operator shall comply with the more stringent control requirements
(e.g., waste management units, numerical treatment standards, etc.) and
the more stringent testing, monitoring, recordkeeping, and reporting
requirements that overlap between the provisions of this subpart and
the provisions of 40 CFR parts 260 through 272. The owner or operator
shall keep a record of the information used to determine which
requirements were the most stringent and shall submit this information
if requested by the Administrator; or
(2) The owner or operator shall submit, no later than four months
before the applicable compliance date specified in Sec. 60.770 of this
subpart, a request for a case-by-case determination of requirements.
The request shall include the information specified in paragraphs
(c)(2)(i) and (c)(2)(ii) of this section.
(i) Identification of the wastewater streams that are subject to
this subpart and to the provisions in 40 CFR parts 260 through 272,
determination of the Group 1/Group 2 status of those streams using the
provisions specified in this subpart, determination of whether or not
those streams are listed or exhibit a characteristic as specified in 40
CFR part 261, and determination of whether the waste management unit is
subject to permitting under 40 CFR part 270.
(ii) Identification of the specific control requirements (e.g.,
waste management units, numerical treatment standards, etc.) and
testing, monitoring, recordkeeping, and reporting requirements that
overlap between the provisions of this subpart and the provisions of 40
CFR parts 260 through 272.
(d) Overlap with the Vinyl Chloride NESHAP. After the compliance
dates specified in Sec. 60.770 of this subpart, the owner or operator
of a Group 1 and Group 2 wastewater stream that is also subject to the
provisions of 40 CFR part 61 subpart F shall comply with the provisions
of either paragraph (d)(1) or (d)(2) of this section.
(1) The owner or operator shall comply with the provisions of both
this subpart and 40 CFR part 61 subpart F or
(2) The owner or operator may submit, no later than four months
before the applicable compliance date specified in Sec. 60.770 of this
subpart, information demonstrating how compliance with 40 CFR Part 61,
subpart F, will also ensure compliance with this subpart. The
information shall include a description of the testing, monitoring,
reporting, and recordkeeping that will be performed.
(e) Overlap with the HON. After the compliance dates specified in
Sec. 60.770 of this subpart, the owner or operator of any Group 1 or
Group 2 process wastewater stream that is also subject to and
controlled according to the provisions in 40 CFR, subpart G shall
comply with either 40 CFR, subpart G or this subpart.
(f) Overlap with other regulations for monitoring, recordkeeping,
or reporting with respect to combustion devices, recovery devices, or
recapture devices. After compliance dates specified in Sec. 60.770 of
this subpart, if any combustion device, recovery device, or recapture
device subject to this subpart is also subject to monitoring,
recordkeeping, and reporting requirements in 40 CFR part 264, subpart
AA or CC, or is subject to monitoring and recordkeeping requirements in
40 CFR part 265, subpart AA or CC and other owner or operator complies
with the periodic reporting requirements under 40 CFR part 264, subpart
AA or CC that would apply to the device if the facility had final-
permitted status, the owner or operator may elect to comply with the
monitoring, recordkeeping, and reporting requirements of this subpart,
or with the monitoring, recordkeeping, and reporting requirements in 40
CFR parts 264 and/or 265, as described in this paragraph (f), which
shall constitute compliance with the monitoring, recordkeeping, and
reporting requirements of this subpart.
Table 1 to Subpart YYY--List of SOCMI Chemicals
------------------------------------------------------------------------
Chemical name <SUP>a CAS No.<SUP>b
------------------------------------------------------------------------
(1,1,2-) Trichloro (1,2,2-) trifluoroethane............. 76131
(2-Ethylhexyl) amine.................................... 104756
1,4-Dichlorobutene...................................... 110576
1-Butene................................................ 106989
[[Page 68050]]
1-Methyl-2-pyrrolidone.................................. 872504
1-Naphthyl-N-methylcarbamate............................
1-Phenyl ethyl hydroperoxide............................ 3071327
2-Butene................................................ 25167673
2-Butyne-1,4-diol....................................... 110656
2-Chloro-1,3-butadiene (Chloroprene).................... 126998
2-Chloro-4-(ethylamino)-6-(isopropylamino)-S-triazine... 1912249
2-Ethylhexanol (2-ethyl-1-hexanol)...................... 104767
2-Hexenedinitrile....................................... 13042029
3,4-Dichloro-1-butene................................... 64037543
3-Hexenedinitrile....................................... 1119853
3-Pentenenitrile........................................ 4635874
6-Ethyl-1,2,3,4-tetrahydro-9,10-antracenedione.......... 15547178
Acenaphthene............................................ 83329
Acetal (1,1-diethoxy-ethane)............................ 105577
Acetaldehyde............................................ 75070
Acetaldol (3-hydroxy-butanal)........................... 107891
Acetamide............................................... 60355
Acetanilide............................................. 103844
Acetic anhydride........................................ 108247
Acetic acid............................................. 64197
Acetoacetanilide........................................ 102012
Acetone cyanohydrin..................................... 75865
Acetone................................................. 67641
Acetonitrile............................................ 75058
Acetophenone............................................ 98862
Acetyl chloride......................................... 75365
Acetylene tetrabromide (1,1,2,2-tetrabromoethane)....... 79276
Acetylene............................................... 74862
Acrolein................................................ 107028
Acrylamide.............................................. 79061
Acrylic acid............................................ 79107
Acrylonitrile........................................... 107131
Adipic acid............................................. 124049
Adiponitrile............................................ 111693
Alcohols, C-11 or higher, mixtures......................
Alcohols, C-11 or lower, mixtures.......................
Alizarin................................................ 72480
Alkyl naphthalenes......................................
Alkyl naphthalene sulfonates............................
Alkyl anthraquinones....................................
Allyl cyanide........................................... 109751
Allyl chloride.......................................... 107051
Allyl bromide........................................... 106956
Allyl alcohol........................................... 107186
Aluminum acetate........................................ 7360443
Aluminum formates.......................................
Aminobenzoic acid (p-).................................. 1321115
Aminoethylethanolamine.................................. 111411
Aminophenol sulfonic acid...............................
Aminophenol (p-)........................................ 123308
Ammonium acetate........................................ 631618
Ammonium thiocyanate.................................... 1762954
Amyl acetates........................................... 628637
123922
Amyl chloride (n-)...................................... 543599
Amyl phenol............................................. 1322061
Amyl chlorides (mixed)..................................
Amyl mercaptans......................................... 110667
Amyl alcohols (mixed)................................... 30899195
Amyl alcohol (tert-).................................... 75854
Amyl alcohol (n-) (1-pentanol).......................... 71410
Amyl ether.............................................. 693652
Amylamines.............................................. 110587
Amylene................................................. 513359
Amylenes, mixed.........................................
Aniline................................................. 62533
Aniline hydrochloride................................... 142041
Anisidine (p-).......................................... 29191524
Anisidine (o-).......................................... 90040
Anisole (methoxy benzene)............................... 100663
Anthracene.............................................. 120127
[[Page 68051]]
Anthranilic acid........................................ 118923
Anthraquinone........................................... 84651
ar-Methylbenzenediamine................................. 25376458
Azobenzene.............................................. 103333
Barium acetate.......................................... 543806
Benzaldehyde............................................ 100527
Benzamide............................................... 55210
Benzene................................................. 71432
Benzenedisulfonic acid.................................. 98486
Benzenesulfonic acid.................................... 98113
Benzenesulfonic acid C<INF>10-16-alkyl derivatives, sodium
salts.................................................. 68081812
Benzidine...............................................
Benzil.................................................. 134816
Benzilic acid........................................... 76937
Benzoguanamine..........................................
Benzoic acid............................................ 65850
Benzoin................................................. 119539
Benzonitrile............................................ 100470
Benzophenone............................................ 119619
Benzotrichloride........................................ 98077
Benzoyl chloride........................................ 98884
Benzoyl peroxide........................................ 94360
Benzyl acetate.......................................... 140114
Benzyl chloride......................................... 100447
Benzyl alcohol.......................................... 100516
Benzyl dichloride....................................... 98873
Benzyl benzoate......................................... 120514
Benzylamine............................................. 100469
Benzylideneacetone...................................... 1896624
Biphenyl................................................ 92524
Bis(Chloromethyl)Ether.................................. 542881
Bisphenol A............................................. 80057
Brometone...............................................
Bromobenzene............................................ 108861
Bromoform............................................... 75252
Bromonaphthalene........................................ 27497514
Butadiene and butene fractions..........................
Butadiene (1,3-)........................................ 106990
Butane.................................................. 106978
Butanediol (1,4-)....................................... 110634
Butanes, mixed..........................................
Butenes, mixed..........................................
Butyl hydroperoxide (tert-)............................. 75912
Butyl acetate (sec-).................................... 105464
Butyl chloride (tert-).................................. 507200
Butyl alcohol (tert-)................................... 75650
Butyl benzoate.......................................... 136607
Butyl mercaptan (n-).................................... 109795
Butyl acrylate (n-)..................................... 141322
Butyl mercaptan (tert-)................................. 75661
Butyl methacrylate (n-)................................. 97881
Butyl alcohol (sec-).................................... 78922
Butyl acetate (tert-)................................... 540885
Butyl acetate (n-)...................................... 123864
Butyl methacrylate (tert-)..............................
Butyl toluene (tert-)................................... 98511
Butyl phenol (tert-).................................... 88186
Butyl alcohol (n-)...................................... 71363
Butylamine (t-)......................................... 75649
Butylamine (s-)......................................... 13952846
Butylamine (n-)......................................... 109739
Butylbenzene (tert-).................................... 98066
Butylbenzoic acid (p-tert-)............................. 98737
Butylbenzyl phthalate................................... 85867
Butylene glycol (1,3-).................................. 107880
Butylenes (n-)..........................................
Butyraldehyde (n-)...................................... 123728
Butyric acid (n-)....................................... 107926
Butyric anhydride (n-).................................. 106310
Butyrolacetone.......................................... 96480
Butyronitrile........................................... 109740
Calcium acetate......................................... 62544
[[Page 68052]]
Calcium propionate...................................... 4075814
Caproic acid............................................ 142621
Caprolactam............................................. 105602
Carbaryl................................................ 63252
Carbazole............................................... 86748
Carbon tetrabromide..................................... 558134
Carbon disulfide........................................ 75150
Carbon tetrachloride.................................... 56235
Carbon tetrafluoride.................................... 75730
Cellulose acetate....................................... 9004357
Chloral................................................. 75876
Chloranil (o-chloranil)................................. 2435532
Chloranil (p-chloranil)................................. 118752
Chloroacetic acid....................................... 79118
Chloroacetophenone (2-)................................. 532274
Chloroaniline (o-)...................................... 95512
Chloroaniline (p-)...................................... 106478
Chloroaniline (m-)...................................... 108429
Chlorobenzaldehyde (4-)................................. 104881
Chlorobenzaldehyde (2-)................................. 89985
Chlorobenzaldehyde (3-)................................. 587042
Chlorobenzene........................................... 108907
Chlorobenzoic acid...................................... 118912
535808
74113
Chlorobenzotrichloride (p-)............................. 5216251
Chlorobenzotrichloride (o-)............................. 2136892
Chlorobenzoyl chloride (p-)............................. 122010
Chlorobenzoyl chloride (o-)............................. 609654
Chlorodifluoroethane.................................... 25497294
Chlorodifluoromethane................................... 75456
Chlorofluorocarbons.....................................
Chloroform.............................................. 67663
Chlorohydrin............................................
Chloronaphthalene....................................... 25586430
Chloronitrobenzene (o-)................................. 88733
Chloronitrobenzene (m-)................................. 121733
Chloronitrobenzene (p-)................................. 100005
Chlorophenol (o-)....................................... 95578
Chlorophenol (m-)....................................... 108430
Chlorophenol (p-)....................................... 106489
Chlorosulfonic acid..................................... 7790945
Chlorotoluene (m-)...................................... 108418
Chlorotoluene (o-)...................................... 95498
Chlorotoluene (p-)...................................... 106434
Chlorotrifluoroethylene................................. 79389
Chlorotrifluoromethane.................................. 75729
Choline chloride........................................ 67481
Chrysene................................................ 218019
Cinnamic acid........................................... 140103
Citric acid............................................. 77929
Cobalt acetate..........................................
Copper acetate.......................................... 142712
Cresol and cresylic acid (o-)........................... 95487
Cresol and cresylic acid (p-)........................... 106445
Cresol and cresylic acid (m-)........................... 108394
Cresols and cresylic acids (mixed)...................... 1319773
Crotonaldehyde.......................................... 4170300
Crotonic acid........................................... 3724650
Cumene hydroperoxide.................................... 80159
Cumene.................................................. 98828
Cyanamide............................................... 420042
Cyanoacetic acid........................................ 372098
Cyanoformamide..........................................
Cyanogen chloride....................................... 506774
Cyanuric acid........................................... 108805
Cyanuric chloride....................................... 108770
Cyclohexane, oxidized................................... 68512152
Cyclohexane............................................. 110827
Cyclohexanol............................................ 108930
Cyclohexanone oxime..................................... 100641
Cyclohexanone........................................... 108941
[[Page 68053]]
Cyclohexene............................................. 110838
Cyclohexylamine......................................... 108918
Cyclooctadiene.......................................... 29965977
Cyclooctadiene (1,3-)................................... 3806595
Cyclooctadiene (1,5-)................................... 111784
Cyclopentadiene (1,3-)..................................
Cyclopropane............................................ 75194
Decahydronaphthalene.................................... 91178
Decanol................................................. 112301
Decyl alcohol (1-decanol)............................... 112301
Di-o-tolyguanidine...................................... 97392
Di(2-methoxyethyl) phthalate............................
Di-n-heptyl-n-nonyl undecyl phthalate...................
Diacetone alcohol....................................... 123422
Diacetoxy-2-Butene (1,4-)...............................
Diallyl phthalate....................................... 131179
Diallyl isophthalate....................................
Diaminobenzoic acids.................................... 27576041
Diaminophenol hydrochloride............................. 137097
Dibromomethane.......................................... 74953
Dibutanized aromatic concentrate........................
Dibutoxyethyl phthalate.................................
Dichloro-1-butene (3,4-)................................ 760236
Dichloro-2-butene (1,4-)................................ 764410
Dichloro-2-butenes......................................
Dichloroaniline (mixed isomers)......................... 27134276
Dichlorobenzene (p-).................................... 106467
Dichlorobenzene (m-).................................... 541731
Dichlorobenzene (o-).................................... 95501
Dichlorobenzidine (3,3'-)............................... 91941
Dichlorodifluoromethane................................. 75718
Dichlorodimethylsilane.................................. 75785
Dichloroethane (1,2-) (Ethylene dichloride) (EDC)....... 107062
Dichloroethyl ether (bis(2-chloroethyl)ether)........... 111444
Dichloroethylene (1,2-)................................. 540590
Dichlorofluoromethane................................... 75434
Dichlorohydrin (a-)..................................... 96231
Dichloromethyl ether....................................
Dichloronitrobenzenes...................................
Dichloropentanes........................................
Dichlorophenol (2,4-)................................... 120832
Dichloropropane (1,1-).................................. 78999
Dichloropropene (1,3-).................................. 542756
Dichloropropene/dichloropropane (mixed).................
Dichlorotetrafluoroethane............................... 1320372
Dicyandiamide........................................... 461585
Dicyclohexylamine....................................... 101837
Dicyclopentadiene....................................... 77736
Diethanolamine (2,2'-Iminodiethanol).................... 111422
Diethyl phthalate....................................... 84662
Diethyl sulfate......................................... 64675
Diethylamine............................................ 109897
Diethylaniline (N,N-)................................... 91667
Diethylaniline (2,6-)................................... 579668
Diethylbenzene.......................................... 25340174
Diethylene glycol monoethyl ether....................... 111900
Diethylene glycol dimethyl ether........................ 111966
Diethylene glycol....................................... 111466
Diethylene glycol monobutyl ether acetate............... 124174
Diethylene glycol monomethyl ether...................... 111773
Diethylene glycol diethyl ether......................... 112367
Diethylene glycol monomethyl ether acetate.............. 629389
Diethylene glycol monoethyl ether acetate............... 112152
Diethylene glycol monohexyl ether....................... 112594
Diethylene glycol monobutyl ether....................... 112345
Diethylene glycol dibutyl ether......................... 112732
Difluoroethane (1,1-)................................... 75376
Dihydroxybenzoic acid (Resorcylic acid)................. 27138574
Diisobutylene........................................... 25167708
Diisodecyl phthalate.................................... 26761400
Diisononyl phthalate.................................... 28553120
Diisooctyl phthalate.................................... 27554263
[[Page 68054]]
Diisopropylamine........................................ 108189
Diketene (4-methylene-2-oxetanone)...................... 674828
Dimethyl sulfate........................................ 77781
Dimethyl ether.......................................... 115106
Dimethyl sulfide........................................ 75183
Dimethyl phthalate...................................... 131113
Dimethyl sulfoxide...................................... 67685
Dimethyl terephthalate.................................. 120616
Dimethylacetamide (N,N-)................................ 127195
Dimethylamine........................................... 124403
Dimethylaminoethanol (2-)............................... 108010
Dimethylaniline (N,N)................................... 121697
Dimethylbenzidine (3,3'-)............................... 119937
Dimethylformamide (N,N-)................................ 68122
Dimethylhydrazine (1,1-)................................ 57147
Dimethylphenol (2,5-) Xylenol (2, 5-)................... 95874
Dimethylphenol (2,6-) Xylenol (2, 6-)................... 576261
Dimethylphenol (3,5-) Xylenol (3, 5-)................... 108689
Dimethylphenol (2,4-) Xylenol (2, 4-)................... 105679
Dimethylphenol (2,3-) Xylenol (2, 3-)................... 526750
Dimethylphenol (3,4-) Xylenol (3, 4-)................... 95658
Dinitrobenzenes (NOS)<SUP>c.................................. 25154545
Dinitrobenzoic acid (3,5-).............................. 99343
Dinitrophenol (2,4-).................................... 51285
Dinitrotoluene (3,4-)................................... 610399
Dinitrotoluene (2,6-)................................... 606202
Dinitrotoluene (2,3-)................................... 602017
Dinitrotoluene (2,4-)................................... 121142
Dioctyl phthalate....................................... 117817
Dioxane (1,4-) (1,4-Diethyleneoxide).................... 123911
Dioxolane (1,3-)........................................ 646060
Diphenyl oxide.......................................... 101848
Diphenyl thiourea (N,N'-)............................... 102089
Diphenyl methane........................................ 101815
Diphenylamine........................................... 122394
Dipropylene glycol...................................... 110985
Dodecandedioic acid..................................... 693232
Dodecene (branched)..................................... 112414
Dodecene (n-)........................................... 25378227
Dodecyl phenol (branched)............................... 121158585
Dodecyl benzene (branched).............................. 123013
Dodecylaniline.......................................... 28675174
Dodecylbenzene sulfonic acid............................ 27176870
Dodecylbenzene, nonlinear...............................
Dodecylbenzene (n-)..................................... 121013
Dodecylbenzene sulfonic acid, sodium salt............... 25155300
Dodecylmercaptan (branched)............................. 25103586
Dodecylphenol........................................... 27193868
Epichlorohydrin (1-chloro-2,3-epoxypropane)............. 106898
Ethane.................................................. 74840
Ethanol................................................. 64175
Ethanolamine............................................ 141435
Ethyl ether............................................. 60297
Ethyl oxalate........................................... 95921
Ethyl orthoformate...................................... 122510
Ethyl acetate........................................... 141786
Ethyl bromide........................................... 74964
Ethyl chloride (Chloroethane)........................... 75003
Ethyl cyanide........................................... 107120
Ethyl acrylate.......................................... 140885
Ethyl sodium oxalacetate................................ 41892711
Ethyl acetoacetate...................................... 141979
Ethyl chloroacetate..................................... 105395
Ethyl mercaptan (ethanethiol)........................... 75081
Ethylamine.............................................. 75047
Ethylaniline (o-)....................................... 578541
Ethylaniline (n-)....................................... 103695
Ethylbenzene............................................ 100414
Ethylcellulose.......................................... 9004573
Ethylcyanoacetate....................................... 105566
Ethylene glycol dibutyl ether........................... 112481
Ethylene dibromide (Dibromoethane)...................... 106934
[[Page 68055]]
Ethylene oxide.......................................... 75218
Ethylene glycol monoethyl ether......................... 110805
Ethylene glycol monoethyl ether acetate................. 111159
Ethylene glycol monomethyl ether........................ 109864
Ethylene dichloride..................................... 107062
Ethylene glycol monobutyl ether acetate................. 112072
Ethylene glycol dimethyl ether.......................... 110714
Ethylene................................................ 74851
Ethylene glycol monophenyl ether........................ 122996
Ethylene glycol monoacetate............................. 542596
Ethylene carbonate...................................... 96491
Ethylene glycol monooctyl ether.........................
Ethylene glycol diacetate............................... 111557
Ethylene glycol diethyl ether (1,2-diethoxyethane)...... 629141
Ethylene glycol monopropyl ether........................ 2807309
Ethylene glycol monohexyl ether......................... 112254
Ethylene glycol monomethyl ether acetate................ 110496
Ethylene glycol monobutyl ether......................... 111762
Ethylene chlorohydrin................................... 107073
Ethylene glycol......................................... 107211
Ethylenediamine......................................... 107153
Ethylenediamine tetraacetic acid........................ 60004
Ethylenimine (Aziridine)................................ 151564
Ethylhexanoic acid (2-)................................. 149575
Ethylhexyl succinate (2-)...............................
Ethylhexyl acrylate (2-isomer).......................... 103117
Ethylmethylbenzene...................................... 25550145
Fluoranthene............................................ 206440
Formaldehyde............................................ 50000
Formamide............................................... 75127
Formic acid............................................. 64186
Fumaric acid............................................ 110178
Furfural (2-furan carboxaldehyde)....................... 98011
Glutaraldehyde.......................................... 111308
Glyceraldehyde.......................................... 367475
Glycerol dichlorohydrin................................. 26545737
Glycerol tri(polyoxypropylene)ether..................... 25791962
Glycerol................................................ 56815
Glycidol................................................ 556525
Glycine................................................. 56406
Glycol ethers...........................................
Glyoxal (ethane dial)................................... 107222
Guanidine...............................................
Guanidine nitrate....................................... 506934
Heptenes................................................
Hexachlorobenzene....................................... 118741
Hexachlorobutadiene..................................... 87683
Hexachlorocyclopentadiene............................... 77474
Hexachloroethane........................................ 67721
Hexadecyl chloride......................................
Hexadecyl alcohol (1-hexadecanol)....................... 36653824
Hexadiene (1,4-)........................................ 592450
Hexamethylene glycol.................................... 629118
Hexamethylene diamine adipate........................... 3323533
Hexamethylenediamine.................................... 124094
Hexamethylenetetramine.................................. 100970
Hexane.................................................. 110543
Hexanetriol (1,2,6-).................................... 106694
Hexyl alcohol........................................... 111273
Hexylene glycol......................................... 107415
Higher glycols..........................................
Hydrogen cyanide........................................ 74908
Hydroquinone............................................ 123319
Hydroxyadipaldehyde..................................... 141311
Hydroxybenzoic acid (p-)................................ 99967
Iminodiethanol (2,2-) (diethanolamine).................. 111422
Isoamyl alcohol......................................... 123513
Isoamyl chloride (mixed)................................
Isoamylene.............................................. 26760645
Isobutane............................................... 75285
Isobutanol.............................................. 78831
Isobutyl methacrylate................................... 97869
[[Page 68056]]
Isobutyl acetate........................................ 110190
Isobutyl acrylate....................................... 106638
Isobutyl vinyl ether.................................... 109535
Isobutyl alcohol........................................ 78831
Isobutylene............................................. 115117
Isobutyraldehyde (2-methyl-propanal).................... 78842
Isobutyric acid......................................... 79312
Isodecanol.............................................. 25339177
Isohexyldecyl alcohol...................................
Isononyl alcohol........................................
Isooctyl alcohol........................................ 26952216
Isopentane.............................................. 78784
Isophorone nitrile......................................
Isophorone.............................................. 78591
Isophthalic acid........................................ 121915
Isoprene................................................ 78795
Isopropanol............................................. 67630
Isopropyl acetate....................................... 108214
Isopropyl ether......................................... 108203
Isopropyl chloride...................................... 75296
Isopropylamine.......................................... 75310
Isopropylphenol......................................... 25168063
Ketene.................................................. 463514
Lactic acid............................................. 79334
Lauryl dimethylamine oxide..............................
Lead subacetate......................................... 1335326
Lead phthalate..........................................
Lead acetate............................................ 6080564
Linear alcohols, ethoxylated and sulfated, sodium salt,
mixed..................................................
Linear alcohols, ethoxylated, mixed.....................
Linear alkyl sulfonate..................................
Linear alcohols, sulfated, sodium salt, mixed...........
Magnesium acetate....................................... 142723
Maleic anhydride........................................ 108316
Maleic hydrazide........................................ 123331
Maleic acid............................................. 110167
Malic acid.............................................. 6915157
Manganese acetate....................................... 638380
Melamine (1,3,5-triazine-2,4,6-triamine)................ 108781
Mercuric acetate........................................ 1600277
Mesityl oxide........................................... 141797
Metanilic acid.......................................... 121471
Methacrylic acid........................................ 79414
Methacrylonitrile....................................... 126987
Methallyl chloride...................................... 563473
Methallyl alcohol....................................... 513428
Methane................................................. 74828
Methanol................................................ 67561
Methionine.............................................. 63683
Methyl mercaptan........................................ 74931
Methyl iodide........................................... 74884
Methyl ethyl ketone (2-butanone)........................ 78933
Methyl isobutyl carbinol................................ 108112
Methyl acetate.......................................... 79209
Methyl chloride (Chloromethane)......................... 74873
Methyl salicylate....................................... 119368
Methyl acetoacetate..................................... 105453
Methyl bromide (Bromomethane)........................... 74839
Methyl formate.......................................... 107313
Methyl phenyl carbinol.................................. 98851
Methyl methacrylate..................................... 80626
Methyl tert-butyl ether................................. 1634044
Methyl isocyanate....................................... 624839
Methyl butynol.......................................... 37365712
Methyl hydrazine........................................ 60344
Methyl isobutyl ketone (Hexone)......................... 108101
Methyl acrylate......................................... 96333
Methyl butenols.........................................
Methyl anthranilate..................................... 134203
Methylamine............................................. 74895
Methylaniline (N-)...................................... 100618
Methylbutanol (2-)...................................... 137326
[[Page 68057]]
Methylcyclohexane....................................... 108872
Methylcyclohexanol...................................... 25639423
Methylcyclohexanone..................................... 1331222
Methylene chloride (Dichloromethane).................... 75092
Methylene dianiline (4,4').............................. 101779
Methylene diphenyl diisocyanate (4,4'-) (MDI)........... 101688
Methylionones (a-)...................................... 79696
Methylnaphthalene (2-).................................. 91576
Methylnaphthalene (1-).................................. 90120
Methylpentane (2-)...................................... 107835
Methylpentynol.......................................... 77758
Methylstyrene (a-)...................................... 98839
Monomethylhydrazine.....................................
Morpholine.............................................. 110918
n-Heptane............................................... 142825
n-Propanol.............................................. 71238
N-Vinyl-2-pyrrolidine...................................
Naphthalene sulfonic acid (a-).......................... 85472
Naphthalene............................................. 91203
Naphthalene sulfonic acid (b-).......................... 120183
Naphthenic acids........................................
Naphthol (a-)........................................... 90153
Naphthol (b-)........................................... 135193
Naphtholsulfonic acid (1-).............................. 567180
Naphthylamine sulfonic acid (1,4-)...................... 84866
Naphthylamine (1-)...................................... 134327
Naphthylamine (2-)...................................... 91598
Naphthylamine sulfonic acid (2,1-)...................... 81163
Neohexane............................................... 75832
Neopentanoic acid....................................... 75989
Neopentyl glycol........................................ 126307
Nickel formate..........................................
Nitriloacetic acid......................................
Nitrilotriacetic acid................................... 139139
Nitroaniline (m-)....................................... 99092
Nitroaniline (p-)....................................... 100016
Nitroaniline (o-)....................................... 88744
Nitroanisole (p-)....................................... 100174
Nitroanisole (o-)....................................... 91236
Nitrobenzene............................................ 98953
Nitrobenzoic acid (m-).................................. 121926
Nitrobenzoic acid (o-).................................. 552169
Nitrobenzoic acid (p-).................................. 62237
Nitrobenzoyl chloride (p-)..............................
Nitroethane............................................. 79243
Nitroguanidine.......................................... 556887
Nitromethane............................................ 75525
Nitronaphthalene (1-)................................... 86577
Nitrophenol (p-)........................................ 100027
Nitrophenol (o-)........................................ 88755
Nitropropane (1-)....................................... 25322014
Nitropropane (2-)....................................... 79469
Nitrotoluene (p-)....................................... 99990
Nitrotoluene (o-)....................................... 88722
Nitrotoluene (m-)....................................... 99081
Nitrotoluene (all isomers).............................. 1321126
Nitroxylene............................................. 25168041
Nonene.................................................. 27215958
Nonyl alcohol........................................... 1430808
Nonylbenzene (branched)................................. 1081772
Nonylphenol............................................. 25154523
Nonylphenol, ethoxylated................................ 9016459
Nonylphenol (branched).................................. 25154523
Octane.................................................. 111659
Octene-1................................................ 111660
Octylamine (tert-)...................................... 107459
Octylphenol............................................. 27193288
Oil-soluble petroleum sulfonate sodium salt.............
Oil-soluble petroleum sulfonate calcium salt............
Oxalic acid............................................. 144627
Oxamide................................................. 471465
Oxo chemicals...........................................
[[Page 68058]]
p-tert-Butyl toluene.................................... 98511
Paraformaldehyde........................................ 30525894
Paraldehyde............................................. 123637
Pentachlorophenol....................................... 87865
Pentaerythritol tetranitrate............................
Pentane................................................. 109660
Pentanethiol............................................ 115775
Pentanol (3-)........................................... 584021
Pentanol (2-)........................................... 6032297
Pentene (1-)............................................ 109671
Pentene (2-)............................................ 109682
Peracetic acid.......................................... 79210
Perchloromethyl mercaptan............................... 594423
Phenacetin.............................................. 62442
Phenanthrene............................................ 85018
Phenetidine (p-)........................................ 156434
Phenetidine (o-)........................................ 94702
Phenol.................................................. 108952
Phenolphthalein......................................... 77098
Phenolsulfonic acids (all isomers)...................... 1333397
Phenyl anthranilic acid (all isomers)................... 91407
Phenylenediamine (m-)................................... 108452
Phenylenediamine (p-)................................... 106503
Phenylenediamine (o-)................................... 95545
Phenylmethylpyrazolone..................................
Phenylpropane........................................... 103651
Phloroglucinol (1,3,5-benzenetriol)..................... 108736
Phosgene................................................ 75445
Phthalic acid........................................... 88993
Phthalic anhydride...................................... 85449
Phthalimide............................................. 85416
Phthalonitrile.......................................... 91156
Picoline (b-)........................................... 108996
Picoline (a-)...........................................
Picramic acid...........................................
Picric acid............................................. 88891
Piperazine.............................................. 110850
Piperidine.............................................. 110894
Piperylene.............................................. 504609
Polybutenes............................................. 9003296
Polyethylene glycol..................................... 25322683
Polypropylene glycol.................................... 25322694
Potassium acetate....................................... 127082
Propane................................................. 74986
Propiolactone (beta-) (2-Oxetanone)..................... 57578
Propionaldehyde......................................... 123386
Propionic acid.......................................... 79094
Propyl acetate (n-)..................................... 109604
Propyl chloride......................................... 540545
Propyl alcohol (n-)..................................... 71238
Propylamine............................................. 107108
Propylene chlorohydrin.................................. 127004
Propylene glycol........................................ 57556
Propylene............................................... 115071
Propylene oxide......................................... 75569
Propylene carbonate..................................... 108327
Propylene glycol monomethyl ether....................... 107982
1,2-dichloropropane..................................... 78875
Pseudocumene............................................ 95636
Pseudocumidine..........................................
Pyrene.................................................. 129000
Pyridine................................................ 110861
Pyrrolidone (2-)........................................ 616455
Quinone................................................. 106514
Resorcinol (1,3-benzenediol)............................ 108463
Salicylic acid.......................................... 69727
Sebacic acid............................................ 111206
Sodium benzoate......................................... 532321
Sodium phenate.......................................... 139026
Sodium acetate.......................................... 127093
Sodium formate.......................................... 141537
Sodium methoxide........................................ 124414
[[Page 68059]]
Sodium cyanide.......................................... 143339
Sodium propionate....................................... 137406
Sodium chloroacetate.................................... 3926623
Sodium carboxymethyl cellulose.......................... 9004324
Sodium oxalate.......................................... 62760
Sodium dodecyl benzene sulfonate........................
Sorbic acid............................................. 110441
Sorbitol (D-Glucitol)................................... 50704
Stilbene................................................ 588590
Styrene................................................. 100425
Succinic acid........................................... 110156
Succinonitrile.......................................... 110612
Sulfanilic acid......................................... 121573
Sulfolane............................................... 126330
Synthesis gas...........................................
Tannic acid............................................. 1401554
Tartaric acid........................................... 526830
Terephthalic acid....................................... 100210
Terephthaloyl chloride.................................. 100209
Tetra (methyl-ethyl) lead...............................
Tetrabromophthalic anhydride............................ 632791
Tetrachlorobenzene (1,2,3,5-)...........................
Tetrachlorobenzene (1,2,4,5-)........................... 95943
Tetrachloroethane (1,1,2,2-)............................ 79345
Tetrachloroethylene (Perchloroethylene)................. 127184
Tetrachlorophthalic anhydride........................... 117088
Tetraethyl lead......................................... 78002
Tetraethylene glycol.................................... 112607
Tetraethylenepentamine.................................. 112572
Tetrafluoroethylene.....................................
Tetrahydrofuran......................................... 109999
Tetrahydronapthalene.................................... 119642
Tetrahydrophthalic anhydride............................ 85438
Tetramethylenediamine................................... 110601
Tetramethylethylenediamine.............................. 110189
Tetramethyllead......................................... 75741
Thiourea................................................ 62566
Tolidines...............................................
Toluene sulfonic acids.................................. 104154
Toluene diisocyanate (2,4-)............................. 584849
Toluene................................................. 108883
Toluene diamine (2,4-).................................. 95807
Toluene diisocyanates (mixture)......................... 26471625
Toluene sulfonamides (o- and p-)........................ 1333079
Toluenesulfonyl chloride................................ 98599
Toluidine (o-).......................................... 95534
Trichloroacetic acid.................................... 76039
Trichloroaniline (2,4,6-)............................... 634935
Trichlorobenzene (1,2,4-)............................... 120821
Trichlorobenzene (1,2,3-)............................... 87616
Trichlorobenzene (1,3,5-)............................... 108703
Trichloroethane (1,1,2-)................................ 79005
Trichloroethane (1,1,1-)................................ 71556
Trichloroethylene....................................... 79016
Trichlorofluoromethane.................................. 75694
Trichlorophenol (2,4,5-)................................ 95954
Trichloropropane (1,2,3-)............................... 96184
Tricresyl phosphate..................................... 1330785
Tridecyl alcohol........................................ 112709
Tridecyl mercaptan......................................
Triethanolamine......................................... 102716
Triethylamine........................................... 121448
Triethylene glycol monoethyl ether...................... 112505
Triethylene glycol...................................... 112276
Triethylene glycol dimethyl ether....................... 112492
Triethylene glycol monomethyl ether..................... 112356
Triisobutylene.......................................... 7756947
Trimellitic anhydride................................... 552307
Trimethyl-1,3-pentanediol (2,2,4-)...................... 144194
Trimethyl-1-pentanol (2,4,4-)........................... 16325636
Trimethylamine.......................................... 75503
Trimethylcyclohexanol................................... 933482
[[Page 68060]]
Trimethylcyclohexanone.................................. 2408379
Trimethylcyclohexylamine................................ 34216347
Trimethylolpropane...................................... 77996
Trimethylpentane (2,2,4-)............................... 540841
Tripropylene glycol..................................... 24800440
Urea.................................................... 57136
Vinyl chloride (Chloroethylene)......................... 75014
Vinyl acetate........................................... 108054
Vinyl toluene........................................... 25013154
Vinyl (N-)-pyrrolidone (2-)............................. 88120
Vinylcyclohexene (4-)................................... 100403
Vinylidene chloride (1,1-dichloroethylene).............. 75354
Vinylpyridine (2-)...................................... 100696
Xanthates............................................... 140896
Xylene sulfonic acid.................................... 25321419
Xylene (m-)............................................. 108383
Xylene (o-)............................................. 95476
Xylene (p-)............................................. 106423
Xylenes (NOS)<SUP>c.......................................... 1330207
Xylenols (Mixed)........................................ 1300716
Xylidene (dimethylbenzene diamine)...................... 1300738
Xylidene (2,3-)......................................... 1300738
Xylidene (2,6-)......................................... 1300738
Xylidene (2,5-)......................................... 1300738
Xylidene (3,5-)......................................... 1300738
Xylidene (2,4-)......................................... 1300738
Xylidene (3,4-)......................................... 1300738
Zinc acetate............................................ 5970456
------------------------------------------------------------------------
<SUP>a Isomer means all structural arrangements for the same number of atoms
of each element and does not mean salts, esters, or derivatives.
<SUP>b CAS Number = Chemical Abstract Service number.
Table 2 To Subpart YYY--Applicability of 40 CFR Part 60 General
Provisions to Subpart YYY
------------------------------------------------------------------------
Applies to
Reference subpart YYY Subject/comment
------------------------------------------------------------------------
60.1.......................... Yes.............. Applicability.
60.2.......................... Yes.............. Definitions. If a
term is defined in
both the General
Provisions and
subpart YYY, the
definition in YYY
shall override the
definition in the
General provisions.
60.3.......................... Yes.............. Units and
abbreviations.
60.4.......................... Yes.............. Address.
60.5.......................... Yes.............. Determination of
construction or
modification.
60.6.......................... Yes.............. Review of plans.
60.7(a)(1).................... Yes.............. Submit a notification
of the date
construction or
reconstruction
commences.
60.7(a)(2).................... Yes.............. Submit a notification
of anticipated date
of initial startup.
60.7(a)(3).................... Yes.............. Submit a notification
of actual date of
initial startup.
60.7(a)(4).................... Yes.............. Submit a notification
of any physical or
operational change
to an existing
facility which
increases the
emission rate of any
air pollutant.
60.7(a)(5).................... No............... Continuous monitoring
requirements and
associated reporting
and recordkeeping
are specified in
Secs. 60.781,
60.784, and 60.785
of subpart YYY.
60.7(a)(6)-160.7(a)(7)........ No............... Subpart YYY is not an
opacity standard.
60.7(b)....................... No............... Sec. 60.785(f)(7) of
subpart YYY specify
which records to
maintain to document
periods of startup,
shutdown, or
malfunction; and
periods when a
continuous
monitoring system is
inoperative.
60.7(c), (d), and (e)......... No............... The semiannual report
required in Sec.
60.784(d) includes
reports of all
excursions and all
periods when
monitoring
parameters are above
the maximum or below
the minimum
established value.
Sec. 60.784(e)
specifies semiannual
reporting for
treatment processes.
Excess emissions are
discussed and
defined in Sec.
60.787(a)(3) and
must be recorded in
the startup,
shutdown, and
malfunction plan as
specified in Sec.
60.787.
60.7(f)....................... No............... Sec. 60.785
specifies data
retention and the
types of records
that must be
maintained.
60.7(g)-(h)................... Yes.............. .....................
60.8.......................... No............... The performance
testing requirements
in 40 CFR 63.7 apply
to subpart YYY as
specified in Table
2A of this subpart.
60.9.......................... Yes.............. Availability of
information.
60.10......................... Yes.............. State authority.
60.11......................... No............... Subpart YYY is not an
opacity standard.
Operation and
maintenance
requirements are
specified throughout
subpart YYY.
60.12......................... Yes.............. Circumvention.
60.13(a)...................... No............... Continuous monitoring
requirements are
specified in Sec.
60.781.
60.13(b)...................... Yes.............. Except use 40 CFR
part 63.11 in place
of the Sec. 60.8
reference to
performance tests.
[[Page 68061]]
60.13(c)-(d).................. No............... Opacity and
continuous emission
monitoring not
required in subpart
YYY.
60.13(e)...................... No............... Monitoring frequency
is specified in Sec.
60.781.
60.13(f)...................... Yes.............. Except Sec.
60.781(g), which
pertains to
installation,
calibration, and
maintenance of
monitoring
equipment, applies,
also.
60.13(g)...................... No............... The locations to
install CMS are
specified in Sec.
60.781.
60.13(h)...................... No............... Provisions explaining
how to calculate
continuous parameter
monitoring values
are specified in
Sec. 60.785.
60.13(i)(1)-(i)(7), (i)(9).... Yes.............. Alternatives to
monitoring methods
or procedures must
be approved by the
Administrator.
60.13(i)(8)................... No............... Opacity monitoring
not required in
subpart YYY.
60.13(j)...................... No............... Continuous emission
monitoring not
required in subpart
YYY.
60.14(a)...................... No............... A modification is
determined as
specified in Sec.
60.772(b).
60.14(b)...................... No............... VOC emissions are
determined as
specified in Sec.
60.772(f).
60.14(c)...................... No............... .....................
60.14(d)...................... No............... Reserved.
60.14(e)...................... No............... Types of physical and
operational changes
that are not
modifications are
specified in Sec.
60.772(c).
60.14(f)-(g).................. Yes.............. .....................
60.14(h)-60.14(l)............. Yes.............. List of changes and
projects that are
exempt from
modification
provisions.
60.15......................... Yes.............. Except 60.772(g)
specifies additional
requirements for
``fixed capital cost
of the new
components.''
60.16......................... Yes.............. Prioritized major
source categories.
60.17......................... Yes.............. Incorporations by
reference.
60.18......................... No............... Control device
requirements are
specified in 40 CFR
part 63.11, as
specified in Table
2A of this subpart.
60.19......................... Yes.............. General notification
and reporting
requirements.
------------------------------------------------------------------------
Table 2A to Subpart YYY--Applicability of 40 CFR Part 63 General
Provisions to Subpart YYY
------------------------------------------------------------------------
Applies to
Reference subpart YYY Subject/comment
------------------------------------------------------------------------
63.6(e)(3)(i)................. Yes.............. The startup,
shutdown,
malfunction plan may
include written
procedures that
identify conditions
that justify a delay
of repair.
63.6(e)(3)(i)(B).............. Yes.............. .....................
63.6(e)(3)(i)(C).............. Yes.............. .....................
63.6(e)(3)(ii)................ Yes.............. .....................
63.6(e)(3)(v)................. Yes.............. .....................
63.6(e)(3)(vi)................ Yes.............. .....................
63.6(e)(3)(vii)............... Yes.............. .....................
63.6(e)(3)(vii)(A)............ Yes.............. .....................
63.6(e)(3)(vii)(B)............ Yes.............. Except the plan shall
provide for
operation in
compliance with Sec.
60.787(a)(3).
63.6(e)(3)(vii)(C)............ Yes.............. .....................
63.6(e)(3)(viii).............. Yes.............. .....................
63.7(a)(3).................... Yes.............. .....................
63.7(d)....................... Yes.............. .....................
63.7(e)(1)-(e)(2)............. Yes.............. Except Sec.
60.783(a)(8),
representative
process unit
operating
conditions, and
(a)(9),
representative
treatment process or
control device
operating
conditions, also
address this issue.
63.7(e)(4).................... Yes.............. .....................
63.7(h)(1)-(h)(2)............. Yes.............. .....................
63.7(h)(5).................... Yes.............. .....................
63.9(a)(4).................... Yes.............. .....................
63.9(b)(5).................... Yes.............. .....................
63.11......................... Yes.............. .....................
------------------------------------------------------------------------
Table 3 to Subpart YYY--Control Requirement Options for Wastewater Tanks, Surface Impoundment, Containers, Individual Drain Systems, and Oil-Water
Separators
--------------------------------------------------------------------------------------------------------------------------------------------------------
Part 60, subpart Part 264, Part 265, Part 61, subpart
Unit operation Part 63, subpart Part 63 (standard-standards) QQQ (petroleum subpart CC (RCRA subpart CC (RCRA FF (benzene
G (HON) refinery) CC) CC) waste)
--------------------------------------------------------------------------------------------------------------------------------------------------------
Wastewater Tanks................ Sec. 63.133 ............................ ................ Sec. 264.1084 Sec. 265.1085 Sec. 61.343
Surface Impoundments............ Sec. 63.134 Secs. 63.942 and 63.943 of ................ Sec. 264.1085 Sec. 265.1086 Sec. 61.344
Subpart QQ.
[[Page 68062]]
Containers...................... Sec. 63.135 Secs. 63.922 and 63.923 of ................ Sec. 264.1086 Sec. 265.1087 Sec. 61.345
Subpart PP.
Individual Drain System......... Sec. 63.136 Sec. 63.962 of Subpart RR.. Sec. 60.693-1 ................ ................ Sec. 61.346
Oil-water separators............ Sec. 63.137 Secs. 63.1042, 63.1043, and ................ ................ ................ Sec. 61.347
63.1044 of Subpart VV.
--------------------------------------------------------------------------------------------------------------------------------------------------------
Table 4 to Subpart YYY--Wastewater Tanks Requiring Controls and Control Requirements
----------------------------------------------------------------------------------------------------------------
Vapor
Capacity (m\3\) pressure Control requirements
(kPa)
----------------------------------------------------------------------------------------------------------------
<75......................................... ........... FR, IFR, EFR, or CVS and CD.
<gr-thn-eq>75 and <151...................... <13.1 FR, IFR, EFR, or CVS and CD.
<gr-thn-eq> IFR, EFR, or CVS and CD.
13.1
<gr-thn-eq>151.............................. <5.2 FR, IFR, EFR, or CVS and CD.
<gr-thn-eq> IFR, EFR, or CVS and CD.
5.2
----------------------------------------------------------------------------------------------------------------
FR means fixed roof requirements in the applicable compliance option.
IFR means internal floating roof requirements in the applicable compliance option.
EFR means external floating roof requirements in the applicable compliance option.
CVS and CD means closed vent system routed to a control device requirements in the applicable compliance option.
Table 5 to Subpart YYY--Compliance Options for Wastewater Tanks, Surface Impoundments, Containers, Individual Drain Systems, and Oil-Water Separators
--------------------------------------------------------------------------------------------------------------------------------------------------------
Part 60, subpart
Headings within Sec. 60.774 Part 63, subpart G Part 63 (standard- QQQ (petroleum Part 264, subpart Part 265, subpart Part 61, subpart
(HON) standards) refinery) CC (RCRA CC) CC (RCRA CC) FF (benzene waste)
--------------------------------------------------------------------------------------------------------------------------------------------------------
Control Requirements............ If WMU subject to Comply with If WMU subject to If WMU subject to If WMU subject to If WMU subject to
YYY or HON, then subpart QQ, PP, YYY or Petroleum YYY and RCRA, YYY and RCRA, YYY and Benzene
comply with HON RR, or VV control Refinery for part 264, then part 265, then Waste, then
control requirements, as individual drain comply with RCRA, comply with RCRA, comply with
requirements. applicable. systems, then part 264 control part 265 control Benzene Waste
comply with requirements. requirements. control
Petroleum requirements.
Refinery control
requirements.
Monitoring...................... If WMU subject to Comply with std- If WMU subject to If WMU subject to If WMU subject to If WMU subject to
HON, can comply stds provisions Petroleum part RCRA, part RCRA, part 265, Benzene Waste,
with either HON or YYY provisions. Refinery, then 264, then can then can comply then can comply
or YYY can comply with comply with with either RCRA, with either
provisions; if either Petroleum either RCRA, part part 265 or YYY Benzene Waste or
WMU not subject Refinery or YYY 264 or YYY provisions; if YYY provisions;
to HON, comply provisions; if provisions; if WMU not subject if WMU not
with YYY WMU not subject WMU not subject to RCRA, part subject to
provisions. to Petroleum to RCRA, part 265, comply with Benzene Waste,
Refinery, comply 264, comply with YYY provisions. comply with YYY
with YYY YYY provisions. provisions.
provisions.
Reporting....................... If WMU subject to Comply with std- If WMU subject to If WMU subject to If WMU subject to If WMU subject to
HON, can comply stds provisions Petroleum RCRA, part 264, RCRA, part 265, Benzene Waste,
with either HON or YYY provisions Refinery, then then can comply then can comply then can comply
or YYY *. can comply with with either RCRA, with either RCRA, with either
provisions; if either Petroleum part 264 or YYY part 265 or YYY Benzene Waste or
WMU not subject Refinery or YYY provisions; if provisions; if YYY provisions;
to HON, comply provisions; if WMU not subject WMU not subject if WMU not
with YYY WMU not subject to RCRA, part to RCRA, part subject to
provisions. to Petroleum 264, comply with 265, comply with Benzene Waste,
Refinery, comply YYY provisions. YYY provisions **. comply with YYY
with YYY provisions.
provisions.
[[Page 68063]]
Recordkeeping................... If WMU subject to Comply with std- If WMU subject to If WMU subject to If WMU subject to If WMU subject to
HON, can comply stds provisions Petroleum RCRA, part 264, RCRA, part 265, Benzene Waste,
with either HON or YYY provisions Refinery, then then can comply then can comply then can comply
or YYY *. can comply with with either RCRA, with either RCRA, with either
provisions; if either Petroleum part 264 or YYY part 265 or YYY Benzene Waste or
WMU not subject Refinery or YYY provisions; if provisions; if YYY provisions;
to HON, comply provisions; if WMU not subject WMU not subject if WMU not
with YYY WMU not subject to RCRA, part to RCRA, part subject to
provisions. to Petroleum 264, comply with 265, comply with Benzene Waste,
Refinery, comply YYY provisions. YYY provisions. comply with YYY
with YYY provisions.
provisions.
Leak Detection.................. If WMU subject to Comply with std- If WMU subject to If WMU subject to If WMU subject to If WMU subject to
HON, can comply stds provisions Petroleum RCRA, part 264, RCRA, part 265, Benzene Waste,
with either HON or YYY provisions. Refinery, then then can comply then can comply then can comply
or YYY can comply with with either RCRA, with either RCRA, with either
provisions; if either Petroleum part 264 or YYY part 265 or YYY Benzene Waste or
WMU not subject Refinery or YYY provisions; if provisions; if YYY provisions;
to HON, comply provisions; if WMU not subject WMU not subject if WMU not
with YYY WMU not subject to RCRA, part to RCRA, part subject to
provisions. to Petroleum 264, comply with 265, comply with Benzene Waste,
Refinery, comply YYY provisions. YYY provisions. comply with YYY
with YYY provisions.
provisions.
Delay of repair................. If WMU subject to Comply with std- If WMU subject to If WMU subject to If WMU subject to If WMU subject to
HON, can comply stds provisions Petroleum RCRA, part 264, RCRA, part 265, Benzene Waste,
with either HON or YYY provisions. Refinery, then then can comply then can comply then can comply
or YYY can comply with with either RCRA, with either RCRA, with either
provisions; if either Petroleum part 264 or YYY part 265 or YYY Benzene Waste or
WMU not subject Refinery or YYY provisions; if provisions; if YYY provisions;
to HON, comply provisions; if WMU not subject WMU not subject if WMU not
with YYY WMU not subject to RCRA, part to RCRA, part subject to
provisions. to Petroleum 264, comply with 265, comply with Benzene Waste,
Refinery, comply YYY provisions. YYY provisions. comply with YYY
with YYY provisions.
provisions.
Control device.................. If WMU subject to Comply with YYY If WMU subject to If WMU subject to If WMU subject to If WMU subject to
HON, can comply provisions. Petroleum part RCRA 264, RCRA, part 265, Benzene Waste,
with either HON Refinery, then then can comply then can comply then can comply
or YYY can comply with with either RCRA with either RCRA with either
provisions; if either Petroleum part 264 or YYY part 265 or YYY Benzene Waste or
WMU not subject Refinery or YYY provisions; if provisions; if YYY provisions;
to HON, comply provisions; if WMU not subject WMU not subject if WMU not
with YYY WMU not subject to RCRA part 264, to RCRA part 265, subject to
provisions. to Petroleum comply with YYY comply with YYY Benzene Waste,
Refinery, comply provisions. provisions. comply with YYY
with YYY provisions.
provisions.
--------------------------------------------------------------------------------------------------------------------------------------------------------
* The owner or operator shall comply with the recordkeeping and reporting provisions in Secs. 60.784 and 60.785 of this subpart when complying with the
provisions for containers in subpart PP.
** The owner or operator shall comply with the reporting provisions in Sec. 60.784 of this subpart when complying with the provisions of RCRA, 40 CFR
part 265.
Table 6 to Subpart YYY--Control Requirements for Items of Equipment That Meet the Criteria of Sec. 60.775
----------------------------------------------------------------------------------------------------------------
Item of equipment Control requirement <SUP>a
----------------------------------------------------------------------------------------------------------------
Drain or drain hub..................... (a) Tight fitting solid cover (TFSC); or
(b) TFSC with a vent to either a fuel gas system or to a control device
meeting the requirements of Sec. 60.780; or
(c) Water seal with submerged discharge or barrier to protect discharge
from wind.
Manhole <SUP>b.............................. (a) TFSC; or
(b) TFSC with a vent to a control device meeting the requirements of
Sec. 60.780; or
(c) If the item is vented to the atmosphere, use a TFSC with a properly
operating water seal at the entrance or exit to the item to restrict
ventilation in the collection system. The vent pipe shall be at least
90 cm in length and not exceeding 10.2 cm in diameter.
Lift station........................... (a) TFSC; or
(b) TFSC with a vent to a control device meeting the requirements of
Sec. 60.780; or
[[Page 68064]]
(c) If the lift station is vented to the atmosphere, use a TFSC with a
properly operating water seal at the entrance or exit to the item to
restrict ventilation in the collection system. The vent pipe shall be
at least 90 cm in length and not exceeding 10.2 cm in nominal inside
diameter. The lift station shall be level controlled to minimize
changes in the liquid level.
Trench................................. (a) TFSC; or
(b) TSFC with a vent to a control device meeting the requirements of
Sec. 60.780; or
(c) If the item is vented to the atmosphere, use a TFSC with a properly
operating water seal at the entrance or exit to the item to restrict
ventilation in the collection system. The vent pipe shall be at least
90 cm in length and not exceeding 10.2 cm in nominal inside diameter.
Pipe................................... Each pipe shall have no visible gaps in joints, seals, or other
emission interfaces.
Oil/Water separator.................... (a) Equip with a fixed roof and closed vent system that routes vapors
to a control device meeting the requirements of Sec. 60.780; or
(b) Equip with a floating roof that meets the equipment specifications
of Sec. 60.693 (a)(1)(i), (a)(1)(ii), (a)(2), (a)(3), and (a)(4).
Tank <SUP>c................................. Maintain a fixed roof <SUP>d. If the tank is sparged <SUP>e or used for heating
or treating by means of an exothermic reaction, a fixed roof and a
closed vent system shall be maintained that routes the VOC vapors to a
control device that meets the requirements of Sec. 60.780.
----------------------------------------------------------------------------------------------------------------
<SUP>a Where a tight fitting solid cover (TFSC) is required, it shall be maintained with no visible gaps or openings,
except during periods of sampling, inspection, or maintenance.
<SUP>b Manhole includes sumps and other points of access to a conveyance system.
<SUP>c Applies to tanks with capacities of 38 m<SUP>3 or greater.
<SUP>d A fixed roof may have openings necessary for proper venting of the tank, such as pressure/vacuum vent, j-pipe
vent.
<SUP>e The liquid in the tank is agitated by injecting compressed air or gas.
Table 7 to Subpart YYY--Monitoring Requirements for Treatment Processes
----------------------------------------------------------------------------------------------------------------
Parameters to be
To comply with monitored Frequency Methods
----------------------------------------------------------------------------------------------------------------
1. Required mass removal of each Appropriate parameters Appropriate frequency Appropriate methods as
organic treated in a properly as specified in Sec. as specified in Sec. specified in Sec.
operated biological treatment unit 60.781(c) and approved 60.781(c) and as 60.781(c) and as
Sec. 60.779. by the permitting approved by permitting approved by permitting
authority. authority. authority.
2. Design steam stripper Sec. Steam flow rate........ Continuously........... Integrating steam flow
60.779(d). monitoring device
equipped with a
continuous recorder.
Wastewater feed mass Continuously........... Liquid flow meter
flow rate. installed at stripper
influent and equipped
with a continuous
recorder.
Wastewater feed Continuously........... Liquid temperature
temperature. monitoring device
installed at stripper
influent and equipped
with a continuous
recorder.
3. Alternative monitoring parameters Other parameters may be ....................... .......................
monitored upon
approval from the
Administrator in
accordance with the
requirements specified
in Sec. 60.781(d).
----------------------------------------------------------------------------------------------------------------
Table 8 to Subpart YYY--Monitoring Requirements for Control Devices
----------------------------------------------------------------------------------------------------------------
Monitoring equipment Parameters to be
Control device required monitored Frequency
----------------------------------------------------------------------------------------------------------------
All control devices.................. 1. Flow indicator 1. Diversion to the Hourly records of
installed at all atmosphere from the whether the flow
bypass lines to the control device or. indicator was
atmosphere and operating and whether
equipped with a diversion was
continuous recorder <SUP>b detected at any time
or. during each hour.
Record and report the
times of all periods
when emissions are
diverted through a
bypass line or the
flow indicator is not
operating.
2. Valves sealed closed 2. Monthly inspections Monthly.
with car-seal or lock- of sealed valves.
and-key configuration.
Thermal Incinerator.................. Temperature monitoring Firebox temperature.... Continuous.
device installed in
firebox or in ductwork
immediately downstream
of firebox <SUP>a and
equipped with a
continuous recorder <SUP>b.
[[Page 68065]]
Catalytic Incinerator................ Temperature monitoring 1. Temperature upstream Continuous.
device installed in and downstream of
gas stream immediately catalyst bed.
before and after 2. Temperature
catalyst bed and difference across
equipped with a catalyst bed.
continuous recorder <SUP>b.
Flare................................ Heat sensing device Presence of a flame at Hourly records of
installed at the pilot the pilot light. whether the monitor
light and equipped was continuously
with a continuous operating and whether
recorder <SUP>b. the pilot flame was
continuously present
during each hour.
Boiler or process heater <44 Temperature monitoring Combustion temperature. Continuous.
megawatts and vent stream is not device installed in
mixed with the primary fuel. firebox <SUP>a and equipped
with continuous
recorder <SUP>b.
Condenser............................ Temperature monitoring Condenser exit (product Continuous.
device installed at side) temperature.
condenser exit and
equipped with
continuous recorder <SUP>b.
Carbon Adsorber (Regenerative)....... Integrating 1. Total regeneration For each regeneration
regeneration stream stream mass or cycle, record the
flow monitoring device volumetric flow during total regeneration
having an accuracy of carbon bed stream mass or
<plus-minus>10 regeneration cycle(s). volumetric flow.
percent, and.
Carbon bed temperature 2. Temperature of For each regeneration
monitoring device. carbon bed after cycle and within 15
regeneration [and minutes of completing
within 15 minutes of any cooling cycle,
completing any cooling record the carbon bed
cycle(s)]. temperature.
Carbon Adsorber (Non-regenerative)... Organic compound Organic compound Daily or at intervals
concentration concentration of no greater than 20
monitoring device <SUP>c. adsorber exhaust. percent of the design
carbon replacement
interval, whichever is
greater.
Alternative monitoring parameters.... Other parameters may be ....................... .......................
monitored upon
approval from the
Administrator in
accordance with the
requirements in Sec.
60.781(e)(3).
----------------------------------------------------------------------------------------------------------------
<SUP>a Monitor may be installed in the firebox or in the ductwork immediately downstream of the firebox before any
substantial heat exchange is encountered.
<SUP>b ``Continuous recorder'' is defined in Sec. 60.771 of this subpart.
<SUP>c As an alternative to conducting this monitoring, an owner or operator may replace the carbon in the carbon
adsorption system with fresh carbon at a regular predetermined time interval that is less than the carbon
replacement interval that is determined by the maximum design flow rate and organic concentration in the gas
stream vented to the carbon adsorption system.
Table 9 to Subpart YYY--Information on Process Wastewater Streams To Be Submitted With Notification of Compliance Status <SUP>a, <SUP>b
--------------------------------------------------------------------------------------------------------------------------------------------------------
Waste
Stream VOC Treatment management Intended
Process unit identification code <SUP>c identifi- concentration Flow rate Group 1 or Compliance process(es) unit(s) control
cation code (ppmw) <SUP>d, <SUP>e (lpm) <SUP>e, <SUP>f Group 2 <SUP>g approach <SUP>h identifi- identifi- device
cation <SUP>i cation
--------------------------------------------------------------------------------------------------------------------------------------------------------
--------------------------------------------------------------------------------------------------------------------------------------------------------
<SUP>a The information specified in this table 9 must be submitted; however, it may be submitted in any format. This table 9 presents an example format.
<SUP>b Other requirements for the Notification of Compliance Status are specified in Sec. 60.784(c).
<SUP>c Also include a description of the process unit (e.g., benzene process unit).
<SUP>d Except when Sec. 60.773(c) is used, annual average concentration as specified in Sec. 60.773(b) and Sec. 60.782.
<SUP>e When Sec. 60.773(c) is used, indicate the wastewater stream is a designated Group 1 wastewater stream.
<SUP>f Except when Sec. 60.773(c) is used, annual average flowrate as specified in Sec. 60.773(b) and Sec. 60.782.
<SUP>g Indicate whether stream is Group 1 or Group 2.
<SUP>h Cite Sec. 60.779 compliance option used.
<SUP>i Identification codes should correspond to those listed in Table 10 of this subpart.
[[Page 68066]]
Table 10 to Subpart YYY--Information for Treatment Processes To Be
Submitted With Notification of Compliance Status <SUP>a,b
------------------------------------------------------------------------
Wastewater
Treatment process Description <SUP>d stream(s) Monitoring
identification <SUP>c treated <SUP>e parameters <SUP>f
------------------------------------------------------------------------
------------------------------------------------------------------------
<SUP>a The information specified in this table 10 must be submitted; however,
it may be submitted in any format. This table 10 presents an example
format.
<SUP>b Other requirements for the Notification of Compliance Status are
specified in Sec. 60.784(c) of this subpart.
<SUP>c Identification codes should correspond to those listed in Table 9 of
this subpart.
<SUP>d Description of treatment process (e.g., steam stripper).
<SUP>e Stream identification code for each wastewater stream treated by each
treatment unit. Identification codes should correspond to entries
listed in Table 9 of this subpart.
<SUP>f Parameter(s) to be monitored or measured in accordance with Table 7
and Sec. 60.781 of this subpart.
Table 11 to Subpart YYY--Information for Waste Management Units To Be
Submitted With Notification of Compliance Status <SUP>a, <SUP>b
------------------------------------------------------------------------
Waste management unit Wastewater stream(s)
Identification <SUP>c Description <SUP>d received or managed <SUP>e
------------------------------------------------------------------------
------------------------------------------------------------------------
<SUP>a The information specified in this table 11 must be submitted; however,
it may be submitted in any format. This table 11 presents an example
format.
<SUP>b Other requirements for the Notification of Compliance Status are
specified in Sec. 60.784(c) of this subpart.
<SUP>c Identification codes should correspond to those listed in Table 9 of
this subpart.
<SUP>d Description of waste management unit.
<SUP>e Stream identification code for each wastewater stream received or
managed by each waste management unit. Identification codes should
correspond to entries listed in Table 9 of this subpart.
Table 12 to Subpart YYY--Information on Residuals To Be Submitted With Notification of Compliance Status <SUP>a, <SUP>b
--------------------------------------------------------------------------------------------------------------------------------------------------------
Control device
Residual Residual Wastewater stream Treatment Fate <SUP>g identification Control device Control device
identification <SUP>c description <SUP>d identification <SUP>e process <SUP>f code description <SUP>h efficiency <SUP>i
--------------------------------------------------------------------------------------------------------------------------------------------------------
--------------------------------------------------------------------------------------------------------------------------------------------------------
<SUP>a The information specified in this table 12 must be submitted; however, it may be submitted in any format. This table 12 presents an example format.
<SUP>b Other requirements for the Notification of Compliance Status are specified in Sec. 60.784(c) of this subpart.
<SUP>c Name or identification code of residual removed from Group 1 wastewater stream.
<SUP>d Description of residual (e.g., steam stripper A-13 overhead condensates).
<SUP>e Identification of stream from which residual is removed.
<SUP>f Treatment process from which residual originates.
<SUP>g Indicate whether residual is sold, returned to production process, or returned to waste management unit or treatment process; or whether VOC mass of
residual is destroyed by 99 percent.
<SUP>h If the fate of the residual is such that the VOC mass is destroyed by 99 percent, give description of device used for VOC destruction.
<SUP>i The fate of the residual is such that the VOC mass is destroyed by 99 percent, provide an estimate of control device efficiency and attach
substantiation in accordance with Sec. 60.784(c)(5) of this subpart.
Table 13 to Subpart YYY--Semiannual Reporting Requirements for Control
Devices [Sec. 60.784(f)]
------------------------------------------------------------------------
Control Device Reporting Requirements
------------------------------------------------------------------------
Thermal Incinerator.......................... 1. Report all daily
average <SUP>a temperatures
that are above the
maximum or below the
minimum operating
parameter value
established in the NCS <SUP>b
or operating permit and
all operating days when
insufficient monitoring
data are collected. <SUP>c
Catalytic Incinerator........................ 1. Report all daily
average <SUP>a upstream
temperatures that are
above the maximum or
below the minimum
operating parameter
value established in the
NCS <SUP>b or operating
permit.
[[Page 68067]]
2. Report all daily
average <SUP>a temperature
differences across the
catalyst bed that are
above the maximum or
below the minimum
operating parameter
value established in the
NCS <SUP>b or operating
permit.
3. Report all operating
days when insufficient
monitoring data are
collected. <SUP>c
Boiler or Process Heater with a design heat 1. Report all daily
input capacity less than 44 megawatts and average <SUP>a firebox
vent stream is not mixed with the primary temperatures that are
fuel. above the maximum or
below the minimum
operating parameter
value established in the
NCS <SUP>b or operating
permit and all operating
days when insufficient
monitoring data are
collected. <SUP>c
Flare........................................ 1. Report the duration of
all periods when all
pilot flames are absent.
Condenser.................................... 1. Report all daily
average <SUP>a exit
temperatures that are
above the maximum or
below the minimum
operating parameter
value established in the
NCS <SUP>b or operating
permit and all operating
days when insufficient
monitoring data are
collected. <SUP>c
Carbon Adsorber.............................. 1. Report all carbon bed
regeneration cycles when
the total regeneration
stream mass or
volumetric flow is above
the maximum or below the
minimum operating
parameter value
established in the NCS <SUP>b
or operating permit.
2. Report all carbon bed
regeneration cycles
during which the
temperature of the
carbon bed after
regeneration is above
the maximum or below the
minimum operating
parameter value
established in the NCS <SUP>b
or operating permit.
3. Report all operating
days when insufficient
monitoring data are
collected. <SUP>c
All Control Devices.......................... 1. Report the times and
durations of all periods
when the vent stream is
diverted through a
bypass line or the
monitor is not
operating, or
2. Report all monthly
inspections that show
the valves are moved to
the diverting position
or the seal has been
changed.
------------------------------------------------------------------------
<SUP>a The daily average is the average of all values recorded during the
operating day, as specified in Sec. 60.785(e) of this subpart.
<SUP>b NCS = Notification of Compliance Status described in Sec. 60.784(c)
of this subpart.
<SUP>c The semiannual reports shall include the duration of periods when
monitoring data are not collected for each excursion as defined in
Sec. 60.784(d)(3) of this subpart.
Table 14 to Subpart YYY--Compound and Default Biorates Used for
Compliance Demonstrations for Enhanced Biological Treatment Processes
(see Sec. 60.783(h))
------------------------------------------------------------------------
Biorate, K1 L/
Compound name g MLVSS-hr
------------------------------------------------------------------------
Acetonitrile........................................... 0.100
Acetophenone........................................... 0.538
Acrylonitrile.......................................... 0.750
Biphenyl............................................... 5.643
Chlorobenzene.......................................... 10.000
Dichloroethyl Ether (bis (2-chloroethyl ether)......... 0.246
Diethyl Sulfate........................................ .0105
Dimethyl Hydrazine (1,1-).............................. 0.227
Dimethyl Sulfate....................................... 0.178
Dinitrophenol (2,4-)................................... 0.620
Dinitrotoluene (2,4-).................................. 0.784
Dioxane (1,4-) (1,4-diethylene oxide).................. 0.393
Ethylene Glycol Dimethyl Ether......................... 0.364
Ethylene Glycol Monobutyl Ether Acetate................ 0.496
Ethylene Glycol Monomethyl Ether Acetate............... 0.159
Hexachlorobenzene...................................... 16.179
Isophorone............................................. 0.598
Methanol............................................... 0.200
Methyl Methacrylate.................................... 4.300
Nitrobenzene........................................... 2.300
Toluidine (-o)......................................... 0.859
Trichlorobenzene (1,2,4-).............................. 4.393
Trichlorophenol (2,4,5-)............................... 4.477
Triethylamine.......................................... 1.064
------------------------------------------------------------------------
3. Part 60 is amended by adding appendix J to read as follows:
Appendix J to Part 60--How to Determine Henry's Law Constants, Fm
Values, Fr Values, and Fe Values for Organic Compounds
1. Use of Appendix and General Information. This appendix has
four sections. Section 2 contains the procedures for determining
Henry's law constants, fraction measured (Fm) values, fraction
removed values (Fr), and fraction emitted (Fe) values for an
individual chemical. Section 3 describes how to locate certain
resources. Section 4 contains five tables and thirteen forms.
1.1 You should use this appendix if you need to:
1. Determine whether a chemical has a Henry's law constant at
25 deg. C that is less than 0.1 y/x atmosphere per mole fraction
(see section 2.1).
2. Determine a fraction measured (Fm) value for a chemical (see
section 2.2).
[[Page 68068]]
3. Subtract the concentration of a chemical from a Method 25D
concentration (see section 2.3).
4. Determine the fraction removed (Fr) value for a chemical that
has a Henry's law constant at 25 deg. C that is greater than or
equal to 0.1 y/x atmosphere per mole fraction (see section 2.4).
5. Determine the fraction emitted (Fe) value for a chemical that
has a Henry's law constant at 25 deg. C that is greater than or
equal to 0.1 y/x atmosphere per mole fraction (see section 2.5).
6. Calculate a Henry's law constant at a specific temperature
using a Henry's law constant at a different temperature for the same
chemical (see section 2.6).
1.2 This appendix requires documentation for some procedures.
The referencing subpart, i.e., the rule to which you are complying,
may require additional recordkeeping and may specify records
concerning this appendix that are to be included in reports.
1.3 When the term ``WATER8'' is used in this appendix, the term
``WATER8, or updates to WATER8'' must be used for the purposes of
this appendix. When the term ``CHEM9'' is used in this appendix, the
term ``CHEM9, or updates to CHEM9'' must be used for the purposes of
this appendix. When the terms ``waste'' or ``wastewater'' are used
in this appendix, the term ``waste or wastewater, as applicable to
the referencing subpart'' must be used for the purposes of this
appendix. When the terms ``Henry's law constant'' or ``Henry's law
constants'' are used in this appendix, the terms ``Henry's law
constant(s) with units of atmosphere per mole fraction'' must be
used for the purposes of this subpart.
2. Procedures.
2.1 How to determine whether a chemical has a Henry's law
constant at 25 deg. C that is less than 0.1 y/x. You must use one of
the following to determine whether a chemical has a Henry's law
constant that is less than 0.1 y/x atmosphere per mole fraction.
2.1.1 Use Table 1. The chemicals listed in Table 1 have a Henry's
law constant at 25 deg. C that is less than 0.1 y/x atmosphere per
mole fraction.
2.1.2 Use CHEM9 or WATER8. Use CHEM9 or WATER8 to determine the
Henry's law constant at 25 deg. C. You must know compound
properties, such as solubility in water and vapor pressure, and the
structure of the compound to estimate a Henry's law constant using
CHEM9 or WATER8.
2.1.3 Determine experimentally. The Henry's law constant may be
measured by several laboratory techniques. These techniques can be
categorized as either two phase closed systems techniques or open
system techniques.
2.1.3.1 Two phase closed systems. For two phase closed system
techniques, the volume of each phase and two concentration
measurements are needed. The concentration measurements are: (1)
concentration in one of the phases, and (2) either the concentration
in the other phase or the total concentration in both phases. Use
Form 1 to calculate the Henry's law constant for two phase closed
systems.
2.1.3.2 Open systems. For open systems, gas is passed through a
liquid volume containing the compound. The Henry's law constant is
calculated from the rate of stripping of the compound from the
water. Use Form 2 to calculate the Henry's law constant for open
systems.
2.1.4 Calculate a Henry's law constant at 25 deg. C from a Henry's
law constant at a different temperature for the same chemical. Use
the procedures specified in section 2.6 to calculate a Henry's law
constant at 25 deg. C from a Henry's law constant at a different
temperature for the same chemical.
2.2. How to determine a Fm value for a chemical. Fm means compound-
specific fraction measured factor, and it has the units of mass
measured by Method 25D divided by the total mass in the wastewater.
You must use one of the following to determine the Fm value for a
chemical.
2.2.1 Use Table 1 or Table 2. To determine the Fm value for a
chemical with a Henry's law constant at 25 deg. C that is less than
0.1 y/x atmosphere per mole fraction, use the Fm value listed for
the chemical in Table 1. To determine the Fm value for a chemical
with a Henry's law constant at 25 deg. C that is greater than or
equal to 0.1 y/x, use the Fm value listed for the chemical in Table
2.
Note to section 2.2.1: Table 1 and Table 2 include Fm values for
Method 25D and for Method 305. Unless otherwise specified in this
appendix or the referencing subpart, use the Fm values for Method
25D.
2.2.2 Use CHEM9. Use CHEM9 to determine an Fm value. You must
know the structure of the chemical and certain other compound
properties, e.g., boiling point, Antoine's coefficients, vapor
pressure, and solubility in water, to estimate an fm value using
CHEM9. The accuracy of the computer estimation procedure depends on
the nature of the compound and the quality of the available data.
The procedure is flexible in that the method can be used with a
variety of different types of compound data. You must confirm and
document the compound properties used as inputs for CHEM9 and the
lack of availability for missing compound properties. In some cases,
this method is not accurate, especially with missing compound
properties. Before accepting the estimation values of CHEM9 in these
cases, you must document the consistency of the predicted values
with other related experimental data.
2.2.3 Measure the Fm value. Spike a sample of waste with a
known amount of the compound of interest. Measure the concentration
of the sample using Method 25D. The Fm value for the recovery of a
specific chemical is the ratio of the Method 25D concentration to
the actual concentration in the waste sample. You must minimize loss
of organic compounds during sample collection and analysis, and
maintain sample integrity. An example of acceptable sampling and
handling procedures are the sampling and handling requirements in
Method 25D.
2.2.4 Extrapolating a Method 25D Fm Value from a Method 305 Fm
value. Method 305 measures the recovered concentration, not the
actual concentration in the wastewater. The Method 25D correction
value may be obtained from the Method 305 value and the ratio of the
Method 25D value to the Method 305 value for that compound. This
ratio for a compound is independent of the wastewater and may be
determined once for each compound.
2.3 How to subtract a chemical from a Method 25D concentration.
You must follow the procedures specified in sections 2.3.1 through
2.3.5 to subtract a chemical's concentration from the total
concentration measured by Method 25D. You may only subtract from the
total Method 25D concentration compounds for which you have a
measured concentration (i.e., you must not subtract compounds for
which test results are below the quantification limit.) If an Fm
value cannot be determined for a chemical, the concentration of the
chemical cannot be subtracted from the Method 25D results. You must
follow the procedures in Form 3 to subtract a chemical from a Method
25D concentration. Form 4 provides an example.
2.3.2 Determine the concentration for each chemical in the
wastewater stream that will be subtracted from the Method 25D
concentration. The concentration for each chemical must be
determined using a method and sampling procedure specified in the
referencing subpart. Methods other than Method 25D and Method 305
are considered alternative methods for the purposes of this
appendix.
2.3.3 Determine the correct Fm value. If an Fm value is needed,
use the procedures in section 2.2 of this appendix to determine the
correct Fm value.
2.3.4 Adjust the concentration of chemicals which may be
subtracted from the Method 25D concentration. You must multiply the
concentration of the chemical measured by the alternative method
(i.e., a method that is not Method 25D or Method 305 and that is
specified in the referencing subpart) by the Method 25D Fm. The
product will be the adjusted concentration for that chemical. This
adjustment must be done for each chemical you subtract from the
concentration measured by Method 25D.
2.3.5 Subtract. Subtract the product(s) you calculated from the
Method 25D concentration.
2.4 How to determine an Fr value for a chemical with a Henry's
law constant at 25 deg. C that is greater than or equal to 0.1 y/x.
Fr means fraction removal value and is unitless. You must use one of
the following to determine a Fr value.
2.4.1 Use Table 2. Use the Fr value listed for the chemical in
Table 2. The chemicals listed in table 2 have a Henry's law constant
at 25 deg. C that is greater than or equal to 0.1 y/x.
2.4.2 Use 0.99. Assign an Fr value of 0.99 to any chemical.
This is the highest Fr value that is assigned to a chemical.
2.4.3 Use CHEM9. Use CHEM9 to determine the Fr value of a
chemical. You must know the compound structure and the Henry's law
constant at 100 deg. C to estimate an Fr value using CHEM9. The
Henry's law constant at 100 deg. C for a chemical must be determined
as specified in either section 2.4.3.1, 2.4.3.2, or 2.4.3.3. The
method used to determine the Henry's law constant at 100 deg. C for
a chemical must be documented.
2.4.3.1 Determine Henry's law at 100 deg. C experimentally. The
Henry's law constant
[[Page 68069]]
may be measured by several laboratory techniques. These techniques
can be categorized as either two phase closed systems techniques or
open system techniques.
2.4.3.1.1 Two phase closed systems. For two phase closed system
techniques, the volume of each phase and two concentration
measurements are needed. The concentration measurements are: (1)
concentration in one of the phases, and (2) either the concentration
in the other phase or the total concentration in both phases. Use
Form 1 to calculate the Henry's law constant for two phase closed
systems.
2.4.3.1.2 Open systems. For open systems, gas is passed through
a liquid volume containing the compound. The Henry's law constant is
calculated from the rate of stripping of the compound from the
water. Use Form 2 to calculate the Henry's law constant for open
systems.
2.4.3.2 Calculate a Henry's law constant at 100 deg. C from a
Henry's law constant at a different temperature for the same
chemical. Use the procedures in section 2.6 to calculate a Henry's
law constant at 100 deg. C from a Henry's law constant at a
different temperature for the same chemical.
2.4.3.3 Literature Value. Experimental values of Henry's law
constants at a 100 deg. C for some chemicals are available in data
bases or reported in the literature. You must provide the reference
for and description of any database or literature you used.
2.5 How to determine an Fe value for a chemical that has a
Henry's law constant at 25 deg. C that is greater than or equal to
0.1 y/x. Use the appropriate Fe value as specified in the
referencing subpart.
2.5.1 Default Fe values for emissions from both the individual
drain system and the treatment process. You must measure the
temperature of the wastewater stream at the point of determination,
unless another location is specified by the referencing subpart. If
the temperature of the wastewater stream is less than or equal to
35 deg. C, you may use the default Fe values listed in either Table
2 or Table 3. If the temperature of the wastewater stream is greater
than 35 deg. C, you must use the default Fe values listed in Table
3.
2.5.1.1 Use Table 2. To use Table 2, use the default Fe value
listed for the chemical in Table 2.
2.5.1.2 Use Table 3. You must either use a default Fe listed in
Table 3 or use Table 3 to interpolate an Fe value. To use Table 3,
you must determine the chemical's Henry's law constant at the
temperature you measured for the wastewater stream. You must find
this Henry's law constant in the table and select an Fe value
greater than or equal to the Fe value that corresponds to the
Henry's law constant.
2.5.2 Site-specific Fe values for emissions from the individual
drain system. Use WATER8 and Forms 6 and 7 for each type of waste
management unit modeled and Forms 8 through 13, as appropriate for
the different types of waste management units. (Note that this Fe
value does not include Fe values for the treatment process.)
2.5.3 Default Fe values for emissions from the biological
treatment process (Fet). The default Fe values in Table 4 and Table
5 are Fe values for the biological treatment system (i.e., the
wastewater treatment plant) and have been assigned the abbreviation
``Fet.'' You must measure the temperature of the wastewater
stream(s) treated in the biological treatment system at the inlet to
the biological treatment system (e.g., at the bar screen). If the
temperature of the wastewater stream(s) is less than or equal to
35 deg. C, you must use either Table 4 or Table 5 to determine the
Fet value. If the temperature of the wastewater stream is greater
than 35 deg. C, you must use Table 5 to determine the Fet value.
2.5.3.1 Use Table 4. To use Table 4, use the default Fet value
listed for the chemical in Table 4.
2.5.3.2 Use Table 5. To use Table 5, you must either use a
default Fet listed in Table 5 or use Table 5 to interpolate an Fet
value. You must determine the chemical's Henry's law constant at the
temperature you measured for the wastewater stream. You must find
this Henry's law constant in the table and select an Fet value
greater than or equal to the Fet value that corresponds to the
Henry's law constant.
2.6 How to calculate a Henry's law constant from a Henry's law
constant at a different temperature for the same chemical. Use
WATER8 and Form 5 to estimate a Henry's law constant from a Henry's
law constant at a different temperature for the same chemical.
3. Location of resources.
3.1 Where to find information on CHEM9 and WATER8.
3.1.1 CHEM9 and WATER8 access via Internet. You can find CHEM9
and WATER8 on the Internet by accessing EPA's Technology Transfer
Network (TTN) via the Internet. The Internet address is: http://
www.epa.gov/ttn/chief/software.html. If you need more information on
the TTN, contact the systems operator at (919) 541-5384.
3.1.2 Procedures used in CHEM9. Reports describing the CHEM9
procedures for estimating Fm, Fr, and Fe values are in Docket Number
A-94-32, Item IV-A-1. The database for CHEM9 is not available as a
hard copy.
Docket No. A-94-32 is available for public inspection and
copying between 8:00 a.m. and 5:30 p.m., Monday through Friday, at
the EPA's Air and Radiation Docket and Information Center, Waterside
Mall, Room M-1500, first floor, 401 M Street SW, Washington, DC
20460, or by calling (202) 260-7548 or 260-7549. A reasonable fee
may be charged for copying.
3.2 Methods.
Method 25D can be found in 40 CFR part 60, Appendix A.
Method 305 can be found in 40 CFR part 63, Appendix A.
4. Tables and Forms. This section contains 5 tables and 13
forms.
Table 1 of Appendix J.--FM Values for Henry's Law Constants at 25 deg.C Less Than 0.1 (Y/X) Atmospheres per Mole
Fraction
[Use with Section 2.1]
----------------------------------------------------------------------------------------------------------------
Compound Y/X Fm 25D Fm 305
----------------------------------------------------------------------------------------------------------------
1H IMIDAZOLE.................................................... 0.000004 0.001 0.001
2,4 D........................................................... 0.000000 0.151 0.167
2,4,5 BENZOIC ACID.............................................. 0.000007 0.000 0.000
2-HYDROXYETHANAL................................................ 0.001400 0.031 0.059
3,4-DIMETHYLPHENOL xylenol...................................... 0.004200 0.018 0.017
3,5-DIBROMO-4HYDROXYBENZONITRILE................................ 0.011700 0.021 0.033
3-OXOPROPANOIC ACID............................................. 0.007900 0.002 0.004
4-OXOBUTANOIC ACID.............................................. 0.011100 0.004 0.006
5-OXOPENTANOIC ACID............................................. 0.013900 0.005 0.007
ACETALDOL....................................................... 0.001900 0.011 0.016
ACETAMIDE....................................................... 0.000100 0.305 0.463
ACETYL-2-THIOUREA, 1-........................................... 0.001600 0.034 0.053
ACETYL-5-HYDROXYPIPERIDINE 3.................................... 0.038900 0.001 0.001
ACETYLAMINOFLUORENE, 2-......................................... 0.074400 0.020 0.018
ACETYLPIPERIDINE 3.............................................. 0.006900 0.151 0.175
ACRIDINE ORANGE*................................................ 0.013300 0.050 0.049
ACRIDINE YELLOW*................................................ 0.000400 0.001 0.001
ACRYLAMIDE...................................................... 0.000015 0.003 0.003
ACRYLIC ACID.................................................... 0.011000 0.431 0.643
ADAMANTANE DICARBOXYLIC ACID.................................... 0.002600 0.001 0.001
[[Page 68070]]
ADENINE......................................................... 0.000005 0.001 0.002
ADIPIC ACID..................................................... 0.000003 0.001 0.001
ADIPONITRILE.................................................... 0.000700 0.004 0.004
ALACHLOR (M).................................................... 0.001800 0.090 0.090
alpha-PICOLINE.................................................. 0.025900 0.870 0.842
AMETRYN......................................................... 0.000001 0.001 0.001
AMINOBIPHENYL, 4-............................................... 0.017200 0.012 0.011
AMINOETHYLPIPERAZINE............................................ 0.000021 0.001 0.001
AMINOPHENOL, 3-................................................. 0.003400 0.035 0.040
AMINOPYRIDINE, 4-............................................... 0.000005 0.000 0.001
ANILINE......................................................... 0.097800 0.142 0.138
ANISIDINE, o-................................................... 0.097200 0.011 0.013
ANTHRAQUINONE................................................... 0.000200 0.001 0.001
ATRAZINE (M).................................................... 0.000200 0.117 0.117
BENZENE ACETIC ACID............................................. 0.025500 0.014 0.015
BENZENE ARSONIC ACID (M)........................................ 0.000006 0.124 0.124
BENZENE DICARBOXYLIC ACID....................................... 0.000900 0.001 0.001
BENZENE SULFONIC ACID (M)....................................... 0.043900 0.146 0.146
BENZIDINE....................................................... 0.000001 0.000 0.000
BENZO (A) ANTHRACENE............................................ 0.000077 0.121 0.095
BENZO(A) PYRENE................................................. 0.000077 1.267 1.000
BENZO (ghi) PERYLENE............................................ 0.002800 0.006 0.005
BENZO (k) FLUORANTHENE.......................................... 0.000059 0.001 0.001
BENZOIC ACID.................................................... 0.001000 0.003 0.003
BENZOTHIAZOLONE 2 (2H)- *....................................... 0.065600 0.121 0.123
BENZYL ALCOHOL.................................................. 0.033900 0.069 0.067
BHC, gamma-..................................................... 0.027400 1.035 0.973
BIS (2-ETHYLHEXYL) PHTHALATE.................................... 0.016700 0.317 0.327
BROMOCHLOROMETHYL ACETATE....................................... 0.010400 0.342 0.541
BUTYL CELLOSOLVE................................................ 0.014600 0.095 0.120
BUTYL-m-CRESOL MONO T........................................... 0.052100 0.042 0.039
BUTYL-p-CRESOL MONO T........................................... 0.052100 0.042 0.039
BUTYRIC ACID.................................................... 0.096100 0.089 0.124
CAPROLACTAM..................................................... 0.000200 0.002 0.003
CAPROLACTONE.................................................... 0.071100 0.205 0.248
CATECHOL........................................................ 0.000002 0.000 0.000
CHLORACETOPHENONE, 2-........................................... 0.048400 0.161 0.152
CHLORO (-p) CRESOL (-m)......................................... 0.009100 0.029 0.028
CHLORO-1, 2-ETHANE DIOL (M)..................................... 0.005400 0.999 0.999
CHLORO-2, 5-DIKETOPYRROLIDINE 3 (M)............................. 0.003700 0.430 0.430
CHLOROACETIC ACID............................................... 0.003600 0.020 0.028
CHLOROANILINE, p-............................................... 0.014700 0.069 0.067
CHLOROBENZOPHENONE (PARA)....................................... 0.000200 0.313 0.283
CHLOROBENZYLATE................................................. 0.000028 0.000 0.000
CHLOROHYDRIN, a 3 CHLORO 1, 2 PROPAN............................ 0.000300 0.003 0.004
CHLOROPHENOL POLYMERS (M)....................................... 0.005600 0.000 0.000
CHLOROPHENOL-4.................................................. 0.062200 0.032 0.031
CHOLINE CHLORIDE................................................ 0.000600 0.012 0.015
CHRYSENE........................................................ 0.000066 0.006 0.004
CITRIC ACID..................................................... 0.000000 0.000 0.000
CREOSOTE (M).................................................... 0.004400 0.025 0.025
CRESOL.......................................................... 0.090000 0.049 0.047
CRESOL (-m)..................................................... 0.039400 0.035 0.033
CRESOL (-o)..................................................... 0.091200 0.057 0.055
CRESOL (-p)..................................................... 0.039700 0.028 0.027
CUMYLPHENOL-4................................................... 0.093300 0.002 0.002
CYANIDE methyl.................................................. 0.001500 0.328 0.417
CYANOMETHYL BENZOATE 4 (M)...................................... 0.000700 0.128 0.128
DIAZINON........................................................ 0.001200 0.001 0.001
DIBENZO (a,h ) ANTHRACENE....................................... 0.002100 0.001 0.001
DIBUTYLPHTHALATE................................................ 0.015600 0.002 0.002
DICHLORO--(2,6)-NITROANILINE (4) (M)............................ 0.000400 0.122 0.122
DICHLOROANILINE 2, 3............................................ 0.029900 0.049 0.047
DICHLOROBENZONITRILE,2 ,6-...................................... 0.064400 0.338 0.322
DICHLOROPHENOL 2, 5............................................. 0.086100 0.151 0.148
DICHLOROTETRAHYDROFURAN 3, 4 (M)................................ 0.007800 0.303 0.303
DICHLORVOS...................................................... 0.019000 0.008 0.011
DIETHANOLAMINE.................................................. 0.000000 0.000 0.000
DIETHYL (N, N) ANILINE.......................................... 0.003200 0.964 0.907
[[Page 68071]]
DIETHYL PROPIONAMIDE, 2aN (M)................................... 0.001100 0.089 0.089
DIETHYLENE GLYCOL............................................... 0.077800 0.000 0.000
DIETHYLENE GLYCOL DIMETHYL ETHER................................ 0.083800 0.105 0.150
DIETHYLENE GLYCOL MONOBUTYL ETHER............................... 0.001200 0.003 0.003
DIETHYLENE GLYCOL MONOETHYL ETHER............................... 0.002700 0.005 0.007
DIETHYLENE GLYCOL MONOETHYL ETHER A............................. 0.035800 0.007 0.010
DIETHYLENE GLYCOL MONOMETHYL ETHER.............................. 0.003200 0.004 0.007
DIETHYLENETRIAMINE.............................................. 0.000001 0.000 0.000
DIETHYLHYDRAZINE N, N........................................... 0.019000 0.184 0.253
DIETHYLTHIOPHOSPHATEBENZO M ETHYL P............................. 0.001200 0.000 0.000
DIMETHOATE (M).................................................. 0.050900 0.110 0.110
DIMETHYL CARBAMOYL CHLORIDE..................................... 0.024700 0.116 0.151
DIMETHYL DISULFIDE.............................................. 0.083300 0.455 1.000
DIMETHYL FORMAMIDE.............................................. 0.010600 0.009 0.013
DIMETHYL HYDRAZINE (1, 1)....................................... 0.091100 0.277 0.382
DIMETHYL PHTHALATE.............................................. 0.054800 0.006 0.007
DIMETHYLAMINOAZOBENZENE,4-...................................... 0.004100 0.022 0.023
DIMETHYLBENZ (A) ANTHRACENE (7, 12)............................. 0.000015 0.008 0.006
DIMETHYLBENZIDINE 3,3........................................... 0.000075 0.000 0.000
DIMETHYLSULFONE................................................. 0.001300 0.002 0.003
DIMETHYLSULFOXIDE............................................... 0.026900 0.037 0.057
DINITRO-o-CRESOL (4, 6)......................................... 0.078000 0.009 0.016
DIPHENYLHYDRAZINE (1, 2)........................................ 0.013600 0.462 0.448
DIPROPYLENE GLYCOL.............................................. 0.000900 0.002 0.003
ENDRIN.......................................................... 0.084400 0.005 0.004
EPINEPHRINE (M)................................................. 0.020300 0.133 0.133
ETHANOLAMINE (mono-)............................................ 0.017800 0.004 0.007
ETHYL CARBAMATE................................................. 0.000600 0.004 0.008
ETHYL MORPHOLINE, ethyl diethylene.............................. 0.011300 0.048 0.059
ETHYLENE GLYCOL................................................. 0.000100 0.002 0.005
ETHYLENE GLYCOL MONOBUTYL ETHER................................. 0.029200 0.056 0.071
ETHYLENE GLYCOL MONOETHYL ETHER................................. 0.061700 0.111 0.144
ETHYLENE GLYCOL MONOETHYL ETHER AC.............................. 0.098600 0.057 0.089
ETHYLENE GLYCOL MONOMETHYL ETHER................................ 0.045800 0.101 0.163
ETHYLENE GLYCOL MONOPHENYL ETHER................................ 0.003800 0.005 0.005
ETHYLENE GLYCOL MONOPROPYL ETHER................................ 0.047400 0.182 0.242
ETHYLENE THIOUREA............................................... 0.000008 0.001 0.002
ETHYLPHENOL, 3-................................................. 0.005600 0.021 0.020
FLUOROACETIC ACID, SODIUM SALT*................................. 0.000300 0.750 1.000
FORMALDEHYDE.................................................... 0.018700 0.533 1.000
FORMAMIDE....................................................... 0.065600 0.092 0.170
FORMIC ACID..................................................... 0.038900 0.078 0.225
FUMARIC ACID.................................................... 0.092200 0.000 0.000
GLUTARIC ACID................................................... 0.001100 0.000 0.000
GLYCERIN (GLYCEROL)............................................. 0.000700 0.000 0.000
GLYCINAMIDE..................................................... 0.008200 0.019 0.089
GLYOXYLIC ACID.................................................. 0.006200 0.001 0.002
GLYPHOSATE...................................................... 0.000400 0.005 0.009
GUANIDINE, NITROSO*............................................. 0.048900 0.000 0.001
GUTHION......................................................... 0.000093 0.001 0.001
GYLCIDOL........................................................ 0.050100 0.024 0.032
HEXAMETHYLENE 1, 6 DIISOCYANATE................................. 0.014800 0.005 0.007
HEXAMETHYLPHOSPHORAMIDE......................................... 0.000000 0.000 0.000
HEXANOIC ACID................................................... 0.058900 0.061 0.075
HYDRAZINE....................................................... 0.037000 0.190 0.332
HYDROCYANIC ACID (M)............................................ 0.025800 0.999 0.999
HYDROQUINONE.................................................... 0.000080 0.000 0.000
HYDROXY-(2)-PROPIONITRILE....................................... 0.004200 0.003 0.004
HYDROXYPROPIONALDEHYDE.......................................... 0.013200 0.066 0.102
INDENO(1,2,3-cd)-PYRENE......................................... 0.000000 0.000 0.000
LEAD ACETATE (M)................................................ 0.000041 0.062 0.062
LEAD SUBACTEATE (M)............................................. 0.000800 0.000 0.000
LEUCINE (M)..................................................... 0.030000 0.469 0.469
MALATHION (M)................................................... 0.006700 0.060 0.060
MALEIC ACID..................................................... 0.000800 0.000 0.000
MALEIC ANHYDRIDE................................................ 0.012200 0.027 0.043
MALIC ACID (hydroxybutaneoic)................................... 0.000000 0.000 0.000
MESITYL OXIDE (M)............................................... 0.019500 0.999 0.999
METHANE SULFONIC ACID *......................................... 0.026700 0.000 0.001
[[Page 68072]]
METHOMYL........................................................ 0.045100 0.008 0.013
METHOXYPHENOL P................................................. 0.017200 0.003 0.003
METHYL HYDRAZINE................................................ 0.024800 0.082 0.155
METHYL METHANESULFONATE......................................... 0.000039 0.001 0.001
METHYL PARATHION................................................ 0.000007 0.012 0.020
METHYL SULFURIC ACID (M)........................................ 0.031200 0.794 0.794
METHYL THIOPHENOL 4............................................. 0.024400 0.885 1.000
METHYL-2-METHOXYAZIRIDINE 1..................................... 0.024200 0.727 0.998
METHYLENE DIPHENYL DIISOCYANATE................................. 0.002700 0.010 0.011
METHYLENE DIPHENYLAMINE (MDA)................................... 0.001600 0.002 0.002
METHYLENE-BIS (2-CHLOROANILINE), 4, 4........................... 0.018700 0.008 0.008
METHYLENEDIANILINE 4, 4......................................... 0.028500 0.001 0.001
METHYLETHYLIDENE BISPHENOL, 4, 4'............................... 0.000001 0.000 0.000
METHYLFURFURAL 5................................................ 0.012200 0.859 1.000
METHYLIMINOACETIC ACID.......................................... 0.055600 0.002 0.004
MONOMETHYL FORMANIDE............................................ 0.000054 0.003 0.005
NABAM........................................................... 0.000000 0.000 0.000
NAPHTHOL, alpha-................................................ 0.001400 0.004 0.004
NAPHTHOL, beta-................................................. 0.000800 0.003 0.003
NAPHTHYLAMINE, alpha-........................................... 0.002800 0.005 0.005
NAPHTHYLAMINE, beta-............................................ 0.002000 0.004 0.004
NEOPENTYL GLYCOL................................................ 0.000900 0.004 0.005
NIACIN (M)...................................................... 0.034200 0.606 0.606
NIACINAMIDE(M).................................................. 0.067800 0.623 0.623
NITROANILINE (-o) (M)........................................... 0.027800 0.351 0.351
NITROGLYCERIN................................................... 0.000000 0.013 0.047
NITROPHENOL, 2-................................................. 0.006500 0.011 0.016
NITROPHENOL, 4-................................................. 0.000073 0.001 0.001
NITROSODIMETHYLAMINE N.......................................... 0.048800 0.103 0.285
NITROSODI-n-PROPYLAMINE N....................................... 0.025200 0.088 0.105
NITROSODIPHENYLAMINE N *........................................ 0.046000 0.026 0.025
NITROSOMORPHOLINE............................................... 0.004700 0.011 0.019
NITROSO-N-METHYLUREA N.......................................... 0.001400 0.015 0.037
OODIETH . O2ETH . THIOETH . PHOSPHORATE (M)..................... 0.000000 0.096 0.096
OXALIC ACID..................................................... 0.000200 0.010 0.028
PARATHION....................................................... 0.034000 0.001 0.001
PENTAERYTHRITOL................................................. 0.000021 0.000 0.000
PHENACETIN (M).................................................. 0.012400 0.135 0.135
PHENOL.......................................................... 0.072200 0.036 0.035
PHENYL MERCURIC ACETATE (M)..................................... 0.000700 0.057 0.057
PHENYLACETIC ACID (M)........................................... 0.045600 0.385 0.385
PHENYLENE DIAMINE (-m).......................................... 0.000600 0.000 0.000
PHENYLENE DIAMINE (-o).......................................... 0.000600 0.001 0.002
PHENYLENE DIAMINE (-p).......................................... 0.000070 0.001 0.001
PHORATE (M)..................................................... 0.024300 0.095 0.095
PHTHALIC ANHYDRIDE.............................................. 0.044100 0.016 0.019
PROPANE SULTONE, 1, 3-.......................................... 0.000500 0.001 0.002
PROPANONAL (methylglyoxal)...................................... 0.001700 0.161 0.242
PROPIOLACTONE b................................................. 0.006400 0.199 0.304
PROPORUR (Baygon)............................................... 0.003200 0.004 0.004
PROPYLENE GLYCOL................................................ 0.083300 0.005 0.008
PYRIDINIUM BROMIDE (M).......................................... 0.091700 0.060 0.060
PYRUVIC ACID.................................................... 0.000200 0.003 0.005
QUINOLINE....................................................... 0.015000 0.002 0.002
QUINONE......................................................... 0.057700 0.868 1.000
RESORCINOL...................................................... 0.001000 0.000 0.000
SIMAZINE (M).................................................... 0.000045 0.124 0.124
SODIUM ACETATE.................................................. 0.000200 0.042 0.079
SODIUM ACRYLATE................................................. 0.076100 0.073 0.108
SODIUM FORMATE.................................................. 0.000094 0.356 0.988
STRYCHNIDIN-10-ONE, 2, 3-DIMETHOXY(M)........................... 0.000800 0.028 0.028
STRYCHNINE (M).................................................. 0.000002 0.058 0.058
SUCCINIC ACID................................................... 0.000097 0.000 0.001
SUCCINIMIDE *................................................... 0.001800 0.000 0.001
SULFANILIC ACID (M)............................................. 0.088900 0.138 0.138
TEREPHTHALIC ACID............................................... 0.000600 0.001 0.001
TETRAETHYLDITHIOPYROPHOSPHATE................................... 0.00040 .............. ..............
TETRAETHYLENE GLYCOL MONOMETHYL ETH............................. 0.000200 0.000 0.001
TETRAETHYLENE PENTAMINE......................................... 0.000000 0.000 0.000
[[Page 68073]]
TETRAETHYLENE PENTAMINE......................................... 0.000000 0.000 0.000
TETRAHYDRO 3-FURANOL............................................ 0.034400 0.095 0.134
THIOFANOX (M)................................................... 0.000500 0.116 0.116
THIOSEMICARBAZIDE*.............................................. 0.003300 0.000 0.000
THIOUREA, 1- (o-CHLOROPHENYL)-.................................. 0.000001 0.000 0.001
TOLUENE DIAMINE (2, 4).......................................... 0.000070 0.001 0.001
TOLUENE DIISOCYANATE (2, 4)..................................... 0.009200 0.000 0.000
TOLUENEDIAMINE (2, 6)........................................... 0.000001 0.000 0.000
TOLUENEDIAMINE (3, 4)........................................... 0.000200 0.002 0.002
TOLUIC ACID (para-)............................................. 0.000300 0.011 0.012
TOLUIDINE m..................................................... 0.089400 0.123 0.118
TRICHLORO (1, 1, 2) TRIFLUOROETHANE............................. 0.000008 1.042 1.000
TRIETHANOLAMINE................................................. 0.000008 0.000 0.000
TRIETHYLENE GLYCOL DIMETHYL ETHER............................... 0.002600 0.017 0.025
TRIETHYLENE GLYCOL MONOMETHYL ETHER............................. 0.001900 0.004 0.005
TRIETHYLENE TETRAMINE........................................... 0.000000 0.000 0.000
TRIPROPYLENE GLYCOL............................................. 0.005300 0.004 0.005
WARFARIN........................................................ 0.000000 0.000 0.000
----------------------------------------------------------------------------------------------------------------
* Molecular structure only approximate.
(M) fraction measured (fm) estimated from Mwt correlation.
Table 2 of Appendix J.--FR, FM, and FE <SUP>1 Values for Compounds With Henry's Law Constants at 25 deg. C Greater
Than or Equal to 0.1 Y/X Atmosphere per Mole Fraction
----------------------------------------------------------------------------------------------------------------
Compound FR Fm25D Fm305 Fe <SUP>1 CAS
----------------------------------------------------------------------------------------------------------------
1 BROMO 2 CHLORO 2 BUTENE.......... 0.990 0.786 1.000 0.761
1 BUTYENE.......................... 0.990 1.172 1.000 0.872
1 ETHYL 4 METHYLBENZENE............ 0.990 1.219 1.000 0.748
1 HEPTANOL......................... 0.946 0.525 0.564 0.186
1 HEPTYNE.......................... 0.990 1.138 1.000 0.980
1 HEXYNE........................... 0.990 1.145 1.000 0.924
1 ISOCYANO 3-METHYLBENZENE......... 0.990 0.870 0.913 0.210
1 ISOPROPYL 4 METHYLBENZENE........ 0.990 1.193 1.000 0.804
1 METHYLCYCLOHEXENE................ 0.990 1.138 1.000 0.980
1 METHYLNAPHTHALENE................ 0.990 1.237 1.000 0.384
1 NONYNE........................... 0.990 1.128 1.000 0.980
1 OCTENE........................... 0.990 1.112 1.000 0.980
1 OCTYNE........................... 0.990 1.132 1.000 0.980
1 PENTYNE.......................... 0.990 1.156 1.000 0.885
1,1 DIETHOXYETHANE................. 0.985 0.810 0.996 0.320
1,1,3 TRIMETHYLCYCLOPENTANE........ 0.990 1.124 1.000 0.980
1,1-DIFLUOROETHANE................. 0.990 1.077 1.000 0.876
1,2 DIETHOXYETHANE................. 0.932 0.762 0.999 0.309
1,2,4,5 TETRAMETHYLBENZENE......... 0.990 1.194 1.000 0.887
1,3-DIOXOLANE...................... 0.642 0.764 1.000 0.232 646-06-0
1,4 PENTADIENE..................... 0.990 1.176 1.000 0.980
1,5 HEXADIENE...................... 0.990 1.155 1.000 0.980
1-NITROPROPANE..................... 0.966 0.522 0.982 0.374
1-PENTANOL......................... 0.990 0.708 0.807 0.579
1-PENTENE.......................... 0.990 1.124 1.000 0.980
1-PROPOXY 2-PROPANOL............... 0.430 0.134 0.167 0.070
2 BUTEN 1 OL....................... 0.207 0.703 0.801 0.095
2 HEPTANONE........................ 0.990 0.955 0.991 0.356
2 METHYL 1 BUTANOL................. 0.797 0.721 0.807 0.201
2 METHYL 2 BUTENE.................. 0.990 1.143 1.000 0.980
2 METHYL 2 PENTANOL................ 0.959 0.806 0.869 0.257
2 METHYL 3 PENTANOL................ 0.989 0.539 0.565 0.241
2 METHYLHEXANE C7H16............... 0.990 1.099 1.000 0.980
2 METHYLNAPHTHALENE................ 0.990 1.237 1.000 0.449
2 NONANONE......................... 0.990 0.959 0.970 0.441
2 OCTANONE......................... 0.990 0.961 0.983 0.350
2 PENTANONE........................ 0.942 0.919 0.998 0.350
2 PENTENE.......................... 0.990 1.131 1.000 0.980
2 PROPYLBENZENE.................... 0.990 1.198 1.000 0.582
2 UNDECANONE....................... 0.990 0.927 0.922 0.495
2-(1-METHOXY)-1-PROPANOL........... 0.648 0.202 0.251 0.093
2,2 DIMETHYL PROPANOIC ACID........ 0.131 0.296 0.376 0.074
[[Page 68074]]
2,2 DIMETHYLBUTANE C6H14........... 0.990 1.108 1.000 0.901
2,2 DIMETHYLPENTANE................ 0.990 1.106 1.000 0.980
2,2,5 TRIMETHYLHEXANE C9H20........ 0.990 1.114 1.000 0.980
2,3 DIMETHYL 1,3 BUTADIENE......... 0.990 1.168 1.000 0.942
2,3 DIMETHYLBUTANE C6H14........... 0.990 1.115 1.000 0.980
2,3 DIMETHYLBUTANOL................ 0.978 0.648 0.694 0.259
2,3 DIMETHYLPENTANE C7H16.......... 0.990 1.112 1.000 0.980
2,3,4 TRIMETHYLPENTANE C8H18....... 0.990 1.121 1.000 0.980
2,3-DIMETHYLPYRIDINE............... 0.048 1.048 1.000 0.110
2,4 DIMETHYLPENTANE C7H16.......... 0.990 1.112 1.000 0.980
2,4,5 T............................ ........... 0.024 0.028 0.000 93-76-5
2,4-DIMETHYLPYRIDINE............... 0.044 1.048 1.000 0.105
2,5-DIMETHYLPYRIDINE............... 0.055 1.048 1.000 0.122
2,6,DIMETHYL2,5-HEPTADIEN4-ONE..... 0.990 0.906 0.882 0.354
2,6-DIMETHYL2,5-HEPTADIEN 4-ONE.... 0.990 0.682 0.649 0.278
2,6-DIMETHYLPYRIDINE............... 0.067 1.048 1.000 0.137
2-CHLORO 2-METHYLBUTANE............ 0.990 1.078 1.000 0.726
2-ETHYL 3-METHOXYPYRAZINE.......... 0.990 0.039 0.050 0.151
2-ETHYLPYRAZINE.................... 0.746 0.452 0.527 0.070
2-ETHYLPYRIDINE.................... 0.080 1.041 1.000 0.141
2-FLUOROPROPANE.................... 0.990 1.099 1.000 0.980
2-ISOBUTYL 3-METHOXYPYRAZINE....... 0.990 0.044 0.057 0.256
2-ISOBUTYLPYRAZINE................. 0.969 0.362 0.395 0.096
2-METHYL PENTANE C6H14............. 0.990 1.100 1.000 0.899
2-METHYLPYRAZINE................... 0.626 0.505 0.613 0.068
2-PENTANOL......................... 0.810 0.721 0.807 0.205
3 METHYL 1 BUTENE.................. 0.990 1.143 1.000 0.980
3 METHYL PYRIDINE.................. 0.630 0.685 0.663 0.131
3 METHYLHEPTANE C8H18.............. 0.990 1.098 1.000 0.980
3 METHYLHEXANE C7H16............... 0.990 1.099 1.000 0.980
3,3 DIMETHYLPENTANE C7H16.......... 0.990 1.106 1.000 0.980
3,4-DIMETHYLPRYIDINE............... 0.025 1.048 1.000 0.083
3,5-DIMETHYLPYRIDINE............... 0.044 1.048 1.000 0.105
3-ETHYLPRYIDINE.................... 0.080 1.041 1.000 0.141
3-HEXANOL.......................... 0.990 0.638 0.694 0.294
3-PENTEN-2-OL...................... 0.860 0.610 0.656 0.230
4 METHYL 1 PENTENE................. 0.990 1.134 1.000 0.980
4 METHYL 2 PENTANOL................ 0.990 0.539 0.565 0.264
4 METHYL 2 PENTANONE............... 0.385 0.923 0.968 0.145
4 METHYLOCTANE C9H20............... 0.990 1.098 1.000 0.980
4-ETHYLPYRIDINE.................... 0.064 1.041 1.000 0.123
4-METHYLPYRIDINE................... 0.990 1.033 1.000 0.109
5 METHOXY 2 PENTANONE.............. 0.798 0.327 0.382 0.142
ACENAPHTHENE....................... 0.990 1.111 0.899 0.804 83-32-9
ACENAPHTHYLENE..................... 0.990 1.094 0.868 0.312 208-96-8
ACETAL............................. 0.990 0.813 1.000 0.432
ACETALDEHYDE....................... 0.953 0.724 1.000 0.485 75-07-0
ACETATE (M)........................ 0.990 0.558 0.558 0.794
ACETIC ACID........................ 0.066 0.101 0.189 0.120 64-19-7
ACETIC ANHYDRIDE................... 0.524 0.165 0.262 0.214 108-24-7
ACETONE............................ 0.843 0.827 0.997 0.261 67-64-1
ACETONITRILE....................... 0.641 0.778 0.989 0.359 75-05-8
ACETOPHENONE....................... 0.735 0.334 0.314 0.137 96-86-2
ACETYL CHLORIDE.................... 0.990 0.923 1.000 0.531 79-36-5
ACETYL DIETHYLMALONATE............. 0.978 0.018 0.025 0.156
ACETYLENE.......................... 0.990 1.280 1.000 0.711 74-86-2
ACETYLFURAN 2 *.................... 0.990 0.365 0.423 0.382 1192-62-7
ACETYLMETHYLPHTHALATE 4............ 0.990 0.036 0.048 0.127
ACETYLPYRIDINE 3................... 0.990 0.927 1.000 0.980 1122-54-9
ACIFLUORFEN........................ 0.990 0.198 0.223 0.601
ACROLEIN........................... 0.968 0.855 1.000 0.427 107-02-8
ACRYLONITRILE...................... 0.969 0.876 0.999 0.429 107-13-1
ADAMANTANE DICHLORIDE.............. 0.990 1.097 0.986 0.562
AFLATOXINS (M)..................... 0.990 0.063 0.063 0.406 1402-68-2
ALDICARB........................... 0.027 0.002 0.002 0.007 116-06-3
ALDRIN............................. 0.990 0.056 0.051 0.469 509-00-2
ALKYLIMINE CARBOXYLIC ACID N,SUB(M) 0.848 0.125 0.125 0.111
ALLYL ALCOHOL...................... 0.783 0.538 0.659 0.276 107-18-6
ALLYL CHLORIDE..................... 0.990 1.092 1.000 0.887 107-05-1
ALLYL ETHER, diallyl ether......... 0.990 0.974 1.000 0.663
ALPHA METHYL STYRENE............... 0.990 1.217 1.000 0.767 98-83-9
[[Page 68075]]
ALPHA METHYL STYRENE DIMERS........ 0.990 1.186 0.975 0.855
alpha-CHLORO-beta-METHYLNAPHTHALENE 0.990 1.197 1.000 0.828 86-52-2
ALPHA-HYDROXYACETALDEHYDE.......... 0.990 0.031 0.059 0.515
ALPHA-HYDROXYADIPIMIDE (M)......... 0.925 0.144 0.144 0.135
AMINO-2-CHLOROTOLUENE 4............ 0.990 0.020 0.020 0.790
AMINO-3-CHLORO-5-PHENYLCYCLOHEXA(M) 0.622 0.143 0.143 0.086
AMINO-4-CHLORO-6-CYANOPYRIDINE 2(M) 0.990 0.148 0.148 0.411
AMINO-4'-CHLOROBIPHENYL 4(M)....... 0.990 0.123 0.123 0.980
AMINO-4-CHLOROPYRIDINE 2 (M)....... 0.990 0.514 0.514 0.710 1072-98-6
AMINO-4-NITROBENZYL ALCOHOL 2 (M).. 0.742 0.149 0.149 0.102
AMINO-4-NITROTOLUENE 2............. 0.990 0.000 0.001 0.802 99-55-8
AMINO-5-CHLOROPYRIDINE 2 (M)....... 0.990 0.514 0.514 0.384 1072-98-6
AMINOBENZOIC ACID (-p) (M)......... 0.624 0.368 0.368 0.086 150-13-0
AMINOCYCLOHEXANE................... 0.934 0.929 0.996 0.416 108-91-8
AMINOMETHYL-3-ISOXAZOLOL 5 (M)..... 0.990 0.760 0.760 0.287 2763-96-4
AMINOPHENOL(-o).................... 0.641 0.034 0.039 0.083 95-55-6
AMINOPHENOL(-p).................... 0.265 0.001 0.001 0.180 101-80-4
AMINO-p'-METHYLAZOBENZENE P (M).... 0.990 0.119 0.119 0.852
AMINOPROPIONITRILE 3 (M)........... 0.834 0.999 0.999 0.163 151-18-8
AMITROLE (M)....................... 0.618 0.999 0.999 0.085 61-82-5
AMMONIA............................ 0.990 0.520 1.000 0.732 7664-41-7
AMPHETAMINE(M)..................... 0.990 0.401 0.401 0.323 60-15-1
AMYL ACETATE(-n)................... 0.990 0.426 0.504 0.462 628-63-7
ANETHOLE (M)....................... 0.990 0.180 0.180 0.406 104-46-1
ANISOLE............................ 0.990 1.036 1.000 0.731 100-66-3
ANTHRACENE......................... 0.990 0.109 0.087 0.513 120-12-7
ARAMITE (M)........................ 0.990 0.058 0.058 0.406 140-57-8
AURAMINE (M)....................... 0.990 0.091 0.091 0.980 492-80-8
AZASERINE (M)...................... 0.986 0.138 0.138 0.206 115-02-6
AZEPINE (M)........................ 0.990 0.058 0.058 0.817 111-49-9
AZIRIDINE ethyleneimine............ 0.990 0.628 0.867 0.685 151-56-4
BENXENEDICARBOXYLIC ACID DIHEPTYL.. 0.990 0.113 0.119 0.667
BENZ(c)ACRIDINE (M)................ 0.990 0.110 0.110 0.853 225-51-4
BENZAL CHLORIDE.................... 0.990 1.159 0.996 0.798 98-87-3
BENZALDEHYDE....................... 0.980 0.516 0.490 0.283 100-52-7
BENZALKONIUM CHLORIDE (M).......... 0.408 0.129 0.129 0.065
BENZEN SULFONATE (M)............... 0.990 0.642 0.642 0.894
BENZENE............................ 0.990 1.227 1.000 0.797 71-43-2
BENZETHONIUM CHLORIDE (M).......... 0.956 0.001 0.001 0.140 121-54-0
BENZIDINE DIHYDROCHLORIDE(M)....... 0.990 0.096 0.096 0.980 531-85-1
BENZO(B)FLUORANTHENE............... 0.990 1.219 0.962 0.135 205-99-2
BENZO(j)FLUORANTHENE (M)........... 0.990 0.099 0.099 0.853 205-82-3
BENZODIOXANE-1,3 (M)............... 0.668 0.108 0.108 0.093
BENZOFLUORANTHENE,3,4-(M).......... 0.990 0.099 0.099 0.853 205-99-2
BENZOFURAN 2,3..................... 0.990 1.061 0.988 0.374
BENZOIC ACID, 4 METHYL............. 0.642 0.102 0.108 0.103
BENZONITRILE....................... 0.990 0.397 0.373 0.170 100-47-0
BENZOPHENONE....................... 0.990 0.052 0.046 0.834 119-61-9
BENZOPYRENE 3,4 (M)................ 0.990 0.099 0.099 0.318 50-32-8
BENZOQUINONE,p-(M)................. 0.990 0.862 0.862 0.794 106-51-4
BENZOTHIAZOLE *.................... 0.990 0.059 0.060 0.341 95-16-9
BENZOTRICHLORIDE................... 0.990 1.069 0.958 0.558 98-07-7
BENZOYL CHLORIDE................... 0.990 1.132 0.979 0.468 98-88-4
BENZYL CHLORIDE.................... 0.990 1.164 1.000 0.415 100-44-7
BENZYL METHYL ETHER................ 0.990 1.047 1.000 0.587 538-86-3
BHC,alpha-......................... 0.990 1.063 1.000 0.729 319-84-6
BHC,beta-.......................... 0.990 1.063 1.000 0.854 319-85-7
BHC,delta-......................... 0.990 1.063 1.000 0.588 319-86-8
BICYCLO(4,2,0) OCTA 1.3.5 TRIENE... 0.990 1.222 1.000 0.759
BICYCLO[2.2.1]-2,5-HEPTADIENE DI(M) 0.990 0.146 0.146 0.980
BIPHENYL........................... 0.990 1.074 0.864 0.445 92-52-4
BIS (2-CHLOROETHOXY) METHANE....... 0.282 0.170 0.196 0.067 111-91-1
BIS(1,1,2,2-TETRACHLOROPROPYL) ETHE 0.990 0.960 1.000 0.980
BIS(2-CHLOROETHYL)ETHER............ 0.656 0.806 0.858 0.162 111-44-4
BIS(2-CHLOROISOPROPYL)ETHER........ 0.990 0.948 0.972 0.310 108-60-1
BIS(CHLOROMETHYL)ETHER............. 0.975 0.888 0.999 0.459 542-88-1
BISPHENOL(A)....................... 0.990 0.011 0.011 0.665 80-05-7
BROMACIL........................... 0.990 0.582 1.000 0.980
BROMO-(1)-CHLOROETHANE-2........... 0.990 0.711 1.000 0.995 107-04-0
BROMO-3-CHLOROBUTADIENE 2.......... 0.990 0.803 1.000 0.820
BROMO-4-CHLORO-6-CYANOBENZYL ALC(M) 0.941 0.131 0.131 0.136
[[Page 68076]]
BROMO-4-CHLOROCYCLOHEXANE 1........ 0.990 0.819 0.986 0.980
BROMO-4-CYANOMETHYL BENZOATE 2 (M). 0.990 0.105 0.105 0.980
BROMO-4-CYANOMETHYL BENZOATE 3 (M). 0.990 0.105 0.105 0.885
BROMOACETONE....................... 0.520 0.356 0.590 0.145 598-31-2
BROMOBENZENE....................... 0.990 1.182 1.000 0.745 108-86-1
BROMOBENZYL ALCOHOL-(m)............ 0.371 0.012 0.015 0.083 15852-73-
BROMOBENZYL ALCOHOL-(o)............ 0.371 0.012 0.015 0.083 18982-34-
BROMOBENZYL ALCOHOL-(p)............ 0.371 0.012 0.015 0.083 873-75-6
BROMOCHLOROBENZENE P............... 0.990 0.870 1.000 0.980 106-39-8
BROMOCHLOROBENZYL ALCOHOL.......... 0.420 0.007 0.009 0.107
BROMOCHLOROMETHANE................. 0.990 1.017 1.000 0.992 74-97-5
BROMODICHLOROMETHANE............... 0.990 0.735 1.000 0.980 75-27-4
BROMOETHYL ACETATE................. 0.911 0.470 0.801 0.458 927-68-4
BROMOETHYLENE...................... 0.990 0.629 1.000 0.990 543-60-2
BROMOFORM.......................... 0.990 0.480 0.998 0.494 75-25-2
BROMOMETHANE....................... 0.990 0.539 1.000 0.852 74-83-9
BROMOPHENYL PHENYL ETHER,4-........ 0.990 0.240 0.265 0.269 101-55-3
BROMOPROPIONITRILE 3 (M)........... 0.990 0.422 0.422 0.856 2417-90-5
BROMOTOLUENE 4..................... 0.990 1.164 1.000 0.676 106-38-7
BROMOURACIL,5-(M).................. 0.990 0.130 0.130 0.980 51-20-7
BUTADIENE-(1,3).................... 0.990 1.187 1.000 0.979 106-99-0
BUTANE............................. 0.990 1.080 1.000 0.980 106-97-8
BUTANEDINITRILE.................... 0.990 0.007 0.009 0.182 110-61-2
BUTANENITRILE (M).................. 0.521 0.999 0.999 0.266 109-74-0
BUTANOL ISO........................ 0.821 0.647 0.756 0.068 78-83-1
BUTANOL(S)......................... 0.846 0.502 0.600 0.253 78-92-2
BUTANOL-1.......................... 0.818 0.502 0.600 0.177 71-36-3
BUTENE............................. 0.990 1.131 1.000 0.980
BUTYL ACETATE(-n).................. 0.990 0.808 0.995 0.368 123-86-4
BUTYL ACRYLATE..................... 0.990 0.781 0.910 0.492 141-32-2
BUTYL BENZENE...................... 0.990 1.181 1.000 0.980 104-51-8
BUTYL BENZYL PHTHALATE............. 0.990 0.052 0.053 0.852 85-68-7
BUTYL CARBITOL..................... 0.990 0.006 0.008 0.980 112-34-5
BUTYL MERCAPTAN.................... 0.990 0.692 1.000 0.980
BUTYL-3-METHOXY PYRAZINE, 2-ISO (M) 0.990 0.142 0.142 0.980 24683-00-
BUTYLAMINE......................... 0.904 0.813 0.948 0.241 109-73-9
BUTYLBUTOXY PROPIONATE............. 0.990 0.263 0.276 0.266
BUTYLENE GLYCOL-(1,3).............. 0.780 0.003 0.004 0.096 107-88-0
BUTYLISOBUTYRATE................... 0.990 0.873 1.000 0.794
BUTYRALDEHYDE...................... 0.989 0.861 0.992 0.490 123-72-8
BUTYRALDEHYDE ISO.................. 0.989 0.886 1.000 0.438 78-84-2
c10 linear......................... 0.990 1.088 1.000 0.980
c11 linear......................... 0.990 1.088 1.000 0.980
CACODYLIC ACID (M)................. 0.983 0.354 0.354 0.219 75-60-5
CAMPHENE (M)....................... 0.990 0.383 0.383 0.588 79-92-5
CAPTAN............................. 0.990 0.007 0.008 0.196
CARBARYL sevin..................... 0.990 0.015 0.016 0.202 63-25-2
CARBAZOLE (M)...................... 0.990 0.141 0.141 0.980 86-74-8
CARBENDAZIM........................ 0.957 0.023 0.038 0.070
CARBON DIOXIDE (M)................. 0.990 0.999 0.999 0.896
CARBON DISULFIDE................... 0.990 0.213 1.000 0.918 75-15-0
CARBON OXYFLUORIDE*................ 0.990 0.884 1.000 0.993 353-50-4
CARBON TETRACHLORIDE............... 0.990 1.027 1.000 0.900 56-23-5
CARBONYL FLUORIDE *................ 0.658 0.884 1.000 0.358
CARBONYL SULFIDE................... 0.886 0.547 1.000 0.500
CHLORAL............................ 0.990 0.938 1.000 0.556 302-17-0
CHLORAMBEN......................... 0.962 0.545 0.633 0.229
CHLORAMBUCIL....................... 0.957 0.031 0.031 0.101 305-03-3
CHLORDANE.......................... 0.990 0.438 0.407 0.151 57-74-9
CHLORENDIC ANHYDRIDE (M)........... 0.990 0.558 0.558 0.794 115-27-5
CHLORINATED TARS (M)............... 0.990 0.050 0.050 0.343
CHLORNAPHAZINE..................... 0.990 0.422 0.385 0.158
CHLORO 2 BUTENE,1 trans............ 0.990 1.098 1.000 0.632
CHLORO(-p)PHENYLHYDRAZINE(M)....... 0.990 0.286 0.286 0.398
CHLORO-1,3-CYCLOPENTADIENE 5....... 0.990 1.148 1.000 0.948
CHLORO-2,2-DIBROMOETHANE 1......... 0.990 0.569 0.919 0.526
CHLORO-2,3-EPOXYPROPANE,1-(M)...... 0.977 0.999 0.999 0.321 106-89-8
CHLORO-2-METHOXYBENZOIC ACID 4 (M). 0.990 0.132 0.132 0.722 57479-70-
CHLORO-2-NITROBENZYL ALCOHOL 4 (M). 0.601 0.132 0.132 0.083 22996-18-
CHLORO-3-NITRO-5-PHENYLCYCLOHEXA 0.631 0.131 0.131 0.087
(M).
CHLORO-3-NITROANILINE 4 (M)........ 0.990 0.139 0.139 0.342 635-22-3
[[Page 68077]]
CHLORO-4AMINOCOUMARAN-6 0.990 0.118 0.118 0.980
CARBOXYLI(M).
CHLORO-4-CYANOBENZYL ALCOHOL 2 (M). 0.743 0.149 0.149 0.102
CHLORO-4-HYDROXYBIPHENYL 3 (M)..... 0.990 0.123 0.123 0.980 92-04-6
CHLORO-4-METHOXY-6-AMINOBENZOIC(M). 0.990 0.125 0.125 0.449
CHLORO-4-METHYL-N-METHYLBENZAMID(M) 0.832 0.134 0.134 0.109
CHLORO-4-NITROANISOLE 2 (M)........ 0.990 0.131 0.131 0.980
CHLORO-4-PHENYLPYRIDINE 2(M)....... 0.839 0.130 0.130 0.110
CHLORO-5AMINO3PYRIDINE CARB.ACID 0.990 0.134 0.134 0.439
(M).
CHLORO-5-CYANOPHTHALIC ACID 4 (M).. 0.990 0.112 0.112 0.980
CHLORO-5-CYANOTOLUENE 3 (M)........ 0.990 0.150 0.150 0.601
CHLORO-5-FLUOROTOLUENE 3........... 0.990 1.150 1.000 0.400 443-83-4
CHLORO-5-PHENOXYDIMETHYL PHTHALA(M) 0.990 0.065 0.065 0.980
CHLOROACETALDEHYDE................. 0.762 0.855 0.997 0.324 107-20-0
CHLOROALLYL ALCOHOL 2.............. 0.926 0.270 0.291 0.244 5976-47-6
CHLOROANILINE(2)................... 0.990 0.245 0.238 0.867 95-51-2
CHLOROANILINE(3)................... 0.990 0.108 0.105 0.867 108-42-9
CHLOROAZOBENZENE................... 0.990 1.204 1.000 0.852
CHLOROBENZENE...................... 0.990 1.157 1.000 0.728 108-90-7
CHLOROBENZENESULFONIC ACID (-p)(M). 0.826 0.137 0.137 0.108 100-03-8
CHLOROBENZILATE.................... 0.876 0.000 0.000 0.030 510-15-6
CHLOROBENZOIC ACID,2............... 0.629 0.083 0.089 0.105 118-91-2
CHLOROBENZOIC ACID,3-.............. 0.535 0.083 0.089 0.092 535-80-8
CHLOROBENZOIC ACID,4-.............. 0.535 0.083 0.089 0.092 74-11-3
CHLOROBENZOTRICHLORIDE P........... 0.990 1.103 1.000 0.980 5216-25-1
CHLOROBENZOTRIFLUORIDE, P.......... 0.990 1.131 1.000 0.980
CHLOROBENZYL ALCOHOL-(m)........... 0.852 0.035 0.033 0.074 873-63-2
CHLOROBENZYL ALCOHOL-(o)........... 0.275 0.058 0.056 0.074 17849-38-
CHLOROBENZYL ALCOHOL-(p)........... 0.251 0.040 0.039 0.074 873-76-7
CHLOROBIPHENYL (-p)................ 0.990 1.204 1.000 0.840 2051-62-9
CHLOROBUTADIENE,1.................. 0.990 1.124 1.000 0.850
CHLOROCOUMARAN 2 (M)............... 0.990 0.135 0.135 0.832 2051-59-4
CHLOROCYANOBENZENE (1,4) (M)....... 0.990 0.362 0.362 0.980 873-32-5
CHLOROCYCLOHEXANE.................. 0.990 1.081 1.000 0.980 542-18-7
CHLOROCYCLOHEXANOL 2............... 0.990 0.102 0.107 0.428 1561-86-0
CHLOROCYCLOHEXANOL 4............... 0.990 0.102 0.107 0.587
CHLORODIACETYL (M)................. 0.990 0.651 0.651 0.980
CHLORODIMETHYL PHTHALATE 3 (M)..... 0.990 0.111 0.111 0.980
CHLORODIPHENYL THIOETHER P (M)..... 0.990 0.123 0.123 0.851 7005-72-3
CHLOROETHANE (ethyl chloride)...... 0.990 1.046 1.000 0.901 75-00-3
CHLOROETHANOL (ETHYLENE CHLOROHYDRI 0.480 0.256 0.309 0.221 107-07-3
CHLOROETHYL(2-) VINYL ETHER........ 0.990 0.934 1.000 0.910 110-75-8
CHLOROETHYLENE..................... 0.990 1.064 1.000 0.757
CHLOROFLUOROBENZENE P.............. 0.990 1.152 1.000 0.980 352-33-0
CHLOROFLUOROMETHANE *.............. 0.355 1.075 1.000 0.980 593-70-4
CHLOROFORM......................... 0.990 1.023 1.000 0.775 67-66-3
CHLOROHYDROXYPHENYL4 METHYLBENZ(M). 0.990 0.094 0.094 0.980
CHLOROMETHYL ACETYLENE *........... 0.990 1.121 1.000 0.980
CHLOROMETHYL BENZOATE P (M)........ 0.990 0.140 0.140 0.980 1126-46-1
CHLOROMETHYL ETHYL KETONE.......... 0.990 0.873 0.935 0.697
CHLOROMETHYL METHYL ETHER.......... 0.937 0.840 1.000 0.494 107-30-2
CHLOROMETHYL PHENYL KETONE......... 0.290 0.715 0.673 0.077 532-27-4
CHLOROMETHYL PHENYLHYDRAZINE P (M). 0.990 0.147 0.147 0.413
CHLOROMETHYLAMINOIMINE (M)......... 0.990 0.999 0.999 0.913
CHLORONAPHTHALENE,2-............... 0.990 1.177 0.980 0.870 91-58-7
CHLORONITROALKOXYIMINE (M)......... 0.958 0.110 0.110 0.142
CHLORONITROBENZENE(-o)............. 0.990 0.519 0.625 0.808 88-73-3
CHLORONITROBENZENE, p.............. 0.990 0.591 0.713 0.301
CHLORO-N-METHYLBENZAMIDE P (M)..... 0.818 0.140 0.140 0.107
CHLOROPHENOL-2..................... 0.323 0.245 0.240 0.107 95-97-8
CHLOROPHENOL-3..................... 0.635 0.057 0.057 0.078 108-43-0
CHLOROPHENYL PHENYL ETHER,4-*...... 0.990 0.861 0.775 0.389 7005-72-3
CHLOROPHENYLETHANOL 1,1............ 0.990 0.057 0.054 0.807
CHLOROPHTHALIC ANHYDRIDE 4 (M)..... 0.595 0.133 0.133 0.083
CHLORO-p'-METHYLBIPHENYL P (M)..... 0.990 0.124 0.124 0.850 1667-11-4
CHLOROPRENE........................ 0.990 1.124 1.000 0.677 126-99-8
CHLOROPROPANE-1.................... 0.990 1.055 1.000 0.858 540-54-5
CHLOROPROPANE-2.................... 0.990 1.050 1.000 0.867 75-29-6
CHLOROPROPENE 3.................... 0.990 1.092 1.000 0.980 557-98-2
CHLOROPROPIONITRILE,3-............. 0.359 0.580 0.622 0.111 542-76-7
CHLOROPROPYLENE-2.................. 0.990 1.090 1.000 0.980 557-98-2
CHLORO-p-XYLENE.................... 0.987 1.163 1.000 0.592 104-82-5
[[Page 68078]]
CHLOROPYRIDINE 2 (M)............... 0.990 0.769 0.769 0.599 109-09-1
CHLOROSTYRENE (-4)................. 0.990 1.179 1.000 0.788 1331-28-8
CHLOROTETRAHYDROFURAN 3 (M)........ 0.990 0.642 0.642 0.407
CHLOROTHIOPHENOL P *............... 0.990 0.893 1.000 0.980 106-54-7
CHLOROTOLUENE-4.................... 0.990 1.164 1.000 0.741 106-43-4
CHLOROURACIL,5-(M)................. 0.990 0.138 0.138 0.980 1820-81-1
cis 1,2 DIMETHYLCYCLOHEXANE........ 0.990 1.117 1.000 0.980
CITRUS RED #2 (M).................. 0.990 0.071 0.071 0.853 6358-53-8
COPPER PHTHALOCYANINE (M).......... 0.990 0.000 0.000 0.764 147-14-8
COUMARAN (M)....................... 0.990 0.215 0.215 0.980 91-64-5
CROTONALDEHYDE..................... 0.578 0.887 0.974 0.212 470-30-3
CROTONYLENE (2-BUTYNE)............. 0.990 1.185 1.000 0.980 503-17-3
CUMENE (isopropylbenzene).......... 0.990 1.197 1.000 0.876 98-82-8
CUMENE HYDROPEROXIDE............... 0.987 0.478 0.464 0.204
CYANOBENZYL ALCOHOL P *............ 0.147 0.002 0.002 0.070
CYANOGEN........................... 0.990 0.800 1.000 0.747 460-19-5
CYANOGEN BROMIDE *................. 0.990 0.558 1.000 0.462 506-68-3
CYANOGEN CHLORIDE(M)............... 0.990 0.999 0.999 0.704 506-77-4
CYANOGUANIDINE (M)................. 0.990 0.999 0.999 0.648 461-58-5
CYANOMETHYLPHTHALATE 4 (M)......... 0.990 0.071 0.071 0.980
CYANOPYRIDINE (-4) *............... 0.990 0.118 0.124 0.980 100-48-1
CYANOPYRIDINE 3 *.................. 0.990 0.113 0.119 0.980 100-54-9
CYANOTOLUENE 4..................... 0.990 0.450 0.419 0.980
CYANURIC ACID (M).................. 0.491 0.505 0.505 0.072 108-80-5
CYCASIN (M)........................ 0.990 0.099 0.099 0.794 14901-08-
CYCLOHEXADIENE1,4DIONE2,6BIS11DIMET 0.753 0.027 0.026 0.072
CYCLOHEXANE........................ 0.990 1.093 1.000 0.859 110-82-7
CYCLOHEXANOL....................... 0.851 0.456 0.493 0.159
CYCLOHEXANOL....................... 0.925 0.243 0.262 0.136 108-93-0
CYCLOHEXANONE...................... 0.198 0.703 0.740 0.088 108-94-1
CYCLOHEXENE........................ 0.990 1.136 1.000 0.980 110-83-8
CYCLOHEXENE 1 ONE, 2............... 0.759 0.498 0.507 0.183
CYCLOHEXYL ACETATE................. 0.990 0.846 0.963 0.273 622-45-7
CYCLOHEXYL-2,2-DIPHENYLETHYLAMIN(M) 0.990 0.097 0.097 0.384
CYCLOHEXYL-4,6-DINITROPHENOL,2-(M). 0.990 0.092 0.092 0.980 131-89-5
CYCLOHEXYLAMINE.................... 0.978 0.878 0.940 0.280 108-91-8
CYCLOHEXYLCYCLOHEXANONE 4.......... 0.990 0.732 0.707 0.727 56025-96-
CYCLOPENTADIENE.................... 0.990 1.198 1.000 0.980
CYCLOPENTADIENE 1,3................ 0.990 1.198 1.000 0.713
CYCLOPENTANE....................... 0.990 1.093 1.000 0.980
CYCLOPENTENE....................... 0.990 1.144 1.000 0.979
CYCLOPHOSPHAMIDE (M)............... 0.990 0.094 0.094 0.610 50-18-0
CYCLOPROPANE C3H6.................. 0.990 1.093 1.000 0.980
CYCLOHEXYL o,o-DIMETHYL PHOS.DIT(M) 0.99 0.105 0.980 0.980
CYMENE,para........................ 0.990 1.193 1.000 0.871
CYTOSINE (M)....................... 0.990 0.811 0.811 0.831 71-30-7
DAUNOMYCIN(M)...................... 0.990 0.000 0.000 0.853 20830-81-
DAZOMET............................ 0.900 0.085 0.153 0.066
DDD,p,p'-.......................... 0.950 1.150 1.000 0.394 72-54-8
DDE,p,p'-.......................... 0.990 1.138 0.990 0.621 72-55-9
DDT................................ 0.990 1.131 1.000 0.980 50-29-3
DECANAL............................ 0.990 0.918 0.928 0.612
DECENE, 8 METHYL 1-................ 0.990 1.116 1.000 0.980
DIACETYL (M)....................... 0.990 0.999 0.999 0.318 431-03-8
DIAMINO-5-SULFONYL BENZYL 2,4 (M).. 0.990 0.133 0.133 0.628
DIAMINODIPHENYLMETHANE P,P' (M).... 0.990 0.126 0.126 0.980 101-77-9
DIAZOMETHANE....................... 0.575 0.573 1.000 0.356
DIBENZOFURANS...................... 0.990 1.112 0.967 0.740
DIBENZOPYRENE 1,2,7,8.............. 0.990 0.803 0.633 0.720
DIBROMO-3-CHLOROPROPANE,1,2........ 0.709 1.048 1.000 0.185 96-12-8
DIBROMOCHLOROMETHANE............... 0.990 0.585 1.000 0.643 124-48-1
DIBROMOETHANE-1,2.................. 0.990 1.114 1.000 0.852 106-93-4
DIBROMOMETHANE..................... 0.990 0.493 1.000 0.558 74-95-3
DIBUTYL ETHER...................... 0.990 0.958 1.000 0.727 142-96-1
DIBUTYLAMINE....................... 0.990 0.949 0.984 0.300
DICHLORO 2-PROPANOL 1,3............ 0.990 0.237 0.257 0.570 96-23-1
DICHLORO PROPANOL 2,3.............. 0.507 0.119 0.130 0.255 616-23-9
DICHLORO-1,3-CYCLOPENTADIENE 5,5(M) 0.990 0.413 0.413 0.980
DICHLORO-2-BUTENE 1,2.............. 0.990 1.079 1.000 0.562
DICHLORO-2-BUTENE(1,4)............. 0.990 1.079 1.000 0.453 764-41-0
DICHLORO-2-BUTENE, 1,4............. 0.990 1.079 1.000 0.612
[[Page 68079]]
DICHLOROANILINE(2,3)............... 0.527 0.121 0.117 0.064
DICHLOROBENZENE(1,2) (-o).......... 0.990 1.134 1.000 0.637 95-50-1
DICHLOROBENZENE(1,3) (-m).......... 0.990 1.134 1.000 0.719 541-73-1
DICHLOROBENZENE(1,4) (-p).......... 0.990 1.134 1.000 0.724 106-46-7
DICHLOROBENZIDINE,3,3'-............ 0.001 0.055 0.053 0.026 91-94-1
DICHLOROBENZOPHENONE P,P........... 0.978 0.366 0.332 0.093 90-98-2
DICHLOROBIPHENYL (PARA)............ 0.990 1.177 1.000 0.914 213029-08
DICHLOROBUTANE (1,4)............... 0.990 1.052 1.000 0.980 110-56-5
DICHLORODIPHENYLMETHANE (M)........ 0.990 0.107 0.107 0.855 2051-90-3
DICHLOROETHANE(1,1)................ 0.990 1.024 1.000 0.792 75-34-3
DICHLOROETHANE(1,2)................ 0.990 1.040 1.000 0.640 107-06-2
DICHLOROETHENE 1,2 trans........... 0.990 1.061 1.000 0.981 156-60-5
DICHLOROETHENE(1,1)................ 0.990 1.061 1.000 0.937 75-35-4
DICHLOROETHYL ETHER................ 0.872 0.711 0.757 0.212
DICHLOROETHYLENE(1,2) cis.......... 0.990 1.061 1.000 0.904 156-54-2
DICHLOROIODOMETHANE................ 0.990 0.553 0.975 0.362
DICHLOROMONOFLUOROMETHANE.......... 0.990 1.023 1.000 0.989 75-43-4
DICHLOROPHENOL..................... 0.990 0.940 0.920 0.227
DICHLOROPHENOL(2,4)................ 0.945 0.158 0.154 0.094 120-83-2
DICHLOROPHENOL(2,6)................ 0.846 0.213 0.209 0.094 87-65-0
DICHLOROPHENOXYACETIC ACID(2,4).... 0.990 0.922 1.000 0.978 94-75-7
DICHLOROPROPANE 1,2................ 0.990 1.054 1.000 0.720 78-87-5
DICHLOROPROPENE(1,3)............... 0.990 1.071 1.000 0.759 542-75-6
DICHLOROPROPYLENE,1,2-(cis)........ 0.990 1.062 1.000 0.831
DICHLOROPROPYLENE,1,2-(trans)...... 0.990 1.072 1.000 0.853 563-54-2
DICHLOROPROPYLENE-2,3.............. 0.990 1.071 1.000 0.857 78-88-6
DICHLOROSTYRENE 2,6................ 0.990 1.149 1.000 0.823
DICHLORO-TRANS-ETHYLENE(1,2)....... 0.990 1.061 1.000 0.980 540-59-0
DIELDRIN........................... 0.990 0.259 0.235 0.225 60-57-1
DIETHYL AMINE...................... 0.828 0.865 1.000 0.286 109-89-7
DIETHYL ETHER...................... 0.990 0.856 1.000 0.423 602-97-6
DIETHYL ETHER ACID CHLORIDE (M).... 0.990 0.379 0.379 0.980 .......................
DIETHYL PHTHALATE.................. 0.990 0.054 0.063 0.853 84-66-2
DIETHYL SULFATE.................... 0.909 0.001 0.002 0.107 .......................
DIETHYL THIOETHER (M).............. 0.990 0.999 0.999 0.980 352-93-2
DIETHYLBENZENE P................... 0.990 1.191 1.000 0.784 105-05-5
DIETHYLDIPHENYL UREA SYM(M)........ 0.990 0.091 0.091 0.859 85-98-3
DIETHYLENE GLYCOL DIETHYL ETHER.... 0.316 0.168 0.217 0.033 .......................
DIETHYLUREA 1,1 (M)................ 0.729 0.726 0.726 0.101 634-95-7
DIHYDRO-5-OXAZALONE (DIHYDROAZLA 0.990 0.982 0.982 0.722 .......................
(M).
DIISOBUTYLENE...................... 0.990 1.127 1.000 0.980 .......................
DIISODECYL PHTHALATE............... 0.990 0.007 0.007 0.451 .......................
DIISOPROPYL BENZENE (PARA)......... 0.990 1.184 1.000 0.980 100-18-5
DIISOPROPYL KETONE................. 0.990 0.973 1.000 0.483 .......................
DIISOPROPYLAMINE................... 0.990 0.939 1.000 0.409 .......................
DIMETHOXY METHANE.................. 0.878 0.594 0.950 0.442 109-87-5
DIMETHOXY-(3,3')-BENZIDINE......... 0.990 0.000 0.000 0.660 119-90-4
DIMETHYL AMINE..................... 0.321 0.709 0.996 0.198 124-40-3
DIMETHYL BENZ(A)ANT 7,12........... 0.990 1.214 0.973 0.857 .......................
DIMETHYL BENZOIC ACID, 2,4......... 0.854 0.101 0.105 0.115 .......................
DIMETHYL BENZOIC ACID, 3,5......... 0.854 0.101 0.105 0.115 .......................
DIMETHYL BENZYLAMINE N,N........... 0.990 0.003 0.003 0.587 103-83-3
DIMETHYL METHYLTHIOCARBAMATE N,N(M) 0.990 0.676 0.676 0.863 .......................
DIMETHYL NITROISOPROPYLAMINE N,N(M) 0.990 0.439 0.439 0.389 .......................
DIMETHYL NITROSAMINE (M)........... 0.990 0.999 0.999 0.980 .......................
DIMETHYL SULFATE................... 0.549 0.034 0.086 0.079 77-78-1
DIMETHYL SULFIDE................... 0.990 0.508 1.000 0.829 75-18-3
DIMETHYL TRISULFIDE................ 0.990 0.354 1.000 0.980 .......................
DIMETHYL-1-NITROBENZENE 2,4........ 0.990 0.564 0.669 0.801 25168-04-
DIMETHYLACETAMIDE.................. 0.547 0.707 0.994 0.284 .......................
dimethylaniline N,N................ 0.990 0.000 0.001 0.342 57-14-7
DIMETHYLBENZYL HYDROPEROXIDE (M)... 0.990 0.149 0.149 0.466 80-15-9
DIMETHYLETHYLAMINE................. 0.990 0.865 1.000 0.523 75-64-9
DIMETHYLGLYCOL..................... 0.990 0.102 0.136 0.483 .......................
DIMETHYLHYDANTOIN,5,5-(M).......... 0.990 0.521 0.521 0.980 77-71-4
DIMETHYLPHENOL (2,4)............... 0.990 0.050 0.047 0.552 105-67-9
DIMETHYLPHENYLCARBINOL (M)......... 0.990 0.385 0.385 0.794 617-94-7
DIMETHYLSULFOXIDE.................. 0.854 0.821 0.990 0.419 .......................
DINITROBENZENE M................... 0.023 0.564 1.000 0.285 99-65-0
DINITROPHENOL 2,4.................. 0.990 0.004 0.008 0.059 51-28-5
DINITROTOLUENE 2,6................. 0.990 ........... ........... 0.109 606-20-2
[[Page 68080]]
DINITROTOLUENE (2,4)............... 0.390 0.052 0.085 0.178 121-14-2
DINOCAP (M)........................ 0.990 0.043 0.043 0.980 39300-45-
DI-n-OCTYL PHTHALATE............... 0.990 0.000 0.000 0.980 117-84-0
DINOSEB (M)........................ 0.990 0.105 0.105 0.575 88-85-7
DIOXANE (1,4)...................... 0.387 0.618 0.869 0.181 123-91-1
DIOXIN (M)......................... 0.990 0.064 0.064 0.279 828-00-2
DIPHENYL ETHER (M)................. 0.990 0.140 0.140 0.662 101-84-8
DIPHENYL THIOETHER (M)............. 0.990 0.132 0.132 0.838 139-66-2
DIPHENYLAMINE (M).................. 0.513 0.140 0.140 0.074 122-39-4
DIPHENYLBUTADIENE 1,3 (M).......... 0.990 0.122 0.122 0.647 886-65-7
DIPHENYLCHLOROMETHANE (M).......... 0.990 0.124 0.124 0.850 90-99-3
DIPHENYLDIKETONE (M)............... 0.990 0.120 0.120 0.851 134-81-6
DIPHENYLETHANE 1,1 (M)............. 0.990 0.134 0.134 0.551 .......................
DIPHENYLETHANOL 1,1 (M)............ 0.416 0.126 0.126 0.066 599-67-7
DIPHENYLHYDRAZINE,1,1-(M).......... 0.990 0.133 0.133 0.796 530-50-7
DIPHENYLMETHANE.................... 0.990 0.628 0.509 0.195 101-81-5
DIPROPYLAMINE...................... 0.979 0.927 0.998 0.411 142-84-7
DIPROPYLBUTRAL..................... 0.990 0.622 0.618 0.292 .......................
DIPROPYLFORMAMIDE (M).............. 0.990 0.503 0.503 0.980 6282-00-4
DI-tert-BUTYL-p-CRESOL............. 0.990 0.031 0.028 0.072 128-37-0
DIVINYL KETONE (M)................. 0.990 0.999 0.999 0.457 .......................
dodecane........................... 0.990 1.089 1.000 0.980 .......................
EDTA (M)........................... 0.990 0.999 0.999 0.412 60-00-4
ENDOSULFAN......................... 0.900 0.020 0.018 0.102 115-29-7
ENDOSULFAN SULFATE (M)............. 0.990 0.014 0.014 0.980 1031-07-8
ENDRIN ALDEHYDE (M)................ 0.990 0.999 0.999 0.412 .......................
EPICHLOROHYDRIN.................... 0.915 0.847 0.939 0.350 106-89-8
EPOXYBUTANE 1,2.................... 0.990 0.879 1.000 0.582 .......................
ETHANE............................. 0.990 1.067 1.000 0.946 .......................
ETHANOL............................ 0.322 0.586 0.860 0.126 64-17-5
ETHENE............................. 0.990 1.187 1.000 0.980 .......................
ETHENYL 2 METHYL BENZENE, 1-....... 0.990 1.240 1.000 0.710 .......................
ETHOXYETHANOL-2.................... 0.545 0.144 0.207 0.134 110-80-5
ETHYL 2 METHYL BENZENE, 1-......... 0.990 1.198 1.000 0.731
ETHYL ACETATE PEROXIDE (M)......... 0.990 0.659 0.659 0.706 .......................
ETHYL ACRYLATE..................... 0.990 0.788 1.000 0.483 140-88-5
ETHYL BUTANOATE.................... 0.990 0.775 1.000 0.457 .......................
ETHYL CYANIDE (PROPIONITRILE) (M).. 0.990 0.999 0.999 0.580 107-12-0
ETHYL ETHER........................ 0.990 0.856 1.000 0.506 60-29-7
ETHYL HEPTANOATE................... 0.990 0.868 1.000 0.470 .......................
ETHYL ISOPROPYL PEROXIDE (M)....... 0.990 0.931 0.931 0.386 .......................
ETHYL METHANOATE................... 0.990 0.537 1.000 0.566 .......................
ETHYL PENTANOATE................... 0.990 0.813 1.000 0.428 .......................
ETHYL PEROXIDE..................... 0.341 0.146 0.283 0.112 .......................
ETHYL PROPYL ETHER................. 0.990 0.894 1.000 0.571 .......................
ETHYL S,S-DIPHENYL PHOSPHORODITH 0.990 0.070 0.070 0.333 1709-49-8
(M).
ETHYL TOLUENE, 4................... 0.990 1.198 1.000 0.857
ETHYL VINYL ETHER.................. 0.990 0.890 1.000 0.652 .......................
ETHYL(2) HEXANOL................... 0.990 0.256 0.268 0.266 104-76-7
ETHYL-(2)-PROPYL-(3) ACROLEIN (M).. 0.977 0.999 0.999 0.257 645-62-5
ETHYLACETATE....................... 0.987 0.722 1.000 0.404 141-78-6
ETHYLAMINE......................... 0.358 0.711 0.999 0.280 75-04-7
ETHYLBENZENE....................... 0.990 1.204 1.000 0.828 100-41-4
ETHYLENE........................... 0.990 1.187 1.000 0.980 74-85-1
ETHYLENE DIAMINE................... 0.963 0.012 0.022 0.241 107-15-3
ETHYLENE DIBROMIDE................. 0.990 0.537 0.999 0.565 106-93-4
ETHYLENE GLYCOL DIMETHYL ETHER..... 0.905 0.601 0.860 0.316 110-71-4
ETHYLENE GLYCOL MONOBUTYL ETHER 0.772 0.031 0.043 0.067 .......................
ACETATE.
ETHYLENE GLYCOL MONOMETHYL ETHER 0.285 0.055 0.093 0.048 110-49-6
ACETATE.
ETHYLENE OXIDE..................... 0.986 0.712 1.000 0.503 75-21-8
ETHYLETHOXY PROPIONATE............. 0.940 0.491 0.577 0.213 .......................
ETHYLHEXYL HEXANOL 2............... 0.990 0.065 0.064 0.125 .......................
ETHYLHEXYLACRYLATE,2-.............. 0.990 0.925 0.992 0.705 103-11-7
FENCHONE,d- (M).................... 0.990 0.149 0.149 0.406 4695-62-9
FLUORANTHENE....................... 0.990 0.049 0.039 0.656 206-44-0
FLUORENE........................... 0.990 0.965 0.774 0.314 86-73-7
FLUOROMETHANE...................... 0.990 1.130 1.000 0.873 .......................
FLUOROURACIL,5- (M)................ 0.990 0.999 0.999 0.412 51-21-8
FORMYL FLUORIDE.................... 0.990 0.848 1.000 0.577 .......................
FREON 11, fluorotrichloromethane... 0.990 1.053 1.000 0.954 .......................
FREON 12 DICHLORODIFLUOROMETHANE... 0.990 1.059 1.000 0.980 75-71-8
[[Page 68081]]
FREON 12, dichlorodifluoromethane.. 0.990 1.059 1.000 0.980 .......................
FREONS (M)......................... 0.990 0.644 0.644 0.980 .......................
FURAN.............................. 0.990 0.983 1.000 0.755 110-00-9
FURFURAL........................... 0.990 0.288 0.334 0.354 98-01-1
FUROIC ACID (M).................... 0.990 0.794 0.794 0.480 88-14-2
GEOSMIN (M)........................ 0.990 0.134 0.134 0.406 19700-21-
GLYOXAL............................ 0.502 0.490 0.888 0.297 .......................
GUANINE (M)........................ 0.990 0.149 0.149 0.980 73-40-5
HEPTACHLOR......................... 0.990 0.619 0.566 0.647 76-44-8
HEPTACHLOR EPOXIDE (M)............. 0.976 0.030 0.030 0.162 1024-57-3
HEPTANAL........................... 0.990 0.942 0.991 0.407 .......................
HEPTANE ISO........................ 0.990 1.099 1.000 0.980 31394-54-
HEPTANE(-n)........................ 0.990 1.085 1.000 0.980 142-82-5
HEXACHLOROBENZENE.................. 0.990 1.047 0.966 0.643 118-74-1
HEXACHLOROBUTADIENE................ 0.990 0.937 0.883 0.855 87-68-3
HEXACHLOROCYCLOHEXANE (GAMMA 0.990 0.141 0.132 0.106 58-89-9
ISOMER).
HEXACHLOROCYCLOPENTADIE NE......... 0.990 0.886 0.826 0.803 77-47-4
HEXACHLOROETHANE................... 0.990 0.515 0.499 0.852 67-72-1
HEXACHLOROPENTADIENE (M)........... 0.990 0.088 0.088 0.860 .......................
HEXADECANE N (M)................... 0.990 0.112 0.112 0.980 544-76-3
HEXAFLUOROACETONE.................. 0.990 0.968 1.000 0.980 .......................
HEXAFLUOROPROPENE.................. 0.990 1.080 1.000 0.980 116-15-4
HEXAMETHYLENEDIAMINE (M)........... 0.971 0.724 0.724 0.213 124-09-4
HEXAMETHYLENIMINE.................. 0.520 0.923 0.989 0.109 .......................
HEXANAL............................ 0.990 0.928 0.997 0.400 .......................
HEXANE(-n)......................... 0.990 1.084 1.000 1.000 110-54-3
HEXANOL 2 ETHYL.................... 0.942 0.256 0.268 0.134 104-76-7
HEXANOL-1.......................... 0.963 0.322 0.355 0.180 111-27-3
HEXEN-2-ONE 5...................... 0.979 0.885 0.915 0.347 .......................
HEXENE............................. 0.990 1.119 1.000 0.980 .......................
HEXYL ETHANOATE.................... 0.990 0.865 0.998 0.475 .......................
HEXYLAMINE......................... 0.948 0.803 0.870 0.239 .......................
HYDROFLUORIC ACID (M).............. 0.990 0.558 0.558 0.537 7664-39-3
HYDROGEN SULFIDE................... 0.990 0.333 1.000 0.882 .......................
HYDROXY DIMETHYL ETHER (M)......... 0.990 0.999 0.999 0.874
HYDROXY-1,3-CYCLOPENTADIENE 5 (M).. 0.990 0.999 0.999 0.728
HYDROXY-4-METHYLTETRAHYDROFURAN(M). 0.990 0.948 0.948 0.385
HYDROXY-5-METHYLDIMETHYL PHTHALA 0.990 0.113 0.113 0.980
(M).
HYDROXY6METHYLPYRIDINE3 CARBOXYLI 0.990 0.148 0.148 0.409 38116-61-
(M).
HYDROXYACETIC ACID................. 0.760 0.000 0.001 0.570 79-14-1
HYDROXYCYCLOHEXANONE 4 (M)......... 0.631 0.761 0.761 0.087
HYDROXYDIMETHYL PHTHALATE 4 (M).... 0.990 0.120 0.120 0.980
HYDROXYMETHYL ACETYLENE (M)........ 0.990 0.999 0.999 0.980
HYDROXYMETHYL ISOPROPYL KETONE (M). 0.990 0.999 0.999 0.662
HYDROXYMETHYL, N-METHYLETHYL AMI 0.990 0.999 0.999 0.980
(M).
HYDROXYMETHYL-N-CHLOROMETHYLETHY 0.990 0.838 0.838 0.980
(M).
HYDROXYMETHYLPHENYL CARBAMATE N (M) 0.920 0.147 0.147 0.137
HYDROXYMETHYLTHIOBENZENE (M)....... 0.990 0.320 0.320 0.790
HYDROXYMETHYLVINYL ETHER (M)....... 0.990 0.490 0.490 0.905
HYDROXYPENTANE 3 (M)............... 0.990 0.999 0.999 0.450
INDANOL,5-(M)...................... 0.990 0.128 0.128 0.980 1470-94-6
INDOLE (M)......................... 0.990 0.708 0.708 0.980 120-72-9
IODOCOUMARAN 2 (M)................. 0.990 0.102 0.102 0.980
ISOBUTANE.......................... 0.990 1.103 1.000 0.963
ISOBUTYL ETHANOATE................. 0.990 0.786 1.000 0.486
ISOBUTYLBENZENE.................... 0.990 1.191 1.000 0.905
ISOBUTYLENE........................ 0.990 1.141 1.000 0.916
ISOCYANO 4 METHYL BENZENE *........ 0.980 0.422 0.384 0.198
ISODECANOL......................... 0.932 0.165 0.158 0.099
ISODECYL OCTYL ESTER............... 0.990 1.033 1.000 0.906
ISOPENTANE......................... 0.990 1.101 1.000 0.954
ISOPENTYL ETHANOATE................ 0.990 0.852 0.999 0.487
ISOPENTYL METHANOATE............... 0.990 0.941 0.997 0.503
ISOPHORONE......................... 0.616 0.525 0.506 0.108 78-59-1
ISOPROPYL AMINE.................... 0.990 0.811 1.000 0.538 75-31-0
ISOPROPYL ETHER.................... 0.019 0.939 1.000 0.730 108-20-3
ISOPROPYL METHANOATE............... 0.990 0.886 1.000 0.578
ISOPROPYL METHANOATE............... 0.990 0.865 1.000 0.547
ISOPROPYL PROPANOATE............... 0.990 0.825 1.000 0.487
ISOXAZOLOL,5-(AMINOMETHYL)-3-(M)... 0.990 0.760 0.760 0.980 2763-96-4
LINDANE hexachlorocyclohexane...... 0.990 1.063 1.000 0.703
[[Page 68082]]
MELAMINE (M)....................... 0.990 0.554 0.554 0.980 108-78-1
MERCAPTOBENZOTHIAZOLE,2............ 0.990 0.844 1.000 0.641
MERCURY (M)........................ 0.990 0.125 0.125 0.854 7439-97-6
METHACRYLIC ACID................... 0.990 0.068 0.091 0.194 79-41-4
METHANE............................ 0.990 1.067 1.000 0.980 74-82-8
METHANETHIOL (M)................... 0.990 0.999 0.999 0.731 74-93-1
METHANOL........................... 0.317 0.433 0.855 0.168 67-56-1
METHAPYRILENE (M).................. 0.990 0.094 0.094 0.980 91-80-5
METHOXYACETIC ACID................. 0.593 0.005 0.010 0.064 625-45-6
METHOXYACETONITRILE (M)............ 0.990 0.999 0.999 0.382 1738-36-9
METHOXYCHLOR....................... 0.990 0.085 0.081 0.333 72-43-5
METHYL 1-PENTENE 2................. 0.990 1.125 1.000 0.980 763-29-1
METHYL 2-PROPYL ETHER.............. 0.990 0.976 1.000 0.537
METHYL ACETATE..................... 0.989 0.590 0.906 0.454 79-20-9
METHYL ACRYLATE.................... 0.990 0.748 1.000 0.478 96-33-3
METHYL ACRYLONITRILE (M)........... 0.990 0.999 0.999 0.980 126-98-7
METHYL AMINE....................... 0.990 0.516 0.992 0.877 74-89-5
METHYL AMINOACETYLENE (M).......... 0.990 0.999 0.999 0.980
METHYL AZIRIDINE 2................. 0.900 0.838 1.000 0.360
METHYL BENZOATE.................... 0.692 0.924 0.981 0.168
METHYL BENZYL ALCOHOL 4............ 0.917 0.058 0.056 0.154
METHYL BIPHENYL (-p) (M)........... 0.990 0.141 0.141 0.819 644-08-6
METHYL BUTANOATE................... 0.990 0.775 1.000 0.413
METHYL CHLORIDE.................... 0.990 1.040 1.000 0.840 74-87-3
METHYL CHLOROACETAMIDE N (M)....... 0.863 0.872 0.872 0.137
METHYL CHLOROCARBONATE (M)......... 0.990 0.999 0.999 0.980 79-22-1
METHYL CHOLANTHRENE 3.............. 0.990 1.234 0.990 0.322 56-49-5
METHYL COUMARAN 2 (M).............. 0.990 0.145 0.145 0.811 607-71-6
METHYL CYCLOHEXANE................. 0.990 1.107 1.000 0.980 108-87-2
METHYL ETHER dimethyl ether........ 0.990 0.698 1.000 0.730 115-10-6
METHYL ETHYL ETHER................. 0.990 0.791 1.000 0.617
METHYL ETHYL KETONE, 2 butanone.... 0.958 0.872 0.990 0.477 78-93-3
METHYL FORMATE..................... 0.590 0.535 0.997 0.548 107-31-3
METHYL HEXANOATE................... 0.990 0.843 1.000 0.441
METHYL IODIDE...................... 0.990 0.354 1.000 0.711 74-88-4
METHYL ISOAMYL KETONE (M).......... 0.990 0.761 0.761 0.318 110-12-3
METHYL ISOBUTYL KETONE............. 0.990 0.933 0.979 0.529 108-10-1
METHYL ISOCYANATE.................. 0.990 0.272 1.000 0.870 624-83-9
METHYL ISOPROPYL KETONE............ 0.986 0.922 0.991 0.523 563-80-4
METHYL MERCAPTAN................... 0.990 0.333 1.000 0.719
METHYL METHACRYLATE................ 0.986 0.801 0.999 0.366 80-62-6
METHYL MORPHOLINE.................. 0.435 0.365 0.475 0.078
METHYL NAPTHALENE (1-)............. 0.990 1.204 0.973 0.512 90-12-0
METHYL NAPTHALENE (-12)............ 0.990 1.219 0.986 0.246 91-57-6
METHYL OCTANOATE................... 0.990 0.888 1.000 0.524
METHYL PENTANOATE.................. 0.990 0.813 1.000 0.417
METHYL PEROXIDE.................... 0.587 0.024 0.070 0.159
METHYL PROPANOATE.................. 0.985 0.724 1.000 0.431
METHYL PROPENE 2 (M)............... 0.990 0.999 0.999 0.980 115-11-7
METHYL PROPYL ETHER................ 0.990 0.848 1.000 0.598
METHYL TERTIARY-BUTYL ETHER........ 0.990 0.911 1.000 0.573 1634-04-4
METHYL TETRAHYDROFURAN 2........... 0.990 0.914 1.000 0.357
METHYL THIOURACIL (M).............. 0.990 0.283 0.283 0.753 56-04-2
METHYL-1,3-CYCLOPENTADIENE 5 (M)... 0.990 0.999 0.999 0.924 26519-91-
METHYL-2,3,4-TRIHYDROQUINOLINE N 0.912 0.218 0.218 0.137
(M).
METHYL-2-AMINOETHYLAMINE (M)....... 0.990 0.999 0.999 0.871 109-81-9
METHYL-2-HYDROXYETHYLAMINE (M)..... 0.578 0.999 0.999 0.081 109-83-1
METHYL-3-ACETYLCYCLOPENTADIENE 1 0.990 0.897 0.897 0.754
(M).
METHYL-3-NITROBENZYL ALCOHOL 4 (M). 0.767 0.141 0.141 0.103 40870-59-
METHYL-4-NITROBENZYL ALCOHOL 2 (M). 0.568 0.141 0.141 0.079 23876-13-
METHYL-5-THIOACETYLDIHYDRO1,3THI 0.994 0.146 0.146 0.980
(M).
METHYLACETONITRILE (M)............. 0.990 0.999 0.999 0.980 75-86-5
METHYLBUTADIENE (isoprene)......... 0.990 1.176 1.000 0.980
METHYLBUTYLAMINE................... 0.809 0.791 0.883 0.178
METHYLCYCLOPENTANE................. 0.990 1.109 1.000 0.980
METHYLENE CHLORIDE, dichloromethane 0.990 1.017 1.000 0.770 75-09-2
METHYLFURAN 2 (M).................. 0.509 0.999 0.999 0.073 534-22-5
METHYLISOBORNEOL,2-(M)............. 0.990 0.141 0.141 0.794 NA
METHYLPHENYL CARBAMATE N (M)....... 0.906 0.320 0.320 0.137
METHYL-PHENYLETHYLAMINE N (M)...... 0.990 0.401 0.401 0.587 589-08-2
METHYL-p'-METHYLTRIPHENYL PHOSPH 0.990 0.079 0.079 0.862
(M).
[[Page 68083]]
METHYLSTYRENE (-4)................. 0.990 1.217 1.000 0.767 98-93-9
METHYLTIN TRICHLORIDE (M).......... 0.470 0.105 0.105 0.070 993-16-8
METHYL-TRIHYDRO-1,3-THIAZOLE 4 (M). 0.990 0.914 0.914 0.316
MITOMYCIN C (M).................... 0.990 0.058 0.058 0.980 50-07-7
MNNG (M)........................... 0.990 0.199 0.199 0.980 70-25-7
MONOCHLORODIFLUOROMETHANE.......... 0.990 1.023 1.000 0.990 75-45-6
MORPHOLINE......................... 0.990 0.148 0.207 0.437 110-91-8
MUSTARD GAS (M).................... 0.990 0.146 0.146 0.406 505-60-2
NAPHTHALENE........................ 0.990 1.239 0.994 0.506
NAPHTHALENE ACETIC ACID 2 METHYL,.. 10.99 0.863 0.830 0.567
NAPHTHOQUINONE-1,4 (M)............. 0.958 0.146 0.146 0.164 130-15-4
NICKEL CYANIDE (M)................. 0.990 0.817 0.817 0.284 557-19-7
NITRO m XYLENE, 2.................. 0.990 0.779 0.923 0.455
NITRO-4-METHYLBENZOATE 3 (M)....... 0.990 0.128 0.128 0.980
NITROANILINE P..................... 0.990 0.000 0.000 0.411 100-01-6
NITROBENZENE....................... 0.808 0.305 0.394 0.228 98-95-3
NITROBENZENESULFONYL CHLORIDE P (M) 0.990 0.114 0.114 0.458 98-74-8
NITROBENZYL ALCOHOL P (M).......... 0.990 0.149 0.149 0.356 619-73-8
NITROBIPHENYL,4-................... 0.976 0.044 0.046 0.075 92-93-3
NITROCELLULOSE (M)................. 0.990 0.000 0.000 0.558 9004-70-0
NITROETHANE........................ 0.225 0.412 0.964 0.161
NITROGEN MUSTARD N-OXIDE (M)....... 0.990 0.139 0.139 0.794 126-85-2
NITROMETHANE....................... 0.990 0.255 0.954 0.883 75-52-5
NITROMETHYLBENZENE................. 0.990 0.463 0.570 0.270
NITROPROPANE 2..................... 0.985 0.531 0.989 0.437 79-46-9
NITROSOBENZYL ALCOHOL 4 (M)........ 0.901 0.405 0.405 0.136
NITROSOPYRROLIDINE N (M)........... 0.990 0.997 0.997 0.980 930-55-2
NITROTOLUENE (-p).................. 0.990 0.339 0.417 0.45199- 99-0
NITROTOLUENE, m.................... 0.990 0.475 0.585 0.279
NITROTOLUENE, o.................... 0.990 0.534 0.657 0.296
NITROTOLUENE, o.................... 0.988 0.534 0.657 0.266
NONANAL............................ 0.990 0.938 0.959 0.558
NONANOL, n......................... 0.856 0.099 0.103 0.091
NONYLPHENOL(M)..................... 0.990 0.115 0.115 0.794 25154-52
OCTAMETHYLPYROPHOSPHORAMIDE (M).... 0.990 0.082 0.082 0.980 152-16-9
OCTANAL............................ 0.990 0.946 0.979 0.465
OCTANE............................. 0.990 1.086 1.000 0.980 111-65-9
OCTANOL 1.......................... 0.990 0.184 0.195 0.240 111-87-5
OCTANOL 2.......................... 0.983 0.381 0.398 0.136
OCTANOL 3.......................... 0.990 0.514 0.536 0.104
OCTANOL 4.......................... 0.990 0.446 0.466 0.118
OIL (decane)....................... 0.990 1.088 1.000 0.951
OXAMIC ACID (M).................... 0.990 0.999 0.999 0.317 471-47-6
PARABROMOPHENOL (M)................ 0.925 0.139 0.139 0.135 106-41-2
PARAFORMALDEHYDE (M)............... 0.990 0.000 0.000 0.558 30525-89-
PARALDEHYDE........................ 0.795 0.717 0.991 0.232 123-63-7
PCB 1016 (monochlorobiphenyl)...... 0.990 1.204 1.000 0.345 12674-11-
PCB 1221 (monochlorobiphenyl)...... 0.990 1.204 1.000 0.418 11104-28-
PCB 1232 (dichlorobiphenyl)........ 0.990 1.177 1.000 0.543 11141-16-
PCB 1242 (trichlorobiphenyl)....... 0.990 1.075 0.929 0.488 53469-21-
PCB 1248 (quatrochlorobiphenyl).... 0.990 1.142 1.000 0.640 12672-29-
PCB 1254(pentachlorobipheny l...... 0.990 0.698 0.618 0.813 11097-69-
PCB 1260 (hexachlorobiphenyl)...... 0.990 0.504 0.450 0.791 11096-82-
PCB'S (Aroclors)................... 0.990 1.142 1.000 0.507
PENTACHLOROBENZENE................. 0.990 1.091 1.000 0.796 608-93-5
PENTACHLOROETHANE.................. 0.990 0.991 0.966 0.877 76-01-7
PENTACHLORONITROBENZENE............ 0.990 0.774 0.839 0.405
PENTACHLOROPHENOL.................. 0.990 0.092 0.090 0.298 87-86-5
PENTADIENE 1,2..................... 0.990 1.191 1.000 0.855
PENTAERYTHRITOL TETRANITRATE (M)... 0.976 0.067 0.067 0.162 78-11-5
PENTANAL........................... 0.990 0.904 0.999 0.406
PENTANE............................ 0.990 1.082 1.000 0.925
PENTYL PROPANOATE.................. 0.990 0.868 1.000 0.537
PENTYLAMINE........................ 0.903 0.822 0.917 0.254
PENTYLBENZENE...................... 0.990 1.173 1.000 0.766
PENTYLCYCLOPENTANE................. 0.990 1.103 1.000 0.980
PERCHLOROMETHYL MERCAPTAN (M)...... 0.990 0.132 0.132 0.980 594-42-3
PERYLENE (M)....................... 0.990 0.099 0.099 0.853 198-55-0
PHENANTHRENE....................... 0.990 0.279 0.222 0.193 85-01-8
PHENOL,3-(1,1-DIMETHYLETHYL)-(M)... 0.990 0.558 0.558 0.794 585-34-2
PHENOTHIAZINE (M).................. 0.990 0.125 0.125 0.874 92-84-2
[[Page 68084]]
PHENYL ISOCYANATE (M).............. 0.990 0.674 0.674 0.855 103-71-9
PHENYLACETIC PEROXIDE (M).......... 0.917 0.149 0.149 0.137
PHENYLCYCLOHEXANONE 4.............. 0.990 1.029 0.914 0.826 4894-75-1
PHENYLHYDRAZINE (M)................ 0.990 0.860 0.860 0.314 100-63-0
PHENYLPHENOL P..................... 0.990 0.001 0.001 0.710 92-69-3
PHENYLTHIOUREA (M)................. 0.990 0.149 0.149 0.863 103-85-5
PHOSGENE (decomposes).............. 0.990 0.868 1.000 0.872 75-44-5
PHOSPHINE.......................... 0.990 0.213 1.000 0.996 7803-51-2
PHTHALATE, DI N BUTYL-............. 0.971 0.006 0.006 0.095 .......................
PHTHALATE, DI N OCTYL.............. 0.990 0.042 0.044 0.574
PHTHALIC ACID...................... 0.990 0.714 0.924 0.858 88-99-3
PHTHALIMIDE........................ 0.990 0.850 0.957 0.854 85-41-6
PICOLINE(2-) (M)................... 0.990 0.999 0.999 0.398 109-06-8
PINENE(alpha-)..................... 0.990 1.165 1.000 0.890 80-56-8
PIPERAZINE......................... 0.990 0.031 0.042 0.339 110-85-0
POLYCYCLIC KETONE O (M)............ 0.990 0.000 0.000 0.948
PROPANAL........................... 0.902 0.813 1.000 0.436
PROPANE............................ 0.990 1.075 1.000 0.880 74-98-6
PROPANE), 2,2'-OXYBIS(2-CHLORO-(M). 0.990 0.138 0.138 0.980 39638-32
PROPANOIC ACID..................... 0.104 0.105 0.163 0.064 79-09-4
PROPANOL........................... 0.595 0.305 0.421 0.185
PROPANOL ISO....................... 0.451 0.740 0.926 0.190 67-63-0
PROPENAL........................... 0.943 0.855 1.000 0.487
PROPENE............................ 0.990 1.144 1.000 0.980
PROPENYL BENZENE................... 0.990 1.217 1.000 0.860
PROPIONALDEHYDE.................... 0.990 0.813 0.999 0.406 123-38-6
PROPIONIC ACID..................... 0.990 0.066 0.102 0.381 79-09-4
PROPIONITRILE (M).................. 0.990 0.999 0.999 0.580 107-12-0
PROPYL ACETATE ISO................. 0.990 0.786 1.000 0.453 108-21-4
PROPYL BUTANOATE................... 0.990 0.843 1.000 0.475
PROPYL ETHER....................... 0.990 0.921 1.000 0.716 111-43-3
PROPYL METHANOATE.................. 0.990 0.714 1.000 0.506
PROPYL PROPANOATE.................. 0.990 0.813 1.000 0.446
PROPYL THIOURACIL (M).............. 0.990 0.140 0.140 0.921 51-52-5
PROPYL(-n) ACETATE................. 0.990 0.773 0.999 0.448 109-60-4
PROPYL(-n) BENZENE................. 0.990 1.191 1.000 0.781 103-65-1
PROPYL-3-METHOXY PYRAZINE,2-ISO(M). 0.990 0.149 0.149 0.980 25773-40-
PROPYLAMINE........................ 0.563 0.778 0.971 0.249 107-10-8
PROPYLCYCLOPENTANE................. 0.990 1.105 1.000 0.980
PROPYLENE.......................... 0.990 1.144 1.000 0.980 115-07-1
PROPYLENE CHLOROHYDRIN............. 0.274 0.338 0.383 0.069
PROPYLENE OXIDE.................... 0.990 0.841 1.000 0.600 75-56-9
PROPYLENIMINE 1,2 2 methyl aziri... 0.609 0.792 0.944 0.239 75-55-8
PROPYN-1-OL 2(PROPARLGYL).......... 0.550 0.271 0.321 0.225 107-19-7
PROPYNE............................ 0.990 1.200 1.000 0.853
PYRENE............................. 0.990 0.046 0.036 0.113 129-00-0
PYRIDINE........................... 0.956 0.608 0.600 0.255 110-86-1
PYRROLIDINE........................ 0.198 0.814 0.936 0.072
QUINALDINE (M)..................... 0.990 0.999 0.999 0.853 91-63-4
RESERPINE (M)...................... 0.990 0.000 0.000 0.648 50-55-5
s ACETYLMERCAPTOSUCCINIC ACID...... 0.318 0.030 0.050 0.069
S4CHL.CYCLOHEX.00DIMETH 0.990 0.052 0.052 0.342
.PHOS.DIT(M).
SACCHARIN (M)...................... 0.990 0.133 0.133 0.850 81-07-2
SAFROLE (M)........................ 0.990 0.144 0.144 0.406 94-59-7
sec BUTYLBENZENE................... 0.990 1.187 1.000 0.860
SILVEX............................. 0.990 1.106 1.000 0.774 93-72-1
SODIUM DODECYL SULFATE (M)......... 0.988 0.081 0.081 0.195 151-21-3
SODIUM DODECYLBENZENE SULFONATE (M) 0.908 0.083 0.083 0.121 25155-30-
STREPTOZOTOCIN (M)................. 0.990 0.092 0.092 0.980 18883-66-
STYRENE............................ 0.990 1.229 1.000 0.800 100-42-5
STYRENE OXIDE...................... 0.990 0.883 0.830 0.341
SULFIDE (M)........................ 0.990 0.999 0.999 0.649
TAMARON (METHAMIDIPHOS)............ 0.306 0.430 0.672 0.091
TARS(M)............................ 0.990 0.025 0.025 0.642
t-BUTYL HYDROPEROXIDE.............. 0.497 0.289 0.404 0.199 75-91-2
TERPINEOL, ALPHA................... 0.990 1.008 0.984 0.473
tert BUTANOL....................... 0.630 0.856 0.989 0.231
tert-AMYLBENZENE................... 0.990 1.173 1.000 0.870
tert-BUTYLBENZENE.................. 0.990 1.192 1.000 0.855
TETRACHLOROAQUINONE (M)............ 0.990 0.102 0.102 0.980
TETRACHLOROBENZENE(1,2,3,4)........ 0.990 1.101 1.000 0.700 634-66-2
[[Page 68085]]
TETRACHLOROBENZENE(1,2,3,5)........ 0.990 1.101 1.000 0.732 634-90-2
TETRACHLOROBENZENE(1,2,4,5)........ 0.990 1.101 1.000 0.732 95-94-3
TETRACHLORODIBENZOFURAN (2,3,7,8) 0.990 0.072 0.072 0.332 51207-31-
(M).
TETRACHLORODIBENZO-p- 0.990 0.109 0.101 0.173 1746-01-6
DIOXIN(2,3,7,8).
TETRACHLOROETHANE(1,1,1,2) (M)..... 0.990 0.141 0.141 0.459 630-20-6
TETRACHLOROETHANE(1,1,2,2)......... 0.990 1.015 0.999 0.397 79-34-5
TETRACHLOROETHENE.................. 0.990 1.048 1.000 0.917 127-18-4
TETRACHLOROPHENOL(2,3,4,6)......... 0.447 1.024 1.000 0.091 58-90-2
TETRACHLOROPHENOL(2,3,5,6)......... 0.990 0.010 0.010 0.980 935-95-5
TETRACHLOROPROPENE(1,1,2,3) (M).... 0.990 0.135 0.135 0.831 10436-39-
TETRADECANE........................ 0.990 1.089 1.000 0.896 629-59-4
TETRAETHYL LEAD.................... 0.990 0.958 0.889 0.980 78-00-2
TETRAETHYLENE GLYCOL (M)........... 0.892 0.128 0.128 0.117 112-60-7
TETRAETHYLENE PENTANE.............. 0.990 1.183 1.000 0.881
TETRAETHYLPYROPHOSPHATE (M)........ 0.990 0.080 0.080 0.980 107-49-3
TETRAFLUOROETHENE.................. 0.990 1.080 1.000 0.980
TETRAFLUOROMETHANE................. 0.990 1.037 1.000 0.980
TETRAHYDROBENZALDEHYDE............. 0.912 0.635 0.641 0.213
TETRAHYDROFURAN.................... 0.830 0.860 1.000 0.322 109-99-9
TETRAHYDRONAPHTHALENE,1,2,3,4-(M).. 0.887 0.452 0.452 0.794 119-64-2
TETRAHYDROPYRAN.................... 0.980 0.898 1.000 0.381 142-68-7
TETRAHYDROTHIOPHENE................ 0.990 0.692 1.000 0.566
TETRALIN........................... 0.990 1.189 1.000 0.632
TETRANITROMETHANE.................. 0.990 0.267 1.000 0.852 509-14-8
THIOACETAMIDE (M).................. 0.990 0.999 0.999 0.375 62-55-5
THIOBENZYL ALCOHOL P (M)........... 0.887 0.588 0.588 0.136 100-53-8
THIOBISETHANE, 1,1'................ 0.990 0.692 1.000 0.763
THIOCYANATE (TOTAL AS SCN-) (M).... 0.990 0.642 0.642 0.894 NA
THIOMETHANOL (M)................... 0.990 0.999 0.999 0.499 74-93-1
THIOPHENOL (M)..................... 0.659 0.826 0.826 0.933 108-98-5
THIOPROPIONAMIDE 2 (M)............. 0.696 0.948 0.948 0.097
THIOUREA........................... 0.892 0.011 0.024 0.472 62-56-6
THIRAM (M)......................... 0.990 0.105 0.105 0.980 137-26-8
THYMINE (M)........................ 0.990 0.556 0.556 0.806 65-71-4
TOLUENE............................ 0.990 1.215 1.000 0.804 108-88-3
TOLUENE24DIAZOBIS-METATOLUENEDIA(M) 0.986 0.011 0.011 0.188
TOLUENESULFONYL CHLORIDE........... 0.604 0.046 0.047 0.068
TOLUIC ALDEHYDE.................... 0.990 0.513 0.478 0.382 122-78-1
TOLUIDINE (-0)..................... 0.459 0.159 0.152 0.052 95-53-4
TOLUIDINE HYDROCHLORIDE,o-(M)...... 0.990 0.258 0.258 0.980 636-21-5
TOLUIDINE P........................ 0.850 0.274 0.262 0.208 106-49-0
TOXAPHENE.......................... 0.990 0.054 0.050 0.735 8001-35-2
trans 1,4 DIMETHYLCYCLOHEXANE...... 0.990 1.117 1.000 0.980
trans 2 BUTENAL.................... 0.387 0.911 1.000 0.267
trans 2 HEPTENE.................... 0.990 1.121 1.000 0.980
trans 2 HEXENAL.................... 0.856 0.963 1.000 0.295
trans 2 OCTENAL.................... 0.990 0.985 0.993 0.381
trans, trans 2,4 HEXADIENAL........ 0.233 0.996 1.000 0.151
TRIBROMOMETHYLPHOSPHATE (M)........ 0.980 0.052 0.052 0.169
TRIBUTYL PHOSPHOROTRITHIOATE SSS... 0.990 . . 0.334 78-48-8
TRIBUTYL TIN ACETATE............... 0.990 0.929 0.980 0.789
TRIBUTYLPHOSPHATE.................. 0.990 1.073 0.988 0.980 126-73-8
TRICHLORO(1,1,2)TRIFLUO ROETHANE(M) 0.990 0.131 0.131 0.980 76-13-1
TRICHLORO-1,2,2-TRIFLUOROETHANE,1,1 0.990 1.033 1.000 0.980 76-13-1
TRICHLORO-1,3,5-TRIAZINE 2,4,6 (M). 0.990 0.133 0.133 0.552 108-77-0
TRICHLOROANISOLE 2,3,6 (M)......... 0.990 0.119 0.119 0.980 50375-10-
TRICHLOROBENZENE 1,2,3............. 0.990 1.114 1.000 0.808 87-61-6
TRICHLOROBENZENE 1,2,4............. 0.990 1.114 1.000 0.637 120-82-1
TRICHLOROBENZENE 1,3,5............. 0.990 1.114 1.000 0.877 108-70-3
TRICHLOROBUTANE 1,2,3 (M).......... 0.990 0.144 0.144 0.980 18338-40-
TRICHLOROETHANE 1,1,1.............. 0.990 1.037 1.000 0.913 71-55-6
TRICHLOROETHANE 1,1,2.............. 0.990 1.025 1.000 0.597 79-00-5
TRICHLOROETHYLENE.................. 0.990 1.053 1.000 0.866 79-01-6
TRICHLOROFLUOROMETHANE............. 0.990 1.027 1.000 0.968 75-69-4
TRICHLOROPHENOL 2,4,5.............. 0.964 0.111 0.108 0.086 95-95-4
TRICHLOROPHENOL 2,4,6.............. 0.990 0.135 0.132 0.167 88-06-2
TRICHLOROPROPANE 1,1,1............. 0.990 1.048 1.000 0.897 7789-89-1
TRICHLOROPROPANE(1,1,2)............ 0.990 1.037 1.000 0.897 598-77-6
TRICHLOROPROPANE(1,2,2)............ 0.990 1.047 1.000 0.897 3175-23-3
TRICHLOROPROPANE(1,2,3)............ 0.990 1.048 1.000 0.894 96-18-4
TRICHLOROPROPENE (1,1,2)(M)........ 0.990 0.228 0.228 0.795
[[Page 68086]]
TRICOSANE N(M)..................... 0.990 0.133 0.133 0.301 629-50-5
TRIETHYLAMINE...................... 0.990 0.937 1.000 0.379 121-44-8
TRIETHYLENE GLYCOL(M).............. 0.846 0.150 0.150 0.111 112-27-6
TRIETHYLPHOSPHOROTHIOAT E,o,o,o-(M) 0.989 0.126 0.126 0.794 126-68-1
TRIFLUOROETHANE(1,1,1)............. 0.990 1.059 1.000 0.980
TRIFLUOROMETHANE................... 0.990 1.057 1.000 0.980
TRIFLURALIN........................ 0.990 0.086 0.116 0.291
TRIISOBUTYLENE..................... 0.990 1.117 1.000 0.980
TRIISOPROPYLAMINE.................. 0.990 1.026 1.000 0.715
TRIMELLITIC ANHYDRIDE (M).......... 0.629 0.129 0.129 0.087 552-30-7
TRIMETHYL BENZENE, 123............. 0.990 1.200 1.000 0.713
TRIMETHYL-4-NITROANILINE 2,3,5 (M). 0.990 0.135 0.135 0.831
TRIMETHYLAMINE..................... 0.990 0.811 1.000 0.464 75-50-3
TRIMETHYLBENZENE (1,3,5)........... 0.990 1.200 1.000 0.766 108-67-3
TRIMETHYLPENTANE 2,2,4............. 0.990 1.116 1.000 1.000 540-84-1
TRIMETHYLSILANOL................... 0.990 0.533 1.000 0.980
TRINITROBENZENE,sym-(M)............ 0.990 0.118 0.118 0.712 99-35-4
TRINITROTOLUENE(2,4,6)............. 0.223 0.004 0.009 0.120 118-96-7
TRIPHENYL PHOSPHINE (M)............ 0.990 0.094 0.094 0.321 603-35-0
TRIPHENYLMETHANE (M)............... 0.990 0.103 0.103 0.980 516-73-3
TRIPHENYLPHOSPHINE NICKEL CARBONM). 0.990 0.037 0.037 0.722
TRIS (1-AZIRIDINYL) PHOSPHINESU(M). 0.990 0.130 0.130 0.379 52-24-4
TRIS (2,3-DIBROMOPROPYL)PHOSPHA(M). 0.990 0.000 0.000 0.980 126-72-7
TRISODIUM NITRILOTRIACETATE (M).... 0.990 0.128 0.128 0.980 5064-31-3
TRYPAN BLUE(M)..................... 0.990 0.000 0.000 0.853 72-57-1
URACIL (M)......................... 0.990 0.794 0.794 0.857 66-22-8
URACIL MUSTARD (M)................. 0.990 0.099 0.099 0.853 66-75-1
UREA............................... 0.990 0.016 0.030 0.582 57-13-6
URETHANE........................... 0.990 0.024 0.039 0.370 51-79-6
VALERIC ACID (M)................... 0.990 0.963 0.963 0.287 109-52-4
VINYL ACETATE...................... 0.990 0.748 1.000 0.592 108-05-4
VINYL ACETYLENE.................... 0.990 1.232 1.000 0.890
VINYL BROMIDE...................... 0.990 0.629 1.000 0.849
VINYL CHLORIDE..................... 0.990 1.081 1.000 0.971 75-01-4
VINYL DIHYDROPYRAN................. 0.990 0.935 1.000 0.554
VINYL METHYL ETHER................. 0.990 0.831 1.000 0.590
VINYLCYCLOHEXENE 4(M).............. 0.990 0.860 0.860 0.980 100-40-3
VINYLIDENE CHLORIDE................ 0.990 1.061 1.000 0.889 75-35-4
XYLENE............................. 0.990 1.206 1.000 0.788 1330-20-7
XYLENE(-m)......................... 0.990 1.206 1.000 0.821 108-38-3
XYLENE(-o)......................... 0.990 1.206 1.000 0.787 95-47-6
XYLENE(-p)......................... 0.990 1.206 1.000 0.824 106-67-9
XYLIDINE dimethylaniline........... 0.606 0.131 0.124 0.074
XYLYL CHLORIDE M (M)............... 0.990 0.310 0.310 0.592 620-19-9
XYLYL CHLORIDE O (M)............... 0.990 0.310 0.310 0.592 552-45-4
----------------------------------------------------------------------------------------------------------------
* Molecular structure only approximate.
(M) fraction measured (fm) estimated from Mwt correlation.
\1\ The Fe values listed in Table 2 are Fe values for emissions from both the individual drain system and the
treatment process. Use these Fe values with Section 2.5.1).
Table 3 of Appendix J--FE Values for Emissions From Both the Individual
Drain System and the Treatment Process
[Use with section 2.5.1]
------------------------------------------------------------------------
Henry's Law Constant Fe Value
------------------------------------------------------------------------
0.00025................................................... 0.001
0.00051................................................... 0.002
0.00076................................................... 0.003
0.00127................................................... 0.005
0.00178................................................... 0.007
0.00254................................................... 0.010
0.00381................................................... 0.015
0.00508................................................... 0.020
0.00635................................................... 0.25
0.00762................................................... 0.030
0.00890................................................... 0.035
0.01017................................................... 0.040
0.01144................................................... 0.045
0.02327................................................... 0.050
[[Continued on page 68087]]
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