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Chemical Datasheet

BENZYLAMINE

Chemical Identifiers | Hazards | Response Recommendations | Physical Properties | Regulatory Information | Alternate Chemical Names

Chemical Identifiers

UN/NA Number - The United Nations-North America number (also called UN number or DOT number). 4-digit number identifying an individual chemical or group of chemicals with similar characteristics. Required on shipping papers; often shown on placards or labels. This numbering system was developed by the U.S. Department of Transportation, and then became the UN standard system for classifying hazardous materials.

CAS Number - Chemical Abstracts Service registry number. Unique identification number assigned to this chemical by the American Chemical Society.

CHRIS Code - 3-letter code used by the U.S. Coast Guard to identify individual chemicals included in its CHRIS (Chemical Hazards Response Information System) manual.

DOT Hazard Label - U.S. Department of Transportation hazard warning label for the chemical (such as flammable liquid or corrosive). This label must be displayed on shipped packages, railroad tank cars, and tank trucks according to specifications described in 49 CFR 172.

NFPA 704 - Text description of the diamond-shaped placard, which contains codes indicating the level of the chemical's health, flammability, and reactivity hazards, along with special hazards such as water- and air-reactivity. (The NFPA 704 diamond is also shown at the top of the datasheet.) See a guide to the NFPA diamond.

General Description - Brief description of the chemical's general appearance, behavior, and hazardousness.

List of data sources.
UN/NA Number CAS Number CHRIS Code DOT Hazard Label
none
  • 100-46-9
data unavailable
NFPA 704: data unavailable
General Description
Colorless to light yellow liquid with a strong odor of ammonia. Floats and mixes with water. (USCG, 1999)

Hazards

Reactivity Alerts - Special alerts if the chemical is especially reactive (see list of reactivity alerts).

Air & Water Reactions - Special alerts if the chemical reacts with air, water, or moisture.

Fire Hazard - Description of the chemical's fire hazards (such as flammability, explosion risk, or byproducts that may evolve if the chemical is burned).

Health Hazard - Description of the chemical's health hazards (such as toxicity, flammability, or corrosivity).

Reactivity Profile - Description of the chemical's potential reactivity with other chemicals, air, and water. Also includes any other intrinsic reactive hazards (such as polymerizable or peroxidizable).

Reactive Groups - List of reactive groups that the chemical is assigned to, based on its known chemistry. Reactive groups are categories of chemicals that react in similar ways because their chemical structures are similar. Reactive groups are used to predict reactivity when you add a chemical to MyChemicals. Read more about reactive groups.

List of data sources.
Reactivity Alerts
none
Air & Water Reactions
Water soluble.
Fire Hazard
Special Hazards of Combustion Products: Toxic nitrogen oxides may form in a fire. (USCG, 1999)
Health Hazard
Inhalation of vapor causes irritation of the mucous membranes of the nose and throat, and lung irritation with respiratory distress and cough. Headache, nausea, faintness, and anxiety can occur. Exposure to vapor produces eye irritation with lachrymation, conjunctivitis, and corneal edema resulting in halos around lights. Direct local contact with liquid is known to produce severe and sometimes permanent eye damage and skin burns. Vapors may also produce primary skin irritation and dermatitis. (USCG, 1999)
Reactivity Profile
In presence of moisture, BENZYLAMINE may weakly corrode some metals. Liquid will attack some plastics [USCG, 1999]. Neutralize acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.
Belongs to the Following Reactive Group(s)

Response Recommendations

Firefighting - Response recommendations if the chemical is on fire (or near a fire).

Non-Fire Response - Response recommendations if the chemical isn't on fire (or near a fire).

Protective Clothing - Recommendations for protective gear and, in some cases, a table of breakthrough times for protective materials.

First Aid - Recommended first aid treatment for people exposed to the chemical.

List of data sources.
Firefighting
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.

Fire Extinguishing Agents: Alcohol foam, dry chemical, carbon dioxide (USCG, 1999)
Non-Fire Response
Neutralizing Agents for Acids and Caustics: Flush with water. (USCG, 1999)
Protective Clothing
Self-contained breathing apparatus; goggles or face shield; rubber gloves (USCG, 1999)
First Aid
INHALATION: remove victim from exposure; if breathing is difficult, administer oxygen; if breathing has stopped, begin artificial respiration.

EYES or SKIN: wash with copious amounts of water for 15 min. (USCG, 1999)

Physical Properties

This section contains physical properties, flammability limits, and toxic thresholds for this chemical (see definitions of each property). More property data is available for common chemicals.

Guide to toxic levels of concern (AEGLs, ERPGs, TEELs, and IDLH).

List of data sources.
Molecular Formula:
  • C7H9N
Flash Point: 168.0 ° F (USCG, 1999)
Lower Explosive Limit: data unavailable
Upper Explosive Limit: data unavailable
Autoignition Temperature: data unavailable
Melting Point: -51.0 ° F (USCG, 1999)
Vapor Pressure: data unavailable
Vapor Density: data unavailable
Specific Gravity: 0.98 at 68.0 ° F (USCG, 1999)
Boiling Point: 364.1 ° F at 760.0 mm Hg (USCG, 1999)
Molecular Weight: 107.16 (USCG, 1999)
Water Solubility: data unavailable
AEGL: data unavailable
ERPG: data unavailable
TEEL-1 TEEL-2 TEEL-3
7.5 mg/m3 50.0 mg/m3 250.0 mg/m3
(SCAPA, 2008)
IDLH: data unavailable

Regulatory Information

Regulatory Names - Names under which this chemical is regulated under several U.S. federal laws: CAA (Clean Air Act of 1990), CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act of 1980, also known as Superfund), EPCRA (Emergency Planning and Community Right-to-Know Act, also known as SARA Title III), and RCRA (Resource Conservation and Recovery Act of 1976).

CAA RMP - Indicates whether this chemical is regulated under Section 112(r) of the Clean Air Act, which lists about 100 toxic, flammable, or explosive hazardous substances. (Section 112(r) mandates the Risk Management Plan regulations.) For listed chemicals, the Threshold Quantity (from 40 CFR 68) is also shown. Facilities that use more than the threshold quantity of a listed chemical in a process are subject to the CAA accidental release prevention provisions.

CERCLA - Indicates whether this chemical is listed as a hazardous substance under CERCLA. For listed chemicals, the Reportable Quantity (from 40 CFR 302) is also shown. Facilities that spill more than the reportable quantity of a listed chemical must report it to federal, state, and local governments.

EHS (EPCRA 302) - Indicates whether this chemical is listed as an Extremely Hazardous Substance under Section 302 of EPCRA. For listed chemicals, the Threshold Planning Quantity (from 40 CFR 355) is also shown. Facilities that store more than the threshold quantity of an EHS chemical must meet the reporting, community right-to-know, and emergency planning requirements of EPCRA.

TRI (EPCRA 313) - Indicates whether this chemical is listed as a toxic chemical under Section 313 (Toxics Release Inventory) of EPCRA. Facilities that manufacture, store, or use significant amounts of Section 313 chemicals may be required to submit annual reports about any releases into the environment (see 40 CFR 372).

RCRA Chemical Code - 4-character identification code assigned to this substance under RCRA.
Regulatory Names: none
CAA RMP: Not a regulated chemical.
CERCLA: Not a regulated chemical.
EHS (EPCRA 302): Not a regulated chemical.
TRI (EPCRA 313): Not a regulated chemical.
RCRA Chemical Code: none

Alternate Chemical Names

This section provides a listing of alternate names for this chemical, including trade names, synonyms, and foreign names.