Listing of Geochemical Data and Assessment of Variability for Soils and Alfalfa of the Uncompahgre Project Area, Colorado J.G. Crock K.C. Stewart R.C. Severson Introduction The Department of Interior (DOI), in response to Congressional requests, formed a multi-agency task group in the fall of 1985, including members from the Water Resources Division (WRD) and the Geological Division (GD) of the U.S. Geological Survey (USGS), the U.S. Fish and Wildlife Services (USFWS), the U.S. Bureau of Reclamation (USBR), and the Bureau of Indian Affairs, to investigate and examine the potential for damage to the lands affected by DOI irrigation projects in the Western U.S. The objective of this task group is to determine if irrigation practices have the potential to cause harmful effects on human health, fish, wildlife, and other water users, or to reduce the suitability of the water for beneficial uses. In 1988, reconnaissance studies were completed at ten areas in the Western U.S. (Harms and others, 1990) where wildlife management areas received irrigation drainage water from federally managed irrigation projects. The purpose of these studies was to recognize potential problems and problem elements from a limited sampling of water, bottom sediments, and biota, but not to characterize the areas in detail. The Uncompahgre Project Area (UPA) in west-central Colorado was one of these ten study areas. The UPA includes parts of the Gunnison River and the Uncompahgre River basin. Currently, approximately 86,000 acres in the area are under irrigation. Also included in the UPA is Sweitzer Lake, a Colorado State Park (1.3 km southeast of Delta, CO) that has been previously reported to contain high levels of selenium (Se) in biota, water, and bottom sediments (Harms and others, 1990). Preliminary results from a reconnaissance study in the UPA are given in detail by Butler and others (1991); the results indicate that the UPA is a major source of Se and molybdenum (Mo) and other dissolved and suspended loads to the Gunnison and Uncompahgre Rivers. The Gunnison River discharges into the Colorado River at Grand Junction, Colorado. As a result of the studies by Butler and others (1991), the DOI task group recommended the lower Gunnison River and the Uncompahgre River basins for a detailed study, which was initiated in early 1991. The detailed studies were to meet the following goals: (1) determine whether irrigation- induced water-quality problems exist, and if so, (2) provide the scientific understanding to mitigate or resolve identified problems. The USBR Uncompahgre Irrigation Project supplies water to irrigate land primarily in the Uncompahgre River basin between Colona and Delta, Colorado (figure 1). Irrigation in the study area dates to the late 1800's when over 30,000 acres were irrigated with water diverted from the Uncompahgre River by 1890. Additional irrigation was possible with the completion of the Gunnison Tunnel in 1909 which brought additional water into the UPA from the Gunnison River. The diversion dam on the Gunnison River was completed in 1912. Additional canals were later completed and the UPA reached its present size. The Taylor Park Reservoir and the Ridgway Reservoir also added to the storage capacity for the UPA. Irrigated crops in the UPA include onions, broccoli, beans, potatoes, barley, sweet corn, alfalfa, feed corn, hay, various small grains, and fruit orchards. This report describes the results of the detailed study of the UPA conducted by the USGS-GD personnel during 1991-92. The specific objectives of this report are to: (1) determine the chemical composition and variability of the irrigated, agricultural soils developed on various parent geologic units within UPA; and (2) estimate the availability of mobile element fractions and its variability among geologic units by sampling and analyzing alfalfa from each soil sampling locality. Selenium is a primary element of concern, however, other elements will also be reported and investigated. This report addresses only the total element concentrations in both the soils and alfalfa and their inter-relations. Extractable, or water-soluble, element concentrations and their relationships with the total soil and alfalfa elemental contents are addressed in Stewart and others (1993). Studies by other scientists of the USGS, USFWS, and USBR are being conducted to: (1) determine the sources, distribution, movement, and fate of contaminants within the hydrologic and biota systems; and (2) measure contaminant concentrations, determine exposure pathways, and document effects as seen in biota.