Phosphine's Corrosive Effects on Metals: Phase II Study Completed
Phosphine's Corrosive Effects on Metals: Phase II Study
Completed
The use of phosphine as an alternative to methyl bromide for fumigation in
food processing and stored-grain facilities has been controversial. Phosphine's
potential corrosive effects on metal and its chemical volatility have caused
many to disavow its use as a fumigant, but others have embraced it as a viable
alternative to methyl bromide.
The corrosiveness of phosphine is relative, dependant on its concentration,
type of exposed metal, temperature, and relative humidity, among other
variables. In the United States, all types of corrosion across all industries
cost approximately $300 billion per year, according to theNational Association of Corrosion
Engineers.
Robert Brigham, consultant to the Environmental Bureau,
Agriculture and Agri-Food Canada,
recently completed a follow-up to his 19971998 study of the
steady-state exposure of metals to phosphine. The study was partially funded by
the USDA's Agricultural Research Service.
By expanding the parameters of the first studytypes of metals used,
temperatures, phosphine concentrations, relative humidity, carbon dioxide
levels, and exposure timesBrigham could more precisely predict the effect
of phosphine on metals.
While corrosion of copper is directly related to the phosphine concentration
and exposure time, the form of the surface deposits was quite a surprise.
Brigham points out that, "sometimes the surface deposits on the metal will
be wet and sometimes dry." The type, or morphology, of surface deposit, is
related to the relative humidity in the storage facility. Logically, a wet
morphology would occur in high humidity conditions.
"The actual wet and dry morphologies occur counterintuitively. A dry
morphology occurs in high relative humidity and wet morphology occurs in low
relative humidity," according to Brigham. Wet surface deposits occur on
copper exposed to more than 100 ppm phosphine at ambient temperatures if the
relative humidity is less than about 50 percent. Higher relative humidity
results in dry surface deposits on copper. Generally, surface deposits, either
wet or dry, increase with phosphine concentration. Higher temperatures and
longer exposures result in more surface deposits and more corrosion on copper.
With the ability to minimize its corrosion of metals, phosphine's
effectiveness as a fumigant can be explored. Brigham's research suggests that
conditions in a food processing and grain-storage facility can be manipulated
to safely and effectively use phosphine. "The lab data fit well with
controlled field exposures," says Brigham.
Brigham's results provide useful data for proprietors when deciding whether
fumigation with phosphine is a viable option. David Mueller of Fumigation
Service and Supply, Inc., Westfield, Indiana, feels the use of phosphine as a
replacement fumigant for methyl bromide is commercially viable. "If
phosphine concentrations are kept at low levels of 85100 ppm and the
temperature at approximately 35 °C, then phosphine is a viable alternative
to methyl bromide."
Brigham also examined the effect of phosphine on electrical component parts
of various types of machinery. While failures did occur, the components were
found to be much more resistant to failure than expected. Forced failures of
electrical components were achieved due to high contact resistance from buildup
of nonconducting surface deposits, electrical shorting from the formation of
wet surface deposits, and disruption of circuits due to the corrosion of
metals. These failures occurred after extremes in relative humidity, phosphine
concentrations, and repeated exposures were inflicted.
Mueller says, "this study is part of the puzzle of how phosphine can
have niche uses as a replacement for methyl bromide. It provides the data that
phosphine users have needed for years."
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Last Updated: February 24, 2000
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