|
|
Technical Factsheet on: ANTIMONY
List
of Contaminants
As part of the Drinking Water and Health pages, this fact
sheet is part of a larger publication:
National Primary Drinking Water Regulations
Drinking Water Standards
MCLG: 0.006 mg/l
MCL: 0.006 mg/l
HAL(child): 1- to 10-day: 0.01 mg/L; Longer-term: 0.01 mg/L
Health Effects Summary
Acute: EPA has found antimony to potentially cause the following health
effects from acute exposures at levels above the MCL: nausea, vomiting
and diarrhea. Short-term exposures in drinking water considered "safe"
for a 10-kg (22 lb.) child consuming one liter of water per day: a long-term
(upto 7 years) exposure to 0.01 mg/L.
Chronic: Antimony has the potential to cause the following health effects
from long-term exposures at levels above the MCL: decreased longevity,
altered blood levels of glucose and cholesterol.
Cancer: There is inadequate evidence to state whether or not antimony
has the potential to cause cancer from lifetime exposures in drinking
water.
Usage Patterns
In 1984, 64.5 million lbs. antimony ore was mined and refined. Production
of the most commonly used antimony compound, the trioxide, increased during
the 1980s to about 31 million lbs, reported in 1985.
In 1985, it was estimated that industries consumed antimony trioxide
as follows: Flame retardant, 76%; catalyst, 6%; pigments, 5%; glass, 8%;
miscellaneous, 5%. Primary antimony was used as follows: Flame retardant,
60%; transportation (including batteries), 10%; ceramics/glass, 10%; other
uses, 10%.
Release Patterns
The most common antimony ores are the sulfide, stibnite, and the trioxide,
valentinite. Other ores include cervantite, livingstonite, jamisonite,
and kermesite. Antimony is also a common component of coal and petroleum.
Industrial dust and exhaust gases of cars and oil fuels are the main
sources of antimony in urban air. Substantial amounts of antimony trioxide
are released to the atmosphere during processing of antimony materials
including smelting of ores, molding and incineration of products, as well
as the combustion of fossil fuels which are utilize the high temperatures
needed to volatilize antimony trioxide.
From 1987 to 1993, according to the Toxics Release Inventory antimony
and antimony compound releases to land and water totalled over 12 million
lbs., of which nearly all was to land. These releases were primarily from
copper and other nonferrous smelting and refining industries. The largest
releases occurred in Arizona and Montana. The greatest releases to water
occurred in Washington and Louisiana.
Environmental Fate
Little information is available on the transformations and transport
of antimony in various media. The mobility of antimony in soils is not
clearly understood. The strength of its adsorption to soil and sediments
depends upon a variety of factors such as pH, organic matter content,
as well as the oxidation state of the particular salt. Some studies indicate
that antimony is highly mobile, while others conclude that it strongly
adsorbs to soil. In water, it usually adheres to sediments.
There is no evidence of bioconcentration of most antimony compounds,
though one report states that the tribromide can be concentrated by certain
forms of marine life to over 300 times its concentration in water.
Chemical/Physical Properties
CAS Number: 1440-36-0 (metal)
Color/ Form/Odor: Antimony is a metal which occurs in nature only in
the combined state
Soil sorption coefficient: N/A
Bioconcentration Factor: BCF up to 300; may accumulate in some aquatic
organisms
Solubilities:
stibine- slightly soluble
trifluoride- 4.4 kg/L at 20 deg C
trioxide- slightly soluble
trisulfide- 1.8 mg/L at 18 deg C
Common Ores: trioxide-Valentinite; sulfide-Stibnite. Other ores/natural
sources: cervantite, livingstonite, jamisonite, kermesite, petroleum
Other Regulatory Information
Monitoring:
-- For Ground Water Sources:
Initial Frequency-1 sample once every 3 years
Repeat Frequency-If no detections for 3 rounds, once every 9 years
-- For Surface Water Sources:
Initial Frequency-1 sample annually
Repeat Frequency-If no detections for 3 rounds, once every 9 years
-- Triggers - If detect at > 0.006 mg/L, sample quarterly.
Analysis
Reference Source |
Method Number |
EPA 600/4-79-020 |
204.2 |
NTIS PB 91-231498 |
200.9; 200.8 |
Standard Methods |
3113 |
ASTM |
D3697-87 |
Treatment/Best Available Technologies: Coagulation/Filtration,
Reverse Osmosis
Toxic Release Inventory - Releases to Water and Land, 1987 to 1993
(in pounds):
|
Water |
Land |
TOTALS |
330,064 |
12,003,373 |
Top Ten States * |
AZ |
505 |
7,074,128
|
MT |
0 |
2,338,697
|
TX |
24,817 |
840,392
|
LA |
55,414 |
344,762
|
WI |
1,445 |
392,000
|
MO |
784 |
188,266
|
WA |
63,220 |
99,915
|
ID |
2,600 |
140,250
|
TN |
687 |
108,325
|
AL |
27,536 |
69,503
|
Major Industries* |
Copper smelting, refining |
505 |
7,074,128
|
Other nonferrous smelt. |
17,015 |
2,383,947
|
Sec. nonferrous smelt. |
1,459 |
803,398
|
Misc Indust. Organics |
18,424 |
581,465
|
Porcelain plumb. fixtures |
1,445 |
392,000
|
Petroleum refining |
111,527 |
202,251
|
Misc Inorganic chems. |
4,962 |
140,250
|
Plastics, resins |
20 |
60,372
|
Storage batteries |
0 |
45,952
|
Synthetic fibers |
26,803 |
12,535
|
* Water/Land totals only include facilities with releases greater than
a certain amount - usually 1000 to 10,000 lbs.
For Additional Information:
EPA can provide further regulatory and other general information:
EPA Safe Drinking Water Hotline - 800/426-4791
Other sources of toxicological and environmental fate data include:
Toxic Substance Control Act Information Line - 202/554-1404
Toxics Release Inventory, National Library of Medicine - 301/496-6531
Agency for Toxic Substances and Disease Registry - 404/639-6000
List
of Contaminants
|