202005chogor0journalOriginalChorazewski, M.[Miroslaw]Goralski, P.[Pawel]Tkaczyk, M.[Mariola]J. Chem. Eng. Data20052005-04-15Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysisHeat capacities at constant pressure of 1-chloropropane, 1-chlorobutane, 1-chloropentane, 1-chlorohexane, 1-chloroheptane, 1-chlorooctane, 1-chlorodecane and 1-bromoalkanes (1-bromoethane, 1-bromopropane, 1-bromobutane, 1-bromopentane, 1-bromohexane, 1-bromoheptane, 1-bromononane, 1-bromodecane) were measured within the temperature range from 284 K to 353 K by a differential scanning calorimeter DSC III (Setaram). These data and data previously reported for a,w -dibromoalkanes and a,w -dichloroalkanes, have been used as input for a group additivity type analysis.heat capacity1-chloroalkanes1-bromoalkanes50619-62411-chloropropaneC3H7Cl1Commercial source1982Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography21-chlorobutaneC4H9Cl1Commercial source199.53Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment299.53Gas chromatography31-chloropentaneC5H11Cl1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography41-chlorohexaneC6H13Cl1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography51-chloroheptaneC7H15Cl1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography61-chlorooctaneC8H17Cl1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography71-chlorodecaneC10H21Cl1Commercial source1982Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography8bromoethaneC2H5Br1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography91-bromopropaneC3H7Br1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography101-bromobutaneC4H9Br1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography111-bromopentaneC5H11Br1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography121-bromohexaneC6H13Br1Commercial source1982Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography131-bromoheptaneC7H15Br1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography141-bromononaneC9H19Br1Commercial source1992Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography151-bromodecaneC10H21Br1Commercial source1982Not known2De-gassed by boiling or ultrasonicallyFractional distillationMolecular sieve treatment2992Gas chromatography11Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551128.6351286.6551128.9951289.1551129.5351291.6551130.151294.1551130.4751296.6551130.9551299.1551131.3351301.6551131.8851304.1551132.3751306.6551132.9451309.1551133.451311.6551133.9251314.1551134.38521Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551156.2251286.6551156.7551289.1551157.2851291.6551157.751294.1551158.2751296.6551158.8651299.1551159.4851301.6551160.0551304.1551160.551306.6551161.0651309.1551161.5951311.6551162.2451314.1551162.9251316.6551163.4251319.1551164.1151321.6551164.8251324.155116551326.6551165.9751329.1551166.7251331.6551167.2951334.1551167.7851336.6551168.5351339.1551169.1251341.6551170.0151344.1551170.4351346.6551170.4951349.1551171.551351.6551173.0251353.1551173.09531Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551184.5751286.6551185.2951289.1551185.9551291.6551186.5251294.1551187.1651296.6551187.6651299.1551188.4651301.6551189.1951304.1551189.8151306.6551190.3251309.1551190.9951311.6551191.8951314.1551192.6551316.6551193.2251319.1551194.0951321.6551194.6951324.1551195.0651326.6551196.1451329.1551196.9951331.6551197.6451334.1551198.4651336.6551199.2351339.1551199.9251341.6551200.4151344.1551201.1951346.6551201.7351349.1551202.5451351.6551203.5751353.1551204.24541Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551212.3651286.6551213.2351289.1551213.9151291.6551214.6351294.1551215.451296.6551216.1251299.1551216.9551301.6551217.7551304.1551218.4451306.6551219.2251309.1551219.9951311.655122151314.1551221.7851316.6551222.4951319.1551223.4351321.6551224.3151324.1551224.751326.6551226.0251329.1551227.1351331.6551228.8651334.1551228.9951336.6551229.4451339.1551230.0651341.6551231.2251344.1551231.8351346.6551232.3251349.1551233.1851351.6551234.5651353.1551235.17551Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551240.9551286.6551241.7551289.1551242.6751291.6551243.451294.1551244.2951296.6551245.2351299.1551246.0551301.6551247.0351304.1551247.6151306.6551248.5351309.1551249.5451311.6551250.6551314.1551251.651316.6551252.251319.1551253.3651321.6551254.4251324.1551254.7651326.6551256.1951329.1551257.5751331.6551258.0651334.1551258.8451336.6551259.8851339.1551261.0151341.6551261.5551344.1551262.951346.6551263.2651349.1551264.351351.6551266.0451353.1551266.51561Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551269.7651286.6551270.7951289.1551271.8351291.6551272.6651294.1551273.6651296.6551274.5351299.1551275.6151301.6551276.5251304.1551277.2951306.6551278.3751309.1551279.2851311.6551280.551314.1551281.5851316.6551282.4751319.1551283.7951321.6551284.9251324.1551285.4551326.6551286.8151329.1551288.4351331.6551289.9551334.1551290.1351336.6551291.3451339.1551291.9151341.6551293.5651344.1551294.1651346.6551294.8251349.1551295.7951351.6551297.2151353.1551298.14571Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551328.5751286.6551329.8251289.155133151291.6551332.0151294.1551333.1451296.6551334.1351299.1551335.3951301.6551336.6151304.1551337.4751306.6551338.6651309.1551339.8351311.6551341.3951314.1551342.4251316.6551343.4151319.1551345.0451321.6551346.3651324.1551346.9951326.6551348.7551329.1551350.0151331.6551351.3151334.1551352.7651336.6551353.3951339.1551355.5251341.6551356.1751344.1551357.7451346.6551358.3851349.1551359.6551351.6551361.4951353.1551362.49581Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1269.1551104.0751271.6551104.3751274.1551104.651276.6551104.8551279.1551105.1451281.6551105.4251284.1551105.6351286.6551105.9151289.1551106.1451291.6551106.4251294.1551106.7551296.6551107.0951299.1551107.42591Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1269.1551129.0251271.6551129.4451274.1551129.7851276.6551130.151279.1551130.4851281.6551130.8651284.1551131.251286.6551131.6451289.1551132.0151291.6551132.4651294.1551132.7851296.6551133.251299.1551133.6451301.655113451304.1551134.5551306.6551134.9351309.1551135.3551311.6551135.851314.1551136.2351316.6551136.6851319.1551137.1651321.6551137.651324.1551138.1151326.6551138.555101Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551159.4551286.6551159.9851289.1551160.5351291.6551161.0151294.1551161.5251296.6551162.0851299.1551162.651301.6551163.0851304.1551163.7251306.6551164.2251309.1551164.7851311.6551165.3451314.1551165.9451316.6551166.4951319.1551167.0951321.6551167.6751324.1551168.2951326.6551168.8351329.1551169.4551331.6551170.0951334.1551170.6351336.655117151339.1551171.9451341.6551172.5751344.1551173.2651346.6551173.8951349.1551174.5151351.6551175.1951353.1551175.475111Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551187.8851286.6551188.4651289.1551189.1751291.6551189.8551294.1551190.3351296.6551190.9451299.1551191.5751301.6551192.1751304.1551193.0151306.6551193.5351309.1551194.1751311.6551194.8651314.1551195.651316.6551196.2151319.1551196.9851321.6551197.6151324.1551198.3551326.6551199.0951329.1551199.851331.6551200.4751334.1551201.4851336.6551201.5751339.1551202.7651341.6551203.5851344.1551204.3351346.6551205.0751349.1551205.8951351.6551206.6951353.1551207.055121Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551215.5451286.6551216.2951289.1551217.0851291.6551217.7851294.1551218.5451296.6551219.2651299.1551219.9951301.6551220.6851304.1551221.3851306.6551222.2251309.1551222.9851311.6551223.7951314.1551224.6351316.6551225.3751319.1551226.251321.6551227.0151324.1551227.8651326.6551228.6751329.1551229.5551331.6551230.3951334.1551231.2151336.6551231.5951339.1551233.2551341.6551233.7751344.1551234.7351346.6551235.6451349.1551236.5551351.6551237.3951353.1551237.855131Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551244.7351286.6551245.5651289.1551246.4451291.6551247.2851294.1551248.1251296.6551248.9351299.1551249.751301.6551250.3851304.1551251.5651306.6551252.3351309.1551253.1951311.6551254.1451314.155125551316.6551255.9751319.1551256.8451321.6551257.8551324.1551258.7651326.6551259.7151329.1551260.6851331.6551261.6151334.1551262.551336.6551262.9751339.1551264.6451341.6551265.4951344.1551266.5251346.6551267.4651349.1551268.4751351.6551269.5151353.1551270.035141Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551302.5551286.6551303.5451289.1551304.6251291.6551305.5751294.1551306.6951296.6551307.6851299.1551308.851301.6551309.8251304.1551310.9551306.6551311.9151309.1551313.0151311.6551314.151314.1551315.1851316.6551316.3251319.1551317.4451321.6551318.751324.1551319.851326.6551320.9651329.1551322.1651331.6551323.3251334.1551324.6351336.655132551339.1551326.9951341.6551328.1351344.1551329.3951346.6551330.4951349.1551331.7951351.6551333.0451353.1551333.745151Principal objective of the workXMLXML11/16/20041Molar heat capacity at constant pressure, J/K/molLarge sample (1 g) DSCLiquidDirect value, XLiquidPressure, kPa101.32561Temperature, K1284.1551332.641286.6551333.6551289.155133551291.6551336.0851294.1551336.951296.6551338.251299.1551339.2951301.6551340.3751304.1551341.4851306.6551342.7451309.1551343.8951311.6551345.1351314.1551346.3451316.6551347.5151319.1551348.8451321.6551350.151324.1551351.4151326.6551352.7151329.1551354.0251331.6551355.3251334.1551356.1451336.6551357.3451339.1551359.351341.6551360.751344.1551362.1351346.6551363.3751349.1551364.8651351.6551366.3851353.1551367.075