Bibliographic Citation
| Document | For copies of Journal Articles, please contact the Publisher or your local public or university library and refer to the information in the Resource Relation field. For copies of other documents, please see the Availability, Publisher, Research Organization, Resource Relation and/or Author (affiliation information) fields and/or Document Availability. |
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| Title | Kinetics of the aminolysis of 1-phenoxy-2,3-propylene carbonate with benzylamine in chlorobenzene |
| Creator/Author | Stroganov, V.F. ; Savchenko, V.N. ; Titskii, G.D. ; Sidorenko, E.V. ; Zaitsev, u.S. |
| Publication Date | 1988 Aug 10 |
| OSTI Identifier | OSTI ID: 6008398 |
| Other Number(s) | CODEN: JOCYA |
| Resource Type | Journal Article |
| Resource Relation | J. Org. Chem. USSR (Engl. Transl.) ; Vol/Issue: 24:3; Translated from Zh. Org. Khim.; 24: No. 3, 500-503 (Mar 1988) |
| Research Org | Ukrainian Scientific-Research Institute of Plastics, Donetsk (USSR) |
| Subject | 400201 -- Chemical & Physicochemical Properties; AMINES-- CATALYTIC EFFECTS;CARBONIC ACID ESTERS-- CATALYSIS;CHLORINATED AROMATIC HYDROCARBONS-- SOLVENT PROPERTIES; ACTIVATION ENERGY;CATALYSTS;CHEMICAL BONDS;CHEMICAL REACTION KINETICS;HYDROGEN;INFRARED SPECTRA;LYSIS;QUANTITY RATIO;SPECTROPHOTOMETRY |
| Related Subject | AROMATICS;ELEMENTS;ENERGY;ESTERS;HALOGENATED AROMATIC HYDROCARBONS;KINETICS;NONMETALS;ORGANIC CHLORINE COMPOUNDS;ORGANIC COMPOUNDS;ORGANIC HALOGEN COMPOUNDS;REACTION KINETICS;SPECTRA |
| Description/Abstract | The kinetics of the reaction of 1-phenoxy-2,3-propylene carbonate with benzylamine in chlorobenzene at 60/degree/C were studied.^Aminolysis of the cyclic carbonate takes place in two parallel directions, i.e., noncatalytic and catalyzed by two molecules of benzylamine.^A mechanism is proposed for the catalytic reaction, involving reaction of the cyclic carbonate, activated by a hydrogen bond with the amine, and the self-associated amine through a six-membered cyclic transition state. |
| Country of Publication | United States |
| Language | English |
| Format | Pages: 445-448 |
| System Entry Date | 2001 May 13 |
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