The Microgravity Research Experiments (MICREX) Database


Diffusion


Refraction Gradients in Glasses


Principal Investigator(s):

Frischat, G. H. (1); Beier, W. (2) Horst, U. (3)

Co-Investigator(s):

None

Affiliations:

(1,2) Technische UniversitŠt Clausthal, Germany; (3) Unknown, possibly: Technische UniversitŠt Clausthal, Germany

Experiment Origin:

Federal Republic of Germany

Mission:

TEXUS 16

LaunchDate/Experiment Date:

11/23/87

Launched From:

ESRANGE, Kiruna, Northern Sweden

Payload Type:

Sounding Rocket Experiment

Processing Facility:

TEXUS Experiment Module TEM 01-2

Builder of Processing Facility:

MBB/ERNO, Bremen, Germany

Experiment Summary:

Refraction Gradients in Glasses

This TEXUS 16 sounding rocket experiment was the twelfth in a series of investigations designed by Frischat et al. to study reaction kinetics in glasses (see Frischat, TEXUS 1, TEXUS 4, TEXUS 6, Spacelab 1, STS-011, TEXUS 11, TEXUS 12, Spacelab D1, TEXUS 13, TEXUS 15, TEXUS 16("Self-diffusion")). (Earlier experiments in the series of experiments included examinations in the areas of (1) interdiffusion between glass melts of differing compositions, (2) corrosion of silica by the melt, and (3) self-diffusion in glass melts.)

Reportedly, the specific objective of the experiment was to study a "Silver/sodium exchange... at 350 ˇC between an alumo-alkali-silicate glass and a... silver containing salt melt." (Reference 3)

Two samples contained within one cartridge were to be processed during the mission: (1) 61 SiO2 . 33 Na2O . 6 Al2O3 (glass) and 9 NaNO3 . 1 AgNO3 (salt melt).

It was reported that shortly after the successful launch of TEXUS 16, fuel in the second stage of the rocket did not ignite as planned. After the apogee was reached and the rocket began to fall, the yo-yo despin system was deployed as programmed. Due to the unexpected excess rocket mass, however, there was an incomplete reduction of rocket spin. Subsequently, the payload separated from the second stage, but the parachute was not released. An unbraked impact of the payload resulted in the destruction of all experiment modules including the TEM 01-2 module.

The Experiment Investigator reported that there were no experimental results. The experiment was reflown on TEXUS 19.

Key Words:

*Diffusion*Glasses*Glass Melts*Alkaline Glasses*Molten Salts*Melt and Solidification*Interdiffusion*Double Diffusion*Liquid/Liquid Diffusion*Reaction Kinetics*Ion Exchange*Solid/Liquid Interface*Liquid/Liquid Interface*Payload Survivability*Acceleration Effects*

Number of Samples:

two

Sample Materials:

(1) Glass: 61 SiO2 . 33 Na2O . 6 Al2O3 (2) Salt Melt: 9 NaNO3 . 1 AgNO3 (Si*O*Na*O*Al*O*, Na*N*O*Ag*N*O*)

Container Materials:

platinum (Pt*)

Experiment/Material Applications:

The experiment was performed to investigate if "...puried silver profiles can be obtained by a one step process with an unstirred salt melt." (Reference (3))

References/Applicable Publications:

(1) Die Kampagne TEXUS 16. In BMFT/DFVLR TEXUS 13-16 Abschlussbericht, 1988, pp. 109-111. (in German; post-flight)

(2) Frischat, G. H. Horst, U., and Beier, W.: Special Refractive Index Profiles in Glasses Obtained by Ion Exchange. TEXUS 20, BMFT Research Report 01 QV 86201, 1989. (in German)

(3) Input received from Experiment Investigator, August 1993.

Contact(s):

Prof. Dr. G. H. Frischat
Institut fźr Nichtmetallische Werkstoffe
Technische UniversitŠt Clausthal
Zehntnerstr. 2-A
38678 Clausthal-Zellerfeld
Germany