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Title THE REACTIONS OF 3-PHENYL-1-BUTYLAMINE-3-C$sup 14$ AND 3-p-ANISYL-1-BUTYLAMINE-3- C$sup 14$ WITH NITROUS ACID
Creator/Author Fort, A.W. ; Leary, R.E.
Publication Date1960 May 20
OSTI IdentifierOSTI ID: 4163830
Other Number(s)CODEN: JACSA; 0002-7863
Resource TypeJournal Article
Resource RelationJournal of the American Chemical Society (U.S.); Vol: 82
Research OrgUniv. of Kentucky, Lexington
SubjectCHEMISTRY; ACETIC ACID;ACIDS;AMINES;CARBON 14;CHEMICAL REACTIONS;ESTERS;LABELLED COMPOUNDS; ORGANIC NITROGEN COMPOUNDS;PREPARATION;SOLUTIONS
Description/Abstract The diazotization of 3-phenyl-1-butylamine-3-C/sup 14/ in acetic acid gives 3-phenyl-1-butene, 3-phenyl-1-butyl acetate, and diastereoisomeric 3-phenyl-2-butyl acetates. 3-pmixture. The secondary ester products of these reactions show extensive isotope-position rearrangement. The significance of these results is discussed. (auth)
LanguageEnglish
FormatPages: 2494-8
System Entry Date2001 Jun 03

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